The present disclosure provides a Lewis acid-base pair catalytic initiator and an application thereof. The Lewis acid-base pair catalytic initiator includes a Lewis acid and a Lewis base, the Lewis acid having a structural general formula as shown in formula (I) and the Lewis base having a structural general formula as shown in formula (II); wherein: the A is selected from element Baron or element Aluminum; the R.sub.1, R.sub.2, R.sub.3, R.sub.4 are independently selected from alkyl, alkoxy, aryl or halogen groups; the alkyl or alkoxy have a carbon number being equal to or greater than 1 to equal to or less than 16; the aryl contains substituents with the number being equal to or less than 5, the substituents being selected from methyl, methoxy or halogen; n is selected from an integer from 1 to 16.

The present invention relates to an organic borate-based catalyst including a compound represented by the following Formula 1 and a hydroxyl group-containing compound, a method for preparing an isobutene oligomer using the same and an isobutene oligomer prepared thereby:

##STR00001##

wherein R.sub.0, R.sub.1 to R.sub.4, o, p, q and r are described therein.

A composition contains a mixture of silyl hydride, an alpha-beta unsaturated ester, a Lewis acid catalyst and an amine having the following formula: R.sup.1R.sup.2R.sup.3N; where the nitrogen is not a member of an N═C—N linkage and where each of R.sup.1, R.sup.2, and R.sup.3 is independently selected from a group consisting of hydrogen, alkyl, substituted alkyl, and conjugated moieties; and wherein at least one of R.sup.1, R.sup.2 and R.sup.3 is a conjugated moiety connected to the nitrogen by a conjugated carbon.

A lubricating oil composition for automobile transmissions including a lubricant base oil, and a liquid random copolymer of ethylene and α-olefin, the liquid random copolymer being produced using a specific catalyst, wherein the lubricating oil composition has a kinematic viscosity at 100° C. of 4.0 to 7.5 mm.sup.2/s, and a Brookfield viscosity at −40° C. of 20,000 mPa.Math.s or less, and wherein the lubricant base oil consists of a mineral oil with a kinematic viscosity at 100° C. of 2 to 10 mm.sup.2/s, a viscosity index of 105 or more, and a pour point of −10° C. or lower, and/or a synthetic oil with a kinematic viscosity at 100° C. of 1 to 10 mm.sup.2/s, a viscosity index of 120 or more, and a pour point of −30° C. or lower.

The present invention relates to a process for the functionalization of a rubber polymer comprising reacting the rubber polymer with at least one source of nitrene or carbene, in the presence of a catalyst of formula Tp.sup.xAg, wherein Tp.sup.x represents a hydrotris(pyrazolyl)borate ligand. This process leads to selective rubber functionalization without secondary reactions such as chain scission or cross linking and produces functionalized rubbers with improved compatibilization properties. The invention also refers to the polymer produced therefrom and to uses of said polymer.

Methods of making polyisobutylene and catalyst systems are described. Polyisobutylene compositions and catalyst system compositions are also described. In some embodiments, a method of making a catalyst system includes: providing a support material; calcining the support material; and forming a catalyst system by adding to the support material (a) a mixture comprising BF.sub.3, (b) a mixture comprising BF.sub.3 and a complexing agent, or (c) both. In some embodiments, a method of making a polymer composition includes providing a catalyst system comprising: (a) a support material selected from the group consisting of Al.sub.2O.sub.3, ZrO.sub.2, TiO.sub.2, SnO.sub.2, CeO.sub.2, SiO.sub.2, SiO.sub.2/Al.sub.2O.sub.3, and combinations thereof; and (b) BF.sub.3; providing a feedstock comprising isobutylene; forming a reaction mixture comprising the feedstock and the catalyst system; contacting the isobutylene with the catalyst system; and obtaining a polymer composition.

A method for preparing a pyridine compound substituted with trifluoromethylthio, difluoromethylthio or trifluoromethyl in the meta position is provided, which includes S1. in a glove box filled with nitrogen, adding a catalyst, a solvent, pinacolborane, and pyridine to a reaction flask, stirring the mixture, and performing a reaction at 40-100° C. for 2-12 hours to obtain dihydropyridine; S2. adding a trifluoromethylthio reagent, a difluoromethylthio reagent, or a trifluoromethyl reagent to the reaction flask, stirring the mixture, and performing a reaction at room temperature to 80° C. for 2-12 hours to obtain trifluoromethylthio-, difluoromethylthio- or trifluoromethyl-substituted dihydropyridine; and S3. placing the reaction flask in the air or adding 2,3-dichloro-5,6-dicyanobenzoquinone, stirring same, and performing a reaction at room temperature for 4-12 hours, followed by distillation under reduced pressure to remove the solvent and column chromatography separation to obtain the meta-substituted pyridine compound.

A mixture M includes at least one compound A, selected from (a1) a compound of the general formula (I) and/or (a2) a compound of the general formula (I′), at least one compound B, selected from (b1) a compound of the general formula (II) and/or (b2) a compound of the general formula (II′) and/or (b3) a compound of the general formula (II″), and at least one compound C, selected from cationic germanium(II) compounds of the general formula (III).

The present disclosure provides a method and a catalyst for selective oligomerization of ethylene. The raw material for the catalyst consists of a dehydropyridine annulene-type ligand, a transition metal compound, and an organometallic compound in a molar ratio of 1:0.5-100:0.1-5000. The present disclosure also provides a method for selective oligomerization of ethylene accomplished by using the above-mentioned catalyst. The catalyst for selective oligomerization of ethylene has high catalytic activity, high selectivity for the target products 1-hexene and 1-octene, and low selectivity for 1-butene and 1-C.sub.10.sup.+.

A catalytic system for use in olefinic polymerization, includes titanium, magnesium, a halogen, organoaluminium, and a boron-based electron donor.