A method for preparing a semiconducting thin film and device for carrying out the method, wherein the method includes: (1) providing a liquid-liquid interface; (2) providing at least one layered semiconductor material or its precursor(s) in the form of particles in a solvent in the form of a dispersion; (3) injecting the dispersion at the liquid-liquid interface, in order to obtain an assembly of semiconductor/semiconductor precursor particles; (4) bringing the assembly of into contact with a flexible substrate; and (5) applying a surface pressure to the dispersion to obtain a particle film of semiconductor/semiconductor precursor on the substrate, wherein the first solvent has a higher density than the second solvent.

A device for coating semiconductor/semiconductor precursor particles on a flexible substrate and a preparation method of a semiconducting thin film, wherein the device includes: a container for a first and second solvent substantially immiscible; injection means for injecting a predetermined dispersion volume of at least one layered semiconductor particle material or its precursor(s), occurring at a liquid-liquid interface formed within the container and between the first and second solvent, and creating a particle film at the liquid-liquid interface; a first support means; substrate extracting means; substrate supply means; compression means, reducing a distance between particles and push the film onto the substrate, wherein the compression means includes several pushing means mounted on a drive device, wherein at least two of the several pushing means are at least partially submerged in the second solvent during drive device rotation, and moved through the second solvent toward the first support means.

A method for transferring an assembly of oriented nanowires from a fluid to a substrate surface, comprising: providing (FIG. 2A) a fluid to a container, said fluid comprising a first liquid (11), a second liquid (12) and a plurality of nanowires (25), wherein the first and second liquids phase separate into a sub phase, a top phase, and an interface (13) between the sub phase and the top phase; wherein the nanowires are functionalized to align vertically into a nanowire aggregate at the interface; wherein the fluid is provided with a substance in a composition configured to change the composition of the top phase or the composition of the sub phase to counteract bulging of the interface (FIG. 2B); and bringing the nanowire aggregate into contact with a substrate surface such that a majority of the nanowires are aligned with respect to each other on the substrate.

A separator for a lithium secondary battery and a manufacturing method thereof are provided. The separator comprises a metal organic framework (MOF) layer formed by Langmuir-Blodgett method, and prevents shuttle phenomenon caused by polysulfide leaching from a positive electrode which includes a sulfur-containing material, and thereby improving cycle stability of a lithium secondary battery.

A method for preparing a semiconducting thin film and device for carrying out the method, wherein the method includes: (1) providing a liquid-liquid interface; (2) providing at least one layered semiconductor material or its precursor(s) in the form of particles in a solvent in the form of a dispersion; (3) injecting the dispersion at the liquid-liquid interface, in order to obtain an assembly of semiconductor/semiconductor precursor particles; (4) bringing the assembly of into contact with a flexible substrate; and (5) applying a surface pressure to the dispersion to obtain a particle film of semiconductor/semiconductor precursor on the substrate, wherein the first solvent has a higher density than the second solvent.

A method for transferring an assembly of oriented nanowires from a fluid to a substrate surface, comprising: providing a fluid to a container, said fluid comprising a first liquid (11), a second liquid (12) and a plurality of nanowires (25), wherein the first and second liquids phase separate into a sub phase, a top phase, and an interface (13) between the sub phase and the top phase; wherein the nanowires are functionalized to align vertically into a nanowire aggregate at the interface; wherein the fluid is provided with a substance in a composition configured to change the composition of the top phase or the composition of the sub phase to counteract bulging of the interface (FIG. 2B); and bringing the nanowire aggregate into contact with a substrate surface such that a majority of the nanowires are aligned with respect to each other on the substrate.

A method for transferring an assembly of oriented nanowires from a fluid to a substrate surface, comprising: providing (FIG. 2A) a fluid to a container, said fluid comprising a first liquid (11), a second liquid (12) and a plurality of nanowires (25), wherein the first and second liquids phase separate into a sub phase, a top phase, and an interface (13) between the sub phase and the top phase; wherein the nanowires are functionalized to align vertically into a nanowire aggregate at the interface; wherein the fluid is provided with a substance in a composition configured to change the composition of the top phase or the composition of the sub phase to counteract bulging of the interface (FIG. 2B); and bringing the nanowire aggregate into contact with a substrate surface such that a majority of the nanowires are aligned with respect to each other on the substrate.

A method for producing an anode for a lithium metal secondary battery includes coating a thin film comprised of Nb.sub.2C, Ti.sub.2C or Ti.sub.3C.sub.2 on a substrate; providing a lithium metal electrode; and laminating the thin film to a surface of the lithium metal electrode. Coating is accomplished by providing a dispersion of a powder comprising Nb.sub.2C, Ti.sub.2C or Ti.sub.3C.sub.2; and coating the dispersion on the substrate by Langmuir-Blodgett scooping (LBS). The method may further include, prior to providing the dispersion, obtaining the powder by etching a MAX phase structure represented by Formula 1, Formula 2 or Formula 3 below:
Nb.sub.2AC(1);
Ti.sub.2AC(2); and
Ti.sub.3AC.sub.2(3), where A is a metal selected from among Group IIIA elements, Group IVA elements, Cd, and combinations thereof. The method may further include, after laminating the thin film, removing the substrate from the thin film.

A method for transferring an assembly of oriented nanowires from a fluid to a substrate surface, comprising: providing (FIG. 2A) a fluid to a container, said fluid comprising a first liquid (11), a second liquid (12) and a plurality of nanowires (25), wherein the first and second liquids phase separate into a sub phase, a top phase, and an interface (13) between the sub phase and the top phase; wherein the nanowires are functionalized to align vertically into a nanowire aggregate at the interface; wherein the fluid is provided with a substance in a composition configured to change the composition of the top phase or the composition of the sub phase to counteract bulging of the interface (FIG. 2B); and bringing the nanowire aggregate into contact with a substrate surface such that a majority of the nanowires are aligned with respect to each other on the substrate.

A Langmuir-Blodgett trough comprising a middle barrier, configured for creating two different layers of material over the surface of a single subphase liquid. The first layer of material is located on a first side of the middle barrier, while the second layer of material is located on a second side of the middle barrier. The through comprises an adjustment apparatus which comprises a first grooved edge, a second grooved edge, a first side barrier, and a second side barrier. The first side barrier and a second side barrier extend between the first grooved edges. The motion of the first and second side barriers is configured to adjust the surface areas of the first and second materials.