Catalyst particles comprising one or more active metal components and methods for manufacturing such catalyst particles are provided. The particles are a composite of a granulating agent or binder material such as an inorganic oxide, and an ultra-stable Y (hereafter “USY”) zeolite in which some of the aluminum atoms in the framework are substituted with zirconium atoms and/or titanium atoms and/or hafnium atoms. The one or more active phase components are incorporated prior to mixing the binder with the post-framework modified USY zeolite, extruding the resulting composite mixture, and forming the catalyst particles. The one or more active phase components are incorporated in the binder material prior to forming the catalyst particles.

Catalyst particles comprising one or more active metal components and methods for manufacturing such catalyst particles are provided. The particles are a composite of a granulating agent or binder material such as an inorganic oxide, and an ultra-stable Y (hereafter “USY”) zeolite in which some of the aluminum atoms in the framework are substituted with zirconium atoms and/or titanium atoms and/or hafnium atoms. The one or more active phase components are incorporated prior to mixing the binder with the post-framework modified USY zeolite, extruding the resulting composite mixture, and forming the catalyst particles. The one or more active phase components are incorporated in the binder material prior to forming the catalyst particles.

Disclosed are a catalyst for carbonylation of dimethyl ether that has high catalyst activity and can be regenerated using a fluidized bed reactor, and a method for preparing the same. The catalyst for carbonylation of dimethyl ether includes a support having a first density; and ferrierite zeolite catalyst particles bound to a surface of the support via a polymer binder and having a second density smaller than the first density.

Disclosed are a catalyst for carbonylation of dimethyl ether that has high catalyst activity and can be regenerated using a fluidized bed reactor, and a method for preparing the same. The catalyst for carbonylation of dimethyl ether includes a support having a first density; and ferrierite zeolite catalyst particles bound to a surface of the support via a polymer binder and having a second density smaller than the first density.

The invention concerns a method for unblocking pores in a metal zeolite based selective catalytic reduction (SCR) catalyst. The method includes filling, at least partially, the SCR catalyst with a liquid, the liquid being preferably distilled water. The method includes letting said liquid inside the SCR catalyst enough time to allow said liquid to dissolve, at least partially, the obstructions and to penetrate into the pores. The method includes heating the SCR catalyst at a temperature above the ebullition temperature of the liquid so as to vaporize the part of the liquid remained into the pores, and generate steam flows through the obstructions, the steam flows removing the obstructions and unblocking the pores, wherein no hydrocarbons are injected during the step of heating.

The invention concerns a method for unblocking pores in a metal zeolite based selective catalytic reduction (SCR) catalyst. The method includes filling, at least partially, the SCR catalyst with a liquid, the liquid being preferably distilled water. The method includes letting said liquid inside the SCR catalyst enough time to allow said liquid to dissolve, at least partially, the obstructions and to penetrate into the pores. The method includes heating the SCR catalyst at a temperature above the ebullition temperature of the liquid so as to vaporize the part of the liquid remained into the pores, and generate steam flows through the obstructions, the steam flows removing the obstructions and unblocking the pores, wherein no hydrocarbons are injected during the step of heating.

Disclosed are a catalyst pre-hydrocarbon-pooling method and a pre-hydrocarbon-pooling device, relating to the technical field of preparation of low carbon olefins. A regenerated catalyst enters a pre-hydrocarbon-pooling reactor, and a pre-hydrocarbon-pooling reaction occurs between the regenerated catalyst and an activation medium to form “hydrocarbon pool” active species. “Pre-hydrocarbon-pooling” treatment is performed on the regenerated catalyst by providing a pre-hydrocarbon-pooling device, so that the regenerated catalyst forms the “hydrocarbon pooled” active species and carbon deposition before entering into an oxygenate conversion reactor, by way of which “hydrocarbon pool” active species distribution and coke distribution of the catalyst in the conversion reactor are improved. This shortens or eliminates a reaction “induction period” and improves the catalytic activity and selectivity of the regenerated catalyst for a reaction of an oxygenate to low-carbon olefins.

A fluidized bed regenerator, a device for preparing low-carbon olefins, and a use thereof are provided. The fluidized bed regenerator includes a second activation zone, a first activation zone, and a gas-solid separation zone from bottom to top; the second activation zone axially communicates with the gas-solid separation zone; the first activation zone is arranged on a periphery of a junction between the second activation zone and the gas-solid separation zone; the first activation zone is an annular cavity; n baffles are radially arranged in the first activation zone, and the n baffles divide the first activation zone into n first activation zone subzones; and a catalyst circulation hole is formed in each of n−1 of the baffles such that a catalyst entering the first activation zone flows in an annular direction.

A fluidized bed regenerator, a device for preparing low-carbon olefins, and a use thereof are provided. The fluidized bed regenerator includes a second activation zone, a first activation zone, and a gas-solid separation zone from bottom to top; the second activation zone axially communicates with the gas-solid separation zone; the first activation zone is arranged on a periphery of a junction between the second activation zone and the gas-solid separation zone; the first activation zone is an annular cavity; n baffles are radially arranged in the first activation zone, and the n baffles divide the first activation zone into n first activation zone subzones; and a catalyst circulation hole is formed in each of n−1 of the baffles such that a catalyst entering the first activation zone flows in an annular direction.

A regeneration method for a benzene alkylation solid acid catalyst, comprising: purging the solid acid catalyst in a reactor with a gas; continuously injecting n-hexane at a feed port of the reactor and heating the n-hexane to wash the solid acid catalyst, and discharging the n-hexane entraining benzene alkylation reaction residues from a discharge port of the reactor; and stopping injecting n-hexane, cleaning off a liquid in the reactor by purging with the gas, and cooling the reactor. In the regeneration method of the present disclosure, the regeneration liquid used is n-hexane, which can increase the solubility of the residues in channels and enhance the regeneration effect. Meanwhile, permanent damage to the channel structure of the catalyst caused by carbon burning regeneration can be avoided, thereby prolonging the lifetime of the catalyst.