A valve structure A of an accumulator sprayer X provided with a cylinder body portion B having a main cylinder portion B1 and a sub-cylinder portion B2, and a cover portion C that is attached to cover the cylinder body portion B, wherein; the accumulator sprayer X sucks up liquid in a container J through a first valve FV to the main cylinder portion B1, pressurizes the liquid and spraying the liquid from a nozzle portion F when the pressure of the liquid reaches a certain pressure; and the valve structure A comprises a spring portion and a valve piston portion, wherein the valve piston portion is provided with a spring attaching portion, the spring portion is attached to the spring attaching portion, the spring portion presses the valve piston portion in vertical direction, and the spring portion has higher rigidity than the valve piston portion.