B01J38/22

Method and system for biomass hydrogasification

The present invention provides a system and method for producing hydrocarbons from biomass. The method is particularly useful for producing substitute natural gas from forestry residues. Certain disclosed embodiments convert a biomass feedstock into a product hydrocarbon by fast pyrolysis. The resulting pyrolysis gas is converted to the product hydrocarbon and carbon dioxide in the presence of hydrogen and steam while simultaneously generating the required hydrogen by reaction with steam under prescribed conditions for self-sufficiency of hydrogen. Methane is a preferred hydrocarbon product. A system also is disclosed for cycling the catalyst between steam reforming, methanation and regeneration zones.

Method and system for biomass hydrogasification

The present invention provides a system and method for producing hydrocarbons from biomass. The method is particularly useful for producing substitute natural gas from forestry residues. Certain disclosed embodiments convert a biomass feedstock into a product hydrocarbon by fast pyrolysis. The resulting pyrolysis gas is converted to the product hydrocarbon and carbon dioxide in the presence of hydrogen and steam while simultaneously generating the required hydrogen by reaction with steam under prescribed conditions for self-sufficiency of hydrogen. Methane is a preferred hydrocarbon product. A system also is disclosed for cycling the catalyst between steam reforming, methanation and regeneration zones.

EFFICIENT PROCESS FOR CONVERTING METHANOL TO GASOLINE

Systems and methods are provided for the conversion of methanol to gasoline. Such methods may be performed be the sequential conversion of methanol to dimethyl ether, the conversion of dimethyl ether (and unconverted methanol, if present) to an intermediate olefin-rich product, and the oligomerization of the olefin-rich product to gasoline boiling range hydrocarbons.

EFFICIENT PROCESS FOR CONVERTING METHANOL TO GASOLINE

Systems and methods are provided for the conversion of methanol to gasoline. Such methods may be performed be the sequential conversion of methanol to dimethyl ether, the conversion of dimethyl ether (and unconverted methanol, if present) to an intermediate olefin-rich product, and the oligomerization of the olefin-rich product to gasoline boiling range hydrocarbons.

Regenerator for catalysts

The present invention concerns a moving bed catalyst regenerator (1) comprising a vessel (2) extending in a vertical direction, said vessel being divided into at least two regeneration zones extending along the vertical height of said vessel, in which particles of catalyst move under gravity, the regenerator being configured such that each regeneration zone is capable of separately regenerating a different composition of catalyst and in which each regeneration zone comprises, in succession and in the order in which the catalysts move: a) a combustion section (CO); b) an oxychlorination section (O) disposed below the combustion section and comprising means for bringing catalyst from the combustion section (CO) to the oxychlorination section (O); c) a calcining section (CA) disposed below the oxychlorination section.

Regenerator for catalysts

The present invention concerns a moving bed catalyst regenerator (1) comprising a vessel (2) extending in a vertical direction, said vessel being divided into at least two regeneration zones extending along the vertical height of said vessel, in which particles of catalyst move under gravity, the regenerator being configured such that each regeneration zone is capable of separately regenerating a different composition of catalyst and in which each regeneration zone comprises, in succession and in the order in which the catalysts move: a) a combustion section (CO); b) an oxychlorination section (O) disposed below the combustion section and comprising means for bringing catalyst from the combustion section (CO) to the oxychlorination section (O); c) a calcining section (CA) disposed below the oxychlorination section.

Regenerator for regenerating catalysts under different operating conditions

The present invention concerns a moving bed catalyst regenerator (1) comprising a vessel (2) extending in a vertical direction, said vessel being divided into at least two regeneration zones extending along the vertical height of said vessel, in which particles of catalyst move under gravity, in which each regeneration zone comprises, in succession and in the order in which the catalysts move: a) a combustion section (CO); b) an oxychlorination section (O) disposed below the combustion section and comprising means for bringing catalyst from the combustion section (CO) to the oxychlorination section (O); c) a calcining section (CA) disposed below the oxychlorination section; characterized in that the regeneration zones are separated from each other by a separation means which is impermeable to catalysts and to gases in a manner such that the catalysts of each of the zones are capable of being regenerated under different operating conditions.

Regenerator for regenerating catalysts under different operating conditions

The present invention concerns a moving bed catalyst regenerator (1) comprising a vessel (2) extending in a vertical direction, said vessel being divided into at least two regeneration zones extending along the vertical height of said vessel, in which particles of catalyst move under gravity, in which each regeneration zone comprises, in succession and in the order in which the catalysts move: a) a combustion section (CO); b) an oxychlorination section (O) disposed below the combustion section and comprising means for bringing catalyst from the combustion section (CO) to the oxychlorination section (O); c) a calcining section (CA) disposed below the oxychlorination section; characterized in that the regeneration zones are separated from each other by a separation means which is impermeable to catalysts and to gases in a manner such that the catalysts of each of the zones are capable of being regenerated under different operating conditions.

Regeneration device, device for preparing low-carbon olefins, and use thereof

A regeneration device, a device for preparing low-carbon olefins, and a use thereof are provided. The regeneration device includes a first regenerator and a second regenerator; a first activation zone of the first regenerator is connected to the second regenerator through a pipeline, such that a catalyst in the first activation zone is able to be delivered to the second regenerator; and the second regenerator is connected to a gas-solid separation zone of the first regenerator through a pipeline, such that a catalyst in the second regenerator is able to be delivered to the gas-solid separation zone. The regeneration device can adjust the coke content, coke content distribution, and coke species in a dimethyl ether/methanol to olefins (DMTO) catalyst to control an operation window of the DMTO catalyst, which improves the selectivity for low-carbon olefins and the atomic economy of a methanol-to-olefins (MTO) technology.

Regeneration device, device for preparing low-carbon olefins, and use thereof

A regeneration device, a device for preparing low-carbon olefins, and a use thereof are provided. The regeneration device includes a first regenerator and a second regenerator; a first activation zone of the first regenerator is connected to the second regenerator through a pipeline, such that a catalyst in the first activation zone is able to be delivered to the second regenerator; and the second regenerator is connected to a gas-solid separation zone of the first regenerator through a pipeline, such that a catalyst in the second regenerator is able to be delivered to the gas-solid separation zone. The regeneration device can adjust the coke content, coke content distribution, and coke species in a dimethyl ether/methanol to olefins (DMTO) catalyst to control an operation window of the DMTO catalyst, which improves the selectivity for low-carbon olefins and the atomic economy of a methanol-to-olefins (MTO) technology.