A catalyst for inducing thermal desorption of organic matter-contaminated soil and a preparation method thereof, which uses a colloidal mixture of ferroferric oxide and ferric chloride as a catalytic active component of thermal desorption, and carbon tetrachloride as a solvent. Based on the mass of solvent, a mass percentage of catalytic active component is 0.1%-15%. Ammonia water is added dropwise to ferric chloride aqueous solution to react in oil bath to generate a ferroferric oxide colloidal solution, then ferric chloride and obtained ferroferric oxide colloidal solution are added to carbon tetrachloride, and mixed solution is continuously stirred in an oil bath to evaporate solvent water to prepare a catalyst with carbon tetrachloride as solvent. Catalyst is environmentally friendly and can induce thermal desorption of organic matters in soil. 100% desorption of chlorobenzene, o-xylene and benzo[A]anthracene can be achieved at 130° C., and energy consumption of thermal desorption is greatly reduced.

A catalyst for inducing thermal desorption of organic matter-contaminated soil and a preparation method thereof, which uses a colloidal mixture of ferroferric oxide and ferric chloride as a catalytic active component of thermal desorption, and carbon tetrachloride as a solvent. Based on the mass of solvent, a mass percentage of catalytic active component is 0.1%-15%. Ammonia water is added dropwise to ferric chloride aqueous solution to react in oil bath to generate a ferroferric oxide colloidal solution, then ferric chloride and obtained ferroferric oxide colloidal solution are added to carbon tetrachloride, and mixed solution is continuously stirred in an oil bath to evaporate solvent water to prepare a catalyst with carbon tetrachloride as solvent. Catalyst is environmentally friendly and can induce thermal desorption of organic matters in soil. 100% desorption of chlorobenzene, o-xylene and benzo[A]anthracene can be achieved at 130° C., and energy consumption of thermal desorption is greatly reduced.

Provided is a method of generating hydrogen efficiently using a renewable resource as a raw material.

A method of producing hydrogen according to the present disclosure is a method in which hydrogen is generated from a saccharide in the presence of a solvent and the following catalyst: catalyst which contains at least one metal element selected from the metal elements in Groups 8, 9, and 10.

The catalyst is preferably a complex or salt of the metal element, and particularly preferably a complex including the at least one metal element selected from the metal elements in Groups 8, 9, and 10 and at least one ligand selected from pentamethylcyclopentadienyl, cyclopentadienyl, p-cymene, and 1,5-cyclooctadiene.

As the solvent, it is preferable to use at least one selected from an organic acid and an ionic liquid.

The saccharide may be a lignin-saccharide complex, and is preferably cellulose.

The present disclosure relates to an ionic liquid composition and a process for its preparation. The process of the present disclosure is simple, single pot and efficient process for preparing the ionic liquid composition which is effective in a Friedel Craft reaction like, alkylation reaction, trans-alkylation, and acylation. The present disclosure envisages an ionic liquid composition comprising at least one metal hydroxide; at least one metal halide; and at least one solvent. Also envisaged is a process for preparing an ionic liquid composition. The process comprises mixing in a reaction vessel, at least one metal hydroxide and at least one metal halide in the presence of at least one solvent under a nitrogen atmosphere and continuous stirring followed by cooling under continuous stirring to obtain the ionic liquid composition.

The present disclosure relates to an ionic liquid composition and a process for its preparation. The process of the present disclosure is simple, single pot and efficient process for preparing the ionic liquid composition which is effective in a Friedel Craft reaction like, alkylation reaction, trans-alkylation, and acylation. The present disclosure envisages an ionic liquid composition comprising at least one metal hydroxide; at least one metal halide; and at least one solvent. Also envisaged is a process for preparing an ionic liquid composition. The process comprises mixing in a reaction vessel, at least one metal hydroxide and at least one metal halide in the presence of at least one solvent under a nitrogen atmosphere and continuous stirring followed by cooling under continuous stirring to obtain the ionic liquid composition.

The present invention relates to the synthesis of 6-substituted 7-deazapurines and their corresponding nucleosides by coupling aryl or alkyl Grignard reagents with halogenated purine nucleosides in the presence of iron or an iron/copper mixture such as Fe(acac)3/CuI. The present invention also relates to pharmaceutical compositions comprising said compounds and the use of said pharmaceutical compositions to treat or prevent viral infections.

The present invention relates to the synthesis of 6-substituted 7-deazapurines and their corresponding nucleosides by coupling aryl or alkyl Grignard reagents with halogenated purine nucleosides in the presence of iron or an iron/copper mixture such as Fe(acac)3/CuI. The present invention also relates to pharmaceutical compositions comprising said compounds and the use of said pharmaceutical compositions to treat or prevent viral infections.

Pt-thixantphos-iodine complex and Pt-thixantphos-bromine complex, and the use thereof for catalysis of a hydroformylation reaction.

Pt-thixantphos-iodine complex and Pt-thixantphos-bromine complex, and the use thereof for catalysis of a hydroformylation reaction.

Process for hydroformylation of olefins using Pt and thixantphos.