B01J31/0287

Process for the preparation of glycerol carbonate

This invention relates to a process for the preparation of glycerol carbonate from the reaction of glycerol and a dialkylcarbonate, for example dimethyl carbonate, or a cyclic alkylene carbonate. More specifically, the invention relates to a process where the synthesis of glycerol carbonate is conducted in the presence of a homogeneous transesterification catalyst and involves the partial reaction of a glycerol reactant stream and a dialkyl carbonate or cyclic alkylene carbonate reactant stream and an intermediate step of alcohol by-product separation before further reaction in order to improve glycerol conversion and glycerol carbonate selectivity and yield.

METHOD OF PREPARING HETEROGENEOUS LINEAR CARBONATE USING CATALYST HAVING EXCELLENT SOLUBILITY

The present invention relates to a method of preparing a heterogeneous linear carbonate, the method including performing a transesterification reaction of dimethyl carbonate (DMC) and ethanol (EtOH) in the presence of a catalyst, wherein the catalyst is one or more selected from the group consisting of lithium methoxide (LME), lithium ethoxide (LEE), sodium methoxide (SME), sodium hydroxide (NaOH), and a mixture thereof, and the catalyst is input in a state of being dissolved in a sulfoxide-based solvent.

METHOD OF PREPARING HETEROGENEOUS LINEAR CARBONATE ADOPTING CATALYTIC FILTERING

Provided herein is a method of preparing a heterogeneous linear carbonate, including: performing a transesterification reaction of dimethyl carbonate (DMC) and ethanol (EtOH) in the presence of a catalyst; and filtering a composite obtained by the transesterification reaction through a filter.

PROCESS FOR THE PREPARATION OF GLYCEROL CARBONATE

This invention relates to aprocess for the preparation of glycerolcarbonate from the reaction of glycerol and a dialkyl-carbonate, for example dimethyl carbonate, or a cyclic alkylene carbonate. More specifically, the invention relates to a process where the synthesis of glycerolcarbonate is conducted in the presence of a homogeneous transesterificationcatalyst and involves the partial reaction of a glycerol reactant stream and a dialkyl carbonateor cyclic alkylene carbonate reactant stream and an intermediate step of alcohol by-product separation before further reaction in order to improve glycerol conversion and glycerol carbonate selectivity and yield.

IONIC LIQUID, ADDUCT AND METHODS THEREOF

The present disclosure relates to preparation of liquid salt including but not limiting to ionic liquid and applications thereof. More particularly, the present disclosure provides a process for preparing ionic liquid which comprises reacting at least one electron-pair acceptor and at least one electron-pair donor to form an adduct, and reacting the adduct with at least one electron-pair acceptor to prepare said salt. The present disclosure also provides for applications of the ionic liquid prepared in the present disclosure.

Ionic liquid compound

The present disclosure provides an ionic liquid compound of Formula (I) and its application in reactions such as alkylation, arylation, acylation, diels alder and oligomerization, ##STR00001## The present disclosure also provides a process for preparing the ionic liquid compound of Formula (I) which involves preparing an ionic salt complex represented by Formula [(NR.sub.1R.sub.2R.sub.3).sub.iM.sub.1].sup.n+[X.sub.j].sup.n by mixing an amine represented by Formula NR.sub.1R.sub.2R.sub.3 and a metal salt represented by formula M.sub.1X.sub.j; and mixing the ionic salt complex and a metal salt represented by formula M.sub.2Y.sub.k to obtain the ionic liquid compound.

METHODS AND INTERMEDIATES FOR PREPARING ANTIVIRAL PRODRUGS

The present invention is related to processes for preparing antiviral prodrugs, co-crystals, solvents, salts or combinations thereof, and related synthetic intermediate compounds.