A composite medium for collecting mineral particles in an aqueous slurry has a polymer substrate deposited or penetrated with an inorganic material and further coated with a hydrophobic material. The hydrophobic material can be a hydrophobic silane or a hydrophobic polymer such as polysiloxane. Alternatively, the inorganic material deposited substrate is first reacted with a reactive silane and then coated with a hydrophobic polymer. The polymer substrate can be in the form of a spherical bead, a small cube, a filter or a conveyor.

A composite medium for collecting mineral particles in an aqueous slurry has a polymer substrate deposited or penetrated with an inorganic material and further coated with a hydrophobic material. The hydrophobic material can be a hydrophobic silane or a hydrophobic polymer such as polysiloxane. Alternatively, the inorganic material deposited substrate is first reacted with a reactive silane and then coated with a hydrophobic polymer. The polymer substrate can be in the form of a spherical bead, a small cube, a filter or a conveyor.

The disclosure relates to mineral processing, and more particularly to a copper(II)-ammonia complex ion sulfidization activator, and its preparation and application. A molar ratio of NH.sub.3 to Cu.sup.2+ in the active ingredient of the copper(II)-ammonia complex ion sulfidization activator is 2:1-4:1. The preparation method includes: dropwise adding an ammonia solution to a copper salt solution; and adjusting the mixture to pH 6-7.2 with dilute sulfuric acid to obtain the copper(II)-ammonia complex ion sulfidization activator. During the sulfidization flotation for the copper oxide ore, the copper(II)-ammonia complex ion sulfidization activator is added and mixed uniformly with the ore slurry prior to the introduction of the sulfidizing agent.

A hydrometallurgical method for simultaneously extracting zinc, lead, silver, iron and calcium from electric arc furnace dust (hazardous waste) produced by the steelmaking industry (steelworks), in the form of industrial products: zinc as zinc sulphate or zinc cathodes; lead and silver as a concentrate of lead and silver; iron as reduced elemental iron for return to the electric arc furnace; and, lastly, calcium as gypsum, without solid waste or liquid effluents being generated relates to the chemical nature of the electric arc furnace dust (complex oxides) changes to a sulfide complex, and eliminating the hazards associated with the generation of fugitive heavy-metal salts. In addition, the hydrometallurgical problem of low recovery of zinc and iron is solved. Consequently, hydrometallurgy is made easier and more environmentally friendly, as condensed water is used as a leachate, the condensed water being continuously regenerated by vacuum evaporation systems without generating effluents.

Apparatus is providing featuring a synthetic bead having a solid-phase body with a surface, and being configured with a predetermined electric charge so as to respond to a corresponding predetermined electric field; and a plurality of molecules attached to at least part of the surface, the molecules comprising a functional group selected for attracting and attaching one or more mineral particles of interest to the molecules. Some combination of the solid-phase body or the surface may be configured from a polymer. The polymer may be polyethylenimine. The polyethylenimine may be engineered or configured to be highly charged so as to be used to collect the mineral particles of interest and then manipulated through and by the corresponding predetermined electric field.

Apparatus is providing featuring a synthetic bead having a solid-phase body with a surface, and being configured with a predetermined electric charge so as to respond to a corresponding predetermined electric field; and a plurality of molecules attached to at least part of the surface, the molecules comprising a functional group selected for attracting and attaching one or more mineral particles of interest to the molecules. Some combination of the solid-phase body or the surface may be configured from a polymer. The polymer may be polyethylenimine. The polyethylenimine may be engineered or configured to be highly charged so as to be used to collect the mineral particles of interest and then manipulated through and by the corresponding predetermined electric field.

A flocculant, according to embodiments of the present disclosure, includes a core nanoparticle and at least one positively charged functional group on a surface of the core nanoparticle. The nanoparticle may comprise a silica, alumina, titania, iron oxide, iron nitride, iron carbide, or a carbon-based nanoparticle. The flocculant may be used, in a method of bitumen recovery, to neutralize and agglomerate bitumen droplets and/or mineral particles derived from oil sands ore. The bitumen droplets agglomerate about the core nanoparticle of the flocculant to form bitumen flocs, while the mineral particles agglomerate about the core nanoparticle of the flocculant to form mineral flocs. The buoyant bitumen flocs may then separate from the dense mineral flocs to enable high-yield recovery of bitumen from oil sands.

A flocculant, according to embodiments of the present disclosure, includes a core nanoparticle and at least one positively charged functional group on a surface of the core nanoparticle. The nanoparticle may comprise a silica, alumina, titania, iron oxide, iron nitride, iron carbide, or a carbon-based nanoparticle. The flocculant may be used, in a method of bitumen recovery, to neutralize and agglomerate bitumen droplets and/or mineral particles derived from oil sands ore. The bitumen droplets agglomerate about the core nanoparticle of the flocculant to form bitumen flocs, while the mineral particles agglomerate about the core nanoparticle of the flocculant to form mineral flocs. The buoyant bitumen flocs may then separate from the dense mineral flocs to enable high-yield recovery of bitumen from oil sands.

A method is provided for using flotation techniques for separating rare earth metal compounds from bastnaesite ore. The method can include grinding the ore to obtain an aqueous slurry of particles, adding a depressant agent to the slurry and adjusting the pH to a suitable value for the flotation process, adding a collector mixture to the slurry that includes at least one hydroxamic acid, and adding a frother agent to the slurry, followed by subjecting the slurry to froth flotation.

The disclosure is directed to a sulfidizing agent obtainable by mixing M.sub.yS.sub.x and ZSH in a weight ratio of from about 90:10 to about 10:90, wherein M is chosen from Li.sup.+, Na.sup.+, K.sup.+, Rb.sup.+, Cs.sup.+, NH.sub.4.sup.+, Mg.sup.2+ and Ca.sup.2+, y is about 1 or about 2, x is from about 1.1 to about 5, and Z is independently chosen from Li.sup.+, Na.sup.+, K.sup.+, Rb.sup.+, Cs.sup.+ and NH.sub.4.sup.+, and a process for using the sulfidizing agent in the recovery of one or more metal ores and/or polymetallic minerals from gangue.