This disclosure relates to processes for converting saturated polyethylene to at least an alkene product. The processes comprise contacting the saturated polyethylene with three or more catalyst components in a reactor, the reactor comprising an alkene reactant. The three or more catalyst components comprise a metathesis catalyst component, an isomerization catalyst component, and a dehydrogenation catalyst component. Contacting causes at least a portion of the saturated polyethylene to undergo dehydrogenation reactions to form unsaturated polyethylene and at least a portion of the unsaturated polyethylene, or products derived therefrom, to undergo metathesis reactions and isomerization reactions to produce an effluent comprising at least the alkene product.

Provided is a refining apparatus of a waste plastic pyrolysis oil including a reactor where a waste plastic pyrolysis oil is introduced and hydrotreated, wherein the reactor includes Area 1 including a hydrotreating catalyst having a Mo content of 1 to 15 wt % with respect to the total weight; and Area 2 including a hydrotreating catalyst having a Mo content of 5 to 40 wt % and a Ni or Co content of 4 to 50 wt % with respect to the total weight, and the waste plastic pyrolysis oil is refined by passing through Area 1 and Area 2 sequentially.

A process of producing a catalyst comprises forming mesoporous beta zeolite particles, impregnating mesoporous beta zeolite particles with a metal and phosphorus to produce a metal and phosphorus impregnated zeolite, and incorporating the metal and phosphorus impregnated zeolite with clay and alumina to produce the catalyst. The forming step comprises converting a crystalline beta zeolite to a non-crystalline material with reduced silica content relative to the crystalline beta zeolite, and crystalizing the non-crystalline material to produce mesoporous beta zeolite particles.

Disclosed is a process for converting methane into value-added compounds. In this process, a gas mixture containing hydrogen as well as high-concentration acetylene formed through methane pyrolysis (e.g. non-oxidative coupling of methane) is selectively hydrogenated in the presence of a bimetallic supported catalyst. This process obtains ethylene from acetylene in the gas mixture while unreacted methane and hydrogen are recovered as byproducts and/or additionally recycled.

Methods for making a supported chromium catalyst are disclosed, and can comprise contacting a silica-coated alumina containing at least 30 wt. % silica with a chromium-containing compound in a liquid, drying, and calcining in an oxidizing atmosphere at a peak temperature of at least 650 C. to form the supported chromium catalyst. The supported chromium catalyst can contain from 0.01 to 20 wt. % chromium, and typically can have a pore volume from 0.5 to 2 mL/g and a BET surface area from 275 to 550 m.sup.2/g. The supported chromium catalyst subsequently can be used to polymerize olefins to produce, for example, ethylene-based homopolymers and copolymers having high molecular weights and broad molecular weight distributions.

The present invention relates to a stoichiometric-combustion spark-ignition engine comprising a specific exhaust gas system for reducing harmful exhaust gases resulting from the combustion process. The exhaust gas system consists in the through-flow direction of a three-way catalytic converter close to the engine, an oxidation catalyst and a gasoline particulate filter.

The present invention relates to a catalyst for selective hydrodesulphurization of cracked naphtha streams in the form of an extrudate, which comprises a support based on an inorganic oxide and an outer layer bound to the support, wherein the outer layer comprises desulphurization metals dispersed therein forming a crown, the desulphurization metals being cobalt and molybdenum. The present invention also relates to the preparation of said catalyst by the incipient wetness impregnation method and to the process for selective hydrodesulphurization of cracked naphtha employing same.

This disclosure generally relates to an oxide composition basically composed of cerium and zirconium that has exceptional and stable porosity, surface area and lattice oxygen mobility. The oxide composition can contain one or more other rare earth oxides other than cerium oxide. For example, some compositions can contain one or more of lanthanum oxide, yttrium oxide and neodymium oxide. The oxide composition can be useful as a catalyst, catalyst support, sensor applications and combinations thereof.

A process for preparing a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW, comprising (i) providing a molding comprising a titanium-containing zeolitic material having framework type MWW; (ii) preparing an aqueous suspension comprising a zinc source and the molding comprising a titanium-containing zeolitic material having framework type MWW prepared in (i); (iii) heating the aqueous suspension prepared in (ii) under autogenous pressure to a temperature of the liquid phase of the aqueous suspension in the range of from 100 to 200 C., obtaining an aqueous suspension comprising a molding comprising zinc and a titanium-containing zeolitic material having framework type MWW; (iv) separating the molding comprising zinc and a titanium-containing zeolitic material having framework type MWW from the liquid phase of the suspension obtained in (iii).

Catalyst compositions comprising a zeolite and a mesoporous support or binder are disclosed. The mesoporous support or binder comprises a mesoporous metal oxide having a particle diameter of greater than or equal to 20 m at 50% of the cumulative pore size distribution (d50). Also disclosed are processes for producing a mono-alkylated aromatic compound (e.g., ethylbenzene or cumene) which exhibit improved yield of the mono-alkylated aromatic compound using alkylation catalysts comprising one or more of these catalyst compositions.