Mixture of bisphosphites having an open and a closed outer unit and the use thereof as a catalyst mixture in hydroformylation.

Diphosphites having an open and a closed 2,4-methylated outer unit and use thereof in hydroformylation.

The present invention concerns a process for oligomerizing an olefin feedstock to form an oligomerization product, and a method of controlling such an oligomerization process. The process comprises oligomerizing propylene to form a C.sub.n olefin, including contacting a feed stream comprising propylene and a recycle fraction with a solid phosphoric acid oligomerization catalyst under effective oligomerization conditions in an oligomerization reactor to produce an oligomerization effluent; and fractionating the oligomerization effluent to obtain a product fraction and the recycle fraction, the product fraction comprising the C.sub.n olefin and the recycle fraction comprising a C.sub.n-3 olefin; wherein the recycle fraction comprises at least 80 wt % of the C.sub.n-3 olefin, based on the weight of the recycle fraction; and wherein n is 9, or 12.

The use of hypophosphorous acid as a corrosion inhibitor for esterification reactions of free fatty acids contained in a fatty substance is described, particularly in the presence of an organosulfonic acid. The invention also relates to a method for the esterification of fatty acids.

Diphosphites having an open and a closed 2,4-methylated outer unit and use thereof in hydroformylation.

Mixture of bisphosphites having an open and a closed outer unit and the use thereof as a catalyst mixture in hydroformylation.

A carbon catalyst has improved catalytic activity, and an electrode and a battery include the carbon catalyst. A carbon catalyst includes a metal and phosphorus atoms, wherein a ratio of a concentration (atomic %) of the phosphorus atoms exhibiting a peak having a peak top within a range of 132.5±0.3 eV and having a full width at half maximum of 2.0±0.5 eV, which is obtained by peak separation of a phosphorus atom P2p peak, with respect to a concentration (atomic %) of carbon atoms in X-ray photoelectron spectroscopic measurement is 0.0005 or more.

A process for cracking olefins to produce propylene, ethylene, or both, includes providing a feed stream that includes mixed butenes and contacting the feed stream with a cracking catalyst at reaction conditions that cause at least a portion of the mixed butenes in the feed stream to react to form propylene, ethylene, or both. The cracking catalyst includes zeolite particles formed from shape selective zeolite particles and an alumina binder. The cracking catalyst further includes at least one transition metal oxide impregnated onto the zeolite particles, where the at least one transition metal oxide can be iron oxide, nickel oxide, or a combinations of these. The cracking catalyst with the iron oxide, nickel oxide, or both increases conversion of mixed butenes to propylene, ethylene, or both alone or in combination with a metathesis upstream of the cracking catalyst, as compared to conventional cracking catalysts.

The use of hypophosphorous acid as a corrosion inhibitor for esterification reactions of free fatty acids contained in a fatty substance is described, particularly in the presence of an organosulfonic acid. The invention also relates to a method for the esterification of fatty acids.

The present invention concerns a process for oligomerizing an olefin feedstock to form an oligomerization product, and a method of controlling such an oligomerization process. The process comprises oligomerizing propylene to form a C.sub.n olefin, including contacting a feed stream comprising propylene and a recycle fraction with a solid phosphoric acid oligomerization catalyst under effective oligomerization conditions in an oligomerization reactor to produce an oligomerization effluent; and fractionating the oligomerization effluent to obtain a product fraction and the recycle fraction, the product fraction comprising the C.sub.n olefin and the recycle fraction comprising a C.sub.n-3 olefin; wherein the recycle fraction comprises at least 80 wt % of the C.sub.n-3 olefin, based on the weight of the recycle fraction; and wherein n is 9, or 12.