Novel iron-phosphate nanoparticles have been synthesized here. These are less than 12 nanometers in dimension. They are deemed useful for remediation of heavy metals and radionuclides and can be applied to insitu remediation of contaminated soils and contaminated waters.

The present subject matter relates to a composition for in-situ remediation of soil and aquifer comprising of a water miscible oil; a solvent (for dissolving the vegetable oil to form a solution); and a catalyst (selected from enzymes biocatalysts, particularly lipases, alkaline compounds, heat or combinations thereof). The present subject matter provides a process for the preparation of the composition and application of the same for surface remediation. Further, the present subject matter provides an in-situ alcoholysis remediation method to reduce contaminant concentrations in aquifer and soil by enabling the generation of both soluble and slowly fermenting electron donors required for the anaerobic remediation of organohalide compounds contaminating soils and groundwater. The method of remediation includes mixing an engineered water-soluble oil or water miscible oil with a solvent and adding a catalyst to groundwater to promote the formation of fatty acid alkyl esters, carboxylic acid salts and glycerol.

Methods of passively sampling PFAS in the environment, PFAS sorbents, apparatus and systems (apparatus plus conditions) for sampling groundwater, porewater, and surface water are described.

A system for decomposing a waste material in an unlined landfill including a landfill site having at least one waste disposal zone for receiving the waste material. The system also includes a remediation system configured for extracting a mixture of leachate and groundwater from groundwater within or adjacent to the landfill site and feeding the mixture into the at least one waste disposal zone along with air and other nutrients to enhance a rate of decay of the waste material within the at least one waste disposal zone.

The present application relates to a novel method for reductive degradation of perfluoroalkyl-containing compounds, such as perfluoroalkyl sulfonates, by activated carbon (AC) supported zero valent iron-nickle nanoparticles (nNi.sup.0Fe.sup.0).

Methods, apparatus, and systems involving wastewater treatment systems are provided. Plastic grids, with first and second legs are provided. These first and second legs have distal ends separated from each other. Flat pipes are also provided for wastewater treatment systems.

A method of sorbing a PFAS compound from a contaminated sample can include admixing a modified clay sorbent with the sample. The modified clay can include a clay intercalated with a blend of mono-quatemary amine compound and multifunctional-quatemary amine compound having a functionality of 3 or more.

An environmental remediation system includes a contaminate treatment mat assembly to extract contaminates in pore water and sediment. The mat assembly includes a flexible liner and pore water and sediment-penetrating chambers individually anchored to the flexible liner. The anchored chambers include lids that are positioned above the liner and containers below the liner. The system includes a plate subsystem including plate holes. The plate subsystem is configured to have the mat assembly removable attached thereunder, absorb impact forces from a delivery system, translate the impact forces into a driving force applied simultaneously to tops of the lids of all the pore water and sediment-penetrating chambers under the plate subsystem to cause penetration of the containers into underlying pore water and sediment, and simultaneously displace fluid through liner holes of the liner and the plate holes. A method for environmental remediating using the system is also provided.

Catalyst materials comprising iron and palladium are described. Also described are methods for preparing such materials. In addition, methods for remediating materials such as sediments and groundwater using the catalyst materials are described.

Reactive treatment cells (RTCs) are described in combination with sediment capping systems as a means for environmental remediation. RTCs include an impermeable housing defining an interior, a permeable ceiling and floor typically including filtration materials such as geotextiles, and at least one interior compartment for treatment reagents. One RTC includes a gabion-like cage structure retaining a geomembrane-supported geosynthetic clay liner (GM-GCL) housing, while a second embodiment includes a hard, cylindrical shell as a replaceable reagent cartridge. RTCs may be employed in initial capping system installations or retrofitted into existing capping systems. RTCs may include optional baffles, flow restrictors, floating discs, sensor probes, and two or more serial reagent zones or compartments.