The invention relates to noble metal-oxo clusters represented by the formula [M.sub.s(R.sub.2XO.sub.2).sub.z(OR′).sub.xO.sub.yX′.sub.q] or solvates thereof, corresponding supported noble metal-oxo clusters, and processes for their preparation, as well as corresponding metal cluster units, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in conversion of organic substrate.

The invention relates to noble metal-oxo clusters represented by the formula [M.sub.s(R.sub.2XO.sub.2).sub.z(OR′).sub.xO.sub.yX′.sub.q] or solvates thereof, corresponding supported noble metal-oxo clusters, and processes for their preparation, as well as corresponding metal cluster units, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in conversion of organic substrate.

A method for producing an olefin oligomer is disclosed, in which an olefin oligomerization reaction is performed in the presence of an olefin oligomerization catalyst comprising (A) a chromium compound, (B) an amine compound of the general formula (1): ##STR00001##
(R.sup.1 to R.sup.4 represent a group such as a hydrocarbon group, Y represents a structure represented by —CR.sup.5R.sup.6—, R.sup.5 and R.sup.6 represent a group such as a hydrogen atom, and Z represents an integer of 1 to 10),
and (C) a compound such as an organometal compound; and the olefin oligomerization catalyst.

A method for producing an olefin oligomer is disclosed, in which an olefin oligomerization reaction is performed in the presence of an olefin oligomerization catalyst comprising (A) a chromium compound, (B) an amine compound of the general formula (1): ##STR00001##
(R.sup.1 to R.sup.4 represent a group such as a hydrocarbon group, Y represents a structure represented by —CR.sup.5R.sup.6—, R.sup.5 and R.sup.6 represent a group such as a hydrogen atom, and Z represents an integer of 1 to 10),
and (C) a compound such as an organometal compound; and the olefin oligomerization catalyst.

A supported catalyst and preparation method thereof, the catalyst comprising an organic polymer material carrier and Raney alloy particles supported on the organic polymer material carrier, wherein substantially all of the Raney alloy particles are partially embedded in the organic polymer material carrier. The catalyst can be used in hydrogenation, dehydrogenation, amination, dehalogenation or desulfuration reactions.

A supported catalyst and preparation method thereof, the catalyst comprising an organic polymer material carrier and Raney alloy particles supported on the organic polymer material carrier, wherein substantially all of the Raney alloy particles are partially embedded in the organic polymer material carrier. The catalyst can be used in hydrogenation, dehydrogenation, amination, dehalogenation or desulfuration reactions.

A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.

A method comprising a) contacting a solvent, a carboxylic acid, and a peroxide-containing compound to form an acidic mixture wherein a weight ratio of solvent to carboxylic acid in the acidic mixture is from about 1:1 to about 100:1; b) contacting a titanium-containing compound and the acidic mixture to form a solubilized titanium mixture wherein an equivalent molar ratio of titanium-containing compound to carboxylic acid in the solubilized titanium mixture is from about 1:1 to about 1:4 and an equivalent molar ratio of titanium-containing compound to peroxide-containing compound in the solubilized titanium mixture is from about 1:1 to about 1:20; and c) contacting a chromium-silica support comprising from about 0.1 wt. % to about 20 wt. % water and the solubilized titanium mixture to form an addition product and drying the addition product by heating to a temperature in a range of from about 50° C. to about 150° C. and maintaining the temperature in the range of from about 50° C. to about 150° C. for a time period of from about 30 minutes to about 6 hours to form a pre-catalyst.

A visible-light-photocatalyzed composite light-transmitting concrete contains several bundles of optical fibers, the optical fibers are coated with a protective layer on their outer surface, the protective layer contains a visible light photocatalyst, and the concrete has several gas-permeable pores. Such concrete is prepared by mixing a visible light photocatalyst and a light-transmitting glue, applying the mixture to the surface of optical fibers to form a protective layer, and using optical fibers in the concrete. The resulting concrete has dual properties of light transmittance and photocatalytic oxidation of gas-phase pollutants under visible light irradiation. The visible-light-photocatalyzed composite light-transmitting concrete significantly breaks through the limitation of photocatalytic concrete to light sources, so that gas-phase pollutants can be removed under visible light irradiation through photocatalysis of light-transmitting concrete. It also has good mechanical properties, decorativeness, and functional practicability due to coated optical fibers.

A visible-light-photocatalyzed composite light-transmitting concrete contains several bundles of optical fibers, the optical fibers are coated with a protective layer on their outer surface, the protective layer contains a visible light photocatalyst, and the concrete has several gas-permeable pores. Such concrete is prepared by mixing a visible light photocatalyst and a light-transmitting glue, applying the mixture to the surface of optical fibers to form a protective layer, and using optical fibers in the concrete. The resulting concrete has dual properties of light transmittance and photocatalytic oxidation of gas-phase pollutants under visible light irradiation. The visible-light-photocatalyzed composite light-transmitting concrete significantly breaks through the limitation of photocatalytic concrete to light sources, so that gas-phase pollutants can be removed under visible light irradiation through photocatalysis of light-transmitting concrete. It also has good mechanical properties, decorativeness, and functional practicability due to coated optical fibers.