A system and method for water purification by capture of contaminants in an aqueous mixture is described herein. A system and method for regenerating the capture system is also described. An integrated capture and regeneration system and method is also described including a separation vessel that houses a capture bed and optionally an electrode in electrical contact with the bed with a power source for applying a voltage to the electrode. The applied voltage enhances capture of the contaminant from aqueous liquid on the capture bed and modulation of the applied voltage enhances release of contaminant on the capture bed into aqueous wash liquid to regenerate the bed. The aqueous wash liquid may contain a counter ion that binds to the contaminant forming an aggregate contaminant phase that separates from the aqueous wash liquid.

A system and method for water purification by capture of contaminants in an aqueous mixture is described herein. A system and method for regenerating the capture system is also described. An integrated capture and regeneration system and method is also described including a separation vessel that houses a capture bed and optionally an electrode in electrical contact with the bed with a power source for applying a voltage to the electrode. The applied voltage enhances capture of the contaminant from aqueous liquid on the capture bed and modulation of the applied voltage enhances release of contaminant on the capture bed into aqueous wash liquid to regenerate the bed. The aqueous wash liquid may contain a counter ion that binds to the contaminant forming an aggregate contaminant phase that separates from the aqueous wash liquid.

A quaternary ammonium group-grafted cation resin and a preparation method thereof are provided. The preparation method includes: adding a chloromethylated cross-linked polystyrene (PS) resin, trimethylamine hydrochloride, and a 20% sodium hydroxide aqueous solution successively to a reactor for a reaction under stirring at 30° C. to 40° C.; filtering a resulting reaction solution, followed by washing and drying to obtain a quaternary ammonium group-grafted resin; adding the quaternary ammonium group-grafted resin, 1,2-dichloroethane, silver sulfate, concentrated sulfuric acid, and fuming sulfuric acid successively for a reaction for 1 hour at 50° C. to 60° C., a reaction for 1 hour at 70° C. to 80° C., and a reaction for 5 hours at 115° C. to 125° C.; and cooling a resulting reaction solution to room temperature, followed by diluting, filtering, washing and drying to obtain the quaternary ammonium group-grafted cation resin.

A quaternary ammonium group-grafted cation resin and a preparation method thereof are provided. The preparation method includes: adding a chloromethylated cross-linked polystyrene (PS) resin, trimethylamine hydrochloride, and a 20% sodium hydroxide aqueous solution successively to a reactor for a reaction under stirring at 30° C. to 40° C.; filtering a resulting reaction solution, followed by washing and drying to obtain a quaternary ammonium group-grafted resin; adding the quaternary ammonium group-grafted resin, 1,2-dichloroethane, silver sulfate, concentrated sulfuric acid, and fuming sulfuric acid successively for a reaction for 1 hour at 50° C. to 60° C., a reaction for 1 hour at 70° C. to 80° C., and a reaction for 5 hours at 115° C. to 125° C.; and cooling a resulting reaction solution to room temperature, followed by diluting, filtering, washing and drying to obtain the quaternary ammonium group-grafted cation resin.

A softening apparatus in which resistance applied between electrodes is decreased to reduce power consumption. The softening apparatus includes a regeneration unit and a softening unit. The regeneration unit includes at least one anode and cathode in a first space which generate regeneration water containing hydrogen ions (H+). The softening unit is disposed in a second space partitioned from the first space and includes an ion exchange body regenerated by the regeneration water.

A softening apparatus in which resistance applied between electrodes is decreased to reduce power consumption. The softening apparatus includes a regeneration unit and a softening unit. The regeneration unit includes at least one anode and cathode in a first space which generate regeneration water containing hydrogen ions (H+). The softening unit is disposed in a second space partitioned from the first space and includes an ion exchange body regenerated by the regeneration water.

The present invention relates to a water softening device including: a resin chamber which has an ion exchange resin and softens hard water passing through the ion exchange resin; and electrodes which are arranged by placing the resin chamber therebetween and apply voltages to the resin chamber so as to soften the hard water, and which regenerates the ion exchange resin, wherein the ion exchange resin is a slightly acidic cation exchange resin and/or a weakly alkaline anion exchange resin. The present invention provides the water softening device capable of easily regenerating the ion exchange resin and repeating the softening-regenerating without using chemicals or the like while maintaining the performance of softening water, thereby enabling a continuous use thereof.

A method for conditioning of spent ion exchange resins from nuclear facilities comprises the steps of: mixing the spent ion exchange resins with water to form a reaction mixture; setting and controlling the pH of the reaction mixture in a range from 1.0 to 3.5, preferably in a range from 2.0 to 3.0; adding an oxidant to the reaction mixture, with the temperature of the reaction mixture maintained at 90 ° ° C. or less so that the spent ion exchange resin and the oxidant react with each other to form an aqueous reaction solution comprising the organic reaction products of the spent ion exchange resin; and electrochemically oxidizing the organic reaction products, wherein carbon dioxide is produced and a carbon-depleted aqueous reaction solution having a TOC (total organic carbon) value of less than 50 ppm is obtained. Furthermore, an apparatus for the conditioning of spent ion exchange resins from nuclear facilities is described.

A method for conditioning of spent ion exchange resins from nuclear facilities comprises the steps of: mixing the spent ion exchange resins with water to form a reaction mixture; setting and controlling the pH of the reaction mixture in a range from 1.0 to 3.5, preferably in a range from 2.0 to 3.0; adding an oxidant to the reaction mixture, with the temperature of the reaction mixture maintained at 90 ° ° C. or less so that the spent ion exchange resin and the oxidant react with each other to form an aqueous reaction solution comprising the organic reaction products of the spent ion exchange resin; and electrochemically oxidizing the organic reaction products, wherein carbon dioxide is produced and a carbon-depleted aqueous reaction solution having a TOC (total organic carbon) value of less than 50 ppm is obtained. Furthermore, an apparatus for the conditioning of spent ion exchange resins from nuclear facilities is described.

A deionization device is for at least partially deionizing a feed liquid in which at least one electrolyte is dissolved. The device has at least one process channel with a feed inlet for receiving the feed liquid, and a feed outlet; one or more collector channel(s) for collecting the anions and cations separated from the feed liquid; an electrolyte outlet for discharging the collected anions and cations; and at least one channel electrode, at least one separating electrode, and at least one collector electrode. The channel and separating electrodes are placed at opposite sides of the process channel, and the separating and collector electrodes are placed at opposite sides of the collector channel(s). A field generator generates an electric and/or magnetic field between the channel and separating electrodes, and between the separating and collector electrodes, to generate an ion flow from the process to the collector channel(s), which is the same for anions and cations.