B01J31/0267

METHOD FOR OLEFIN OLIGOMERIZATION

The present invention relates to a method for olefin oligomerization and comprising i) injecting an olefin monomer and a solvent into a continuous stirred tank reactor (CSTR); ii) injecting an oligomerization catalyst system comprising a ligand compound, a transition metal compound, and a co-catalyst into the continuous stirred tank reactor; and iii) performing a multimerization reaction of the olefin monomer, wherein a ratio of the flowing rates of the olefin monomer and the solvent is from 1:1 to 2:1. In the method for olefin oligomerization according to the present invention, high linear alpha-olefin selectivity may be attained even with a small amount of a solvent used by controlling reaction conditions during the multimerization reaction of olefin by a continuous reaction using a continuous stirred tank reactor.

Microencapsulated polyaddition catalyst

A microencapsulated polyaddition catalyst comprises a capsule core, containing polyaddition catalyst, and an acrylic copolymer capsule shell, the acrylic copolymer comprising copolymerized units of an intermolecular anhydride of an ethylenically unsaturated C.sub.3-C.sub.12 carboxylic acid. The polyaddition catalyst is selected from acyclic tertiary amines, alicyclic tertiary amines, N-alkylimidazoles, phosphines and organic metal salts. It is suitable for catalysing the reaction of a polyol compound with a polyisocyanate compound. The polyaddition catalyst is released by a chemical stimulus, such as on contact with polyols or water, for example.

Synthesis method and synthesis device for cyclododecene

A synthesis method and a synthesis device of cyclododecene according to the present invention have a high conversion rate of cyclododecatriene which is a reactant and a high selectivity of cyclododecene which is a required product, and even so, have an effect of significantly decreasing a reaction time. In addition, the method and the device have an excellent conversion rate of cyclododecatriene and an excellent selectivity of cyclododecene, while maintaining excellent reactivity without an organic solvent such as ethanol. Therefore, a volume of the reactor relative to an output of cyclododecene may be further decreased. Moreover, the method and the device may minimize costs for facilities and process, are practical, decrease a process time, and are industrially advantageous for mass production as compared with the conventional art.

ETHYLENE OLIGOMERIZATION PROCESSES
20220380274 · 2022-12-01 ·

Process for producing alpha olefins comprising contacting ethylene, a zirconium based catalyst system comprising, a hydrocarbylmetal compound, a chain transfer agent, and optionally an organic reaction medium. Chain transfer agents which can be utilized include a) hydrogen, b) a compound comprising a hydrogen silicon bond, a compound having a hydrogen sulfur bond, a compound having a hydrogen phosphorus bond, or c) a transition metal compound chain transfer agent.

Preparation method for epoxy compound having alkoxysilyl group

Provided is a method for preparing an epoxy compound having an alkoxysilyl group effectively by using a mild catalyst as well as an aromatic alcohol ring-opening agent. The preparation method for an epoxy compound having an alkoxysilyl group includes: performing a ring opening step by reacting an epoxy compound having an epoxide group, which is a starting material, with an aromatic alcohol ring-opening agent in the presence of a phosphine-based catalyst and an optional solvent so as to obtain an intermediate having a partially ring-opened epoxide group; and performing an alkoxysilylation step by reacting the intermediate having a partially ring-opened epoxide with isocyanate alkoxysilane.

METHOD FOR PREPARING ACRYLONITRILE DIMER

A method for preparing an acrylonitrile dimer according to the present disclosure makes it is possible to efficiently recover an acrylonitrile dimerization catalyst while reducing the process load.

METHOD OF PREPARING ACRYLONITRILE DIMER
20220356149 · 2022-11-10 ·

The present disclosure relates to a method for preparing acrylonitrile dimer.

ETHYLENE OLIGOMERIZATION PROCESSES
20230093448 · 2023-03-23 ·

Process for producing alpha olefins comprising contacting ethylene, a zirconium based catalyst system comprising, a hydrocarbylmetal compound, a chain transfer agent, and optionally an organic reaction medium. Chain transfer agents which can be utilized include a) hydrogen, b) a compound comprising a hydrogen silicon bond, a compound having a hydrogen sulfur bond, a compound having a hydrogen phosphorus bond, or c) a transition metal compound chain transfer agent.

Method for preparing cyclododecene and synthesis device therefor

A method for preparing cyclododecene and a synthesis device therefor, of the present invention, remarkably increase the conversion ratio of cyclododecatriene and selectivity of cyclododecene, can minimize the costs required for equipment and processing, are practical, reduce processing time, and are industrially advantageous to mass production in comparison with a conventional method and device.

Synthesis of N-vinyl compounds by reacting cylic NH-compounds with acetylene in presence of homogenous catalyst

A process can be used to produce N-vinyl compounds by homogeneous catalysis. In the process, acetylene is reacted with a cyclic compound having at least one nitrogen as a ring member, hearing a substitutable hydrogen residue (cyclic compound C), in a liquid phase in the presence of a ruthenium complex containing at least one phosphine as a ligand (RuCat).