Patent classifications
B01J29/146
Bimetallic catalysts supported on zeolites for selective conversion of n-butane to ethane
A hydrogenolysis bimetallic supported catalyst comprising a first metal, a second metal, and a zeolitic support; wherein the first metal and the second metal are different; and wherein the first metal and the second metal can each independently be selected from the group consisting of iridium (Ir), platinum (Pt), rhodium (Rh), ruthenium (Ru), palladium (Pd), molybdenum (Mo), tungsten (W), nickel (Ni), and cobalt (Co).
Structured catalyst for steam reforming, reforming apparatus provided with structured catalyst for steam reforming, and method for manufacturing structured catalyst for steam reforming
A structured catalyst for steam reforming of the present disclosure is used for producing reformed gas containing hydrogen from a reforming raw material containing hydrocarbon, and includes a support having a porous structure constituted of a zeolite-type compound, and at least one catalytic substance present inside the support. The support includes channels connecting with each other, and the catalytic substance is metal nanoparticles and present at least in the channels of the support.
Structured catalyst for oxidation for exhaust gas purification, method for producing same, automobile exhaust gas treatment device, catalytic molding, and gas purification method
The structured catalyst for oxidation for exhaust gas purification includes a support having a porous structure constituted by a zeolite-type compound, and at least one type of oxidation catalyst that is present in the support and selected from the group consisting of metal and metal oxide, the support having channels that communicate with each other, and the oxidation catalyst being present in at least the channels of the support.
METHOD FOR PRODUCING LIGHT AROMATIC
A method for producing light aromatics, includes the steps of: i) contacting a feedstock comprising heavy aromatic(s) with a catalyst in a fluidized reactor for aromatics lightening reaction in the presence of hydrogen to obtain a product rich in C6-C8 light aromatic(s) and a spent catalyst, wherein the heavy aromatic is one or more selected from C9+ aromatics; ii) separating the resulted product rich in C6-C8 light aromatic(s) to obtain hydrogen, a non-aromatic component, C6-C8 light aromatic(s) and a C9+ aromatic component; and iii) recycling at least a part of the C9+ aromatic component to the fluidized reactor. The method has strong adaptability to feedstocks and high flexibility in operation and allows a long-period stable operation. The method can produce high-value light aromatics from heavy aromatics that are difficult to be treated and utilized.
Method for producing bio-jet fuel
A method for producing a bio-jet fuel includes a reaction step of hydrogenating, isomerizing, and decomposing a crude oil obtained by a deoxygenation treatment of a raw oil containing a triglyceride and/or a free fatty acid, by using a hydrogenation catalyst and an isomerization catalyst in a hydrogen atmosphere under conditions of a reaction temperature of 180° C. to 350° C. and a pressure of 0.1 MPa to 30 MPa.
HEAT SOURCE DEVICE AND METHOD FOR USING SILVER ZEOLITE
Provided is a new heat source device utilizing a catalytic reaction heat of silver zeolite, the heat source device including an accommodation container for accommodating the silver zeolite while ensuring air permeability, in which the accommodation container is configured to be ventilated with a mixed gas containing hydrogen, steam, and air, the accommodation container is configured as a metal cylindrical member that includes a metal ventilation structure having a mesh on a downstream side in a ventilation direction, the mesh having a mesh size finer than a particle diameter of the silver zeolite; and the cylindrical member has a double pipe structure including an inner pipe and an outer pipe, said inner pipe being a straight pipe for allowing the mixed gas to linearly flow therein.
Solid-Acid Catalyzed Paraffin Alkylation With Rare Earth-Modified Molecular Sieve Adsorbents
This invention describes methods of alkylating isobutane which include a catalytic reaction system comprising a crystalline zeolite catalyst and a rare earth-modified molecular sieve adsorbent (RE—MSA). The crystalline zeolite catalyst comprises sodalite cages and supercages, a Si/Al molar ratio of 20 or less, less than 0.5 weight percent alkali metals; and up to 5 wt% of Pt, Pd and or Ni, and acid-site density (including both Lewis and Brønsted acid sites) of at least 100 .Math.mole/gm. The RE-modified molecular sieve adsorbent (Re—MSA) comprising sodalite cages and supercages, a Si/Al molar ratio of 20 or less, less than 1 wt% of alkali metals, RE (rare earth elements) in the range of 10 to 30 wt% and transition metals selected from groups 9-11 in the range from 2 wt% to 10 wt; and acid-site density of no more than 30 .Math.mole/gm. The invention also includes methods of making RE—MSA.
HYDROCRACKING CATALYST FOR HEAVY FRACTION OF BIO-OIL, METHOD FOR PREPARING THE SAME AND METHOD FOR BIO-OIL UPGRADING USING THE SAME
Disclosed herein are a catalyst for hydrocracking reaction of high molecular weight components in bio-oil, a method for preparing the same and a method for bio-oil upgrading using the same. The catalyst includes a zeolite carrier; and at least one metal selected from the group consisting of nickel (Ni), ruthenium (Ru) and cerium (Ce) supported on the carrier. The catalyst promotes the hydrocracking of high molecular weight compounds contained in the bio-oil, but also inhibits the polymerization reaction of the decomposed product, thereby more effectively enhancing the hydrocracking reaction of the bio-oil.
Structured catalyst for hydrodesulfurization, hydrodesulfurization device including the structured catalyst, and method for producing structured catalyst for hydrodesulfurization
Provided is a structured catalyst for hydrodesulfurization that suppresses the decline in catalytic activity and achieves efficient hydrodesulfurization. The structured catalyst for hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound, and at least one catalytic substance (20) present in the support (10), the support (10) having channels (11) connecting with each other, and the catalytic substance (20) being present at least in the channels (11) of the support (10).
Alkylating process for alkyl benzenes
This invention relates to an alkylating process for alkyl benzenes, including the steps of: a) an alkyl benzene and a first stream of alkylating agent being fed into a first reaction zone, contacting with a catalyst A, to produce a process stream I; b) the process stream I and a second stream of alkylating agent being fed into at least one second reaction zone, contacting with a catalyst B, to produce a process stream II; and c) the process stream II being fed into at least one third reaction zone, contacting with a catalyst C, to produce a process stream III containing an alkylate. The present alkylating process can improve the utilization efficiency of the alkylating agent.