This disclosure relates to processes for converting saturated polyethylene to at least an alkene product. The processes comprise contacting the saturated polyethylene with three or more catalyst components in a reactor, the reactor comprising an alkene reactant. The three or more catalyst components comprise a metathesis catalyst component, an isomerization catalyst component, and a dehydrogenation catalyst component. Contacting causes at least a portion of the saturated polyethylene to undergo dehydrogenation reactions to form unsaturated polyethylene and at least a portion of the unsaturated polyethylene, or products derived therefrom, to undergo metathesis reactions and isomerization reactions to produce an effluent comprising at least the alkene product.

An emission control device for a vehicle, which includes an open cell carbon foam substrate having a geometric surface area of at least about 5000 m.sup.2/m.sup.3, wherein the substrate has a catalytic metal.

A hydrocarbon adsorbent, according to one embodiment of the present invention, comprises a copper-containing ZSM-5 zeolite, wherein a Si/Al molar ratio of the ZSM-5 zeolite may be 11.5 to 40, and the amount of the copper included is 1 wt % to 10 wt %.

A substrate for a catalytic converter, comprising an open cell carbon foam having a geometric surface area of at least about 5000 m.sup.2/m.sup.3 and a permeability of at least about 8.0 darcys.

A substrate for a catalytic converter, comprising an open cell carbon foam having a geometric surface area of at least about 5000 m.sup.2/m.sup.3 and a permeability of at least about 8.0 darcys.

A substrate for a catalytic converter, comprising an open cell carbon foam having a geometric surface area of at least about 5000 m.sup.2/m.sup.3 and a permeability of at least about 8.0 darcys.

The present invention provides a porous metal-containing carbon-based material that is stable at high temperatures under aqueous conditions. The porous metal-containing carbon-based materials are particularly useful in catalytic applications. Also provided, are methods for making and using porous shaped metal-carbon products prepared from these materials.

Described herein are methods of making the visible light photocatalysts without the use of templates that can comprise: (1) mixing a metal precursor, an alcohol, and a solvent to form a self assembled shapes at a temperature between the freezing point of the solvent and the boiling point of the solvent, (2) strengthening the shapes at a temperature of about 35 C. to about 300 C. for about 30 minutes to about 96 hours, and then (3) annealing the shapes at a temperature of between about 450 C. to about 750 C. for between about 4 hours to about 16 hours in a gaseous atmosphere. Also described are photocatalysts created by the described methods.

Catalytic articles comprising a substrate having a catalytic coating thereon, the catalytic coating comprising a catalytic layer having a thickness and an inner surface proximate to the substrate and an outer surface distal to the substrate; where the catalytic layer comprises a noble metal component on support particles and where the concentration of the noble metal component towards the outer surface is greater than the concentration towards the inner surface are highly effective towards treating exhaust gas streams of internal combustion engines. The articles are prepared via a method comprising providing a first mixture comprising micron-scaled support particles and applying the first mixture to a substrate to form a micro-particle layer; providing a second mixture comprising nano-scaled support particles and a noble metal component having an initial pH and applying the second mixture to the micro-particle layer and calcining the substrate.

A hydrocarbon adsorbent, according to one embodiment of the present invention, comprises a copper-containing ZSM-5 zeolite, wherein a Si/Al molar ratio of the ZSM-5 zeolite may be 11.5 to 40, and the amount of the copper included is 1 wt % to 10 wt %.