B01J35/73

CONVERSION OF BETA-HYDROXY CARBONYL SPECIES AND PREPARATION OF AMINO ALCOHOL PRECURSOR USING BIFUNCTIONAL CATALYSTS DERIVED FROM LAYERED DOUBLE HYDROXIDES
20240261765 · 2024-08-08 ·

Disclosed are methods for conversion of ?-hydroxy carbonyl species and preparation of amino alcohol precursor using bifunctional catalysts derived from layer double hydroxides. By the bifunctional catalyst, the abundant basic sites on HTO allow retro-aldol condensation to outpace direct hydrogenation, thus achieving an exceptional selectivity towards a desired product produced through retro-aldol condensation and then hydrogenation. Accordingly, this method exhibits particular utility in the renewable production of N-acetylethanolamine from biomass-derived N-acetyl glucosamine (GlcNAc) without using homogeneous base as a co-catalyst.

CONVERSION OF BETA-HYDROXY CARBONYL SPECIES AND PREPARATION OF AMINO ALCOHOL PRECURSOR USING BIFUNCTIONAL CATALYSTS DERIVED FROM LAYERED DOUBLE HYDROXIDES
20240261765 · 2024-08-08 ·

Disclosed are methods for conversion of ?-hydroxy carbonyl species and preparation of amino alcohol precursor using bifunctional catalysts derived from layer double hydroxides. By the bifunctional catalyst, the abundant basic sites on HTO allow retro-aldol condensation to outpace direct hydrogenation, thus achieving an exceptional selectivity towards a desired product produced through retro-aldol condensation and then hydrogenation. Accordingly, this method exhibits particular utility in the renewable production of N-acetylethanolamine from biomass-derived N-acetyl glucosamine (GlcNAc) without using homogeneous base as a co-catalyst.

Catalyst for selective hydrogenation of dienes, preparation method and application thereof

A mixed metal oxide catalyst for selective hydrogenation of dienes comprising a Group VIII metal, a trivalent metal, a Group IA metal, a Group IVB metal, a Group IIB metal, two Group VIB metals and SiO.sub.2Al.sub.2O.sub.3 as balance. The catalyst comprises 10-40 wt % of Group VIII metal, 5-30 wt % of trivalent metal, 0.1-8 wt % of Group IA metal, 0.1-8 wt % of Group IVB metal, 0.1-30 wt % of Group IIB metal, 5-50 wt % of two Group VIB metals and 10-30 wt % of SiO.sub.2Al.sub.2O.sub.3, based on the catalyst in terms of oxide, and has 150-300 m.sup.2/g of specific surface area, 0.4-0.8 ml/g of pore volume.

Preparing layered double hydroxide nanostructures
09656877 · 2017-05-23 ·

Provided is a method for manufacturing nanostructured layered double hydroxides (LDHs) having a uniform size distribution with homogenous nano-disc morphology. Disclosed method has three main steps of: pretreatment of metal wires; wire-explosion in a liquid phase; and finally, centrifugation and drying the as-prepared colloidal products to obtain the LDHs nanostructured dried powder.

Hydroxide catalysts for lignin depolymerization

Solid base catalysts and their use for the base-catalyzed depolymerization (BCD) of lignin to compounds such as aromatics are presented herein. Exemplary catalysts include layered double hydroxides (LDHs) as recyclable, heterogeneous catalysts for BCD of lignin.

METHODS OF MAKING AND USING LAYERED COBALT NANO-CATALYSTS

A method of making LDO-Co nanoparticles is described herein. A method of using LDO-Co nanoparticles, particularly in the treatment of wastewater, is described herein.

NOx storage materials and traps resistant to thermal aging
09540980 · 2017-01-10 · ·

Nitrogen oxide storage catalysts comprising a substrate and at least two coating layers, where the second layer is substantially free of platinum, cerium and barium, and methods of manufacturing and using these nitrogen oxide storage catalysts are disclosed.

CIT-10: A TWO DIMENSIONAL LAYERED CRYSTALLINE MICROPOROUS SILICATE COMPOSITION AND COMPOSITIONS DERIVED THEREFROM
20170001872 · 2017-01-05 ·

This disclosure relates to a new crystalline microporous silicate solid, designated CIT-10, comprising a two dimensional layered structure, having an organic interlayer sandwiched between individual crystalline silicate layers. This CIT-10 material can be converted to a pure-silicate of RTH topology, as well as two new of pillared silicate structures, designated CIT-11 and CIT-12. This disclosure characterizes new materials and provides methods of preparing and using these new crystalline microporous solids.

Sintered body, method for producing same, and dielectric composition

A sintered body containing polycrystalline grains of a metal oxynitride containing at least two metal elements, wherein Ba and at least one metal element of a crystal phase of the sintered body are contained in a triple point that is not a void between the polycrystalline grains. A method for producing the sintered body includes sintering a mixture of at least a metal oxynitride as a main component and a sintering aid containing cyanamide in an atmosphere containing nitrogen or a rare gas or in a reduced-pressure atmosphere of 10 Pa or less while applying a mechanical pressure with a retention time at a maximum heating temperature during the sintering set to 1 minute to 10 minutes.

Sintered body, method for producing same, and dielectric composition

A sintered body containing polycrystalline grains of a metal oxynitride containing at least two metal elements, wherein Ba and at least one metal element of a crystal phase of the sintered body are contained in a triple point that is not a void between the polycrystalline grains. A method for producing the sintered body includes sintering a mixture of at least a metal oxynitride as a main component and a sintering aid containing cyanamide in an atmosphere containing nitrogen or a rare gas or in a reduced-pressure atmosphere of 10 Pa or less while applying a mechanical pressure with a retention time at a maximum heating temperature during the sintering set to 1 minute to 10 minutes.