A hot air circulation type indirect thermal desorption-based soil remediation system and method, belonging to the technical field of soil remediation. The system includes a thermal desorption reactor, a dust remover, a hot air circulating fan, a hot air heater, an air preheater, a combustion fan and a combustion device. By using thermal desorption gas generated by soil being heated and volatilized as a heat transfer medium and by a circular heating manner, hot air efficiently transfers heat to the soil by contact, and the high-temperature fume is kept from direct contact with the soil, so the system has the advantages of high treatment capacity, small equipment scale and the like.

An in-situ vapor injection thermal desorption device includes a sectional combined input head, several intermediate connectors and a bottom protector connected in series from top to bottom. The in-situ vapor injection thermal desorption device further includes several water-vapor coupling injection activation chips, selectively disposed below any of the intermediate connectors; the sectional combined input head is provided with a high-pressure-gas inlet, several pairs of heat-transfer-oil inlets and heat-transfer-oil outlets, and several pairs of hot-water inlets and hot-water outlets; the water-vapor coupling injection activation chip is provided with several gas-liquid spraying holes. The disclosure is an assembling structure; the number of the water-vapor coupling injection activation chips can be increased or reduced according to remediation depth on an actual site; it can be repeatedly used, uniformly sprayed, and enables the vapor for treating the organic soil to be generated in situ and remediating organic pollution sites in a low-carbon, energy-saving way.

The invention provides a system for pyrolysis, comprising: (i) a gas producer comprising a gasification zone and a producer gas outlet, wherein the gas producer is configured to: oxidise at least one carbon-containing feed in the presence of an oxidising gas in the gasification zone to form a producer gas; and discharge the producer gas from the gasification zone via the producer gas outlet, wherein a residual oxygen content of the producer gas is substantially depleted or maintained below a maximum predetermined amount by controlling a ratio of oxygen fed to the gasification zone to the carbon-containing feed, (ii) a pyrolyzer comprising a pyrolysis zone and one or more pyrolyzer gas outlets, wherein the pyrolyzer is configured to: feed the producer gas discharged from the gasification zone to the pyrolysis zone; pyrolyze a pyrolyzable organic feed in the pyrolysis zone in the presence of the producer gas to produce a carbonaceous pyrolysis product and a gas mixture comprising combustible components comprising pyrolysis gas; and discharge the gas mixture from the pyrolysis zone via the one or more pyrolyzer gas outlets, and (iii) a first combustor comprising a combustion zone, wherein the first combustor is configured to: receive the gas mixture discharged from the pyrolysis zone in the combustion zone; feed an oxygen-containing gas to the combustion zone; and combust at least a portion of the combustible components present in the gas mixture in the combustion zone to produce a combustion product gas.

Methods are provided for generating or recovering gaseous materials such as hydrogen and solids such as metals through the smoldering combustion of an organic material. The methods include admixing a porous matrix material with an organic material, and, in some embodiments a catalyst, to produce a porous mixture. The mixture is exposed to an oxidant, initiating a self-sustaining smoldering combustion of the mixture, and collecting the vapors and combustion products or processing the porous matrix following combustion to physically separate the porous matrix material from ash containing inorganic materials of value. Additional embodiments aggregate the organic material or catalyst or porous matrix material or mixture thereof in an impoundment such as a reaction vessel, lagoon or matrix pile. Further embodiments utilize at least one heater to initiate combustion and at least one air supply port to supply oxidant to initiate and maintain combustion.

A combined remediation method of petroleum-contaminated soil includes: impurity removal pretreatment, photocatalytic pre-oxidation, stepwise thermal desorption of petroleum from soil, and high-temperature oxidation; with iron-titanium composite metal oxide (ITCMO) as a catalyst, conducting oxidation pretreatment under light conditions so that some cross-linked structures in macromolecular petroleum contaminants are broken and degraded; and conducting stepwise pyrolysis to achieve a removal rate of more than 98.00%. The new method adopts a combined remediation technology of photocatalytic pre-oxidation-stepwise pyrolysis, which realizes a relatively-high removal rate of petroleum hydrocarbons and the efficient and harmless remediation of high-concentration petroleum-contaminated soil, and remedied soil can be reused.

A hot air circulation type indirect thermal desorption-based soil remediation system and method, belonging to the technical field of soil remediation. The system includes a thermal desorption reactor, a dust remover, a hot air circulating fan, a hot air heater, an air preheater, a combustion fan and a combustion device. By using thermal desorption gas generated by soil being heated and volatilized as a heat transfer medium and by a circular heating manner, hot air efficiently transfers heat to the soil by contact, and the high-temperature fume is kept from direct contact with the soil, so the system has the advantages of high treatment capacity, small equipment scale and the like.

A system and method for performing pyrolysis comprises a reactor through which organic material is conveyed from an upstream end toward a downstream end and within which said pyrolysis will occur; a combustion chamber fluidically connected to the downstream end of the reactor; an output pipe fluidically connected to the downstream end of the reactor; a capsule surrounding a first part of the reactor and into an internal portion of which heated thermal fluids are disposed for heating the first part of said reactor; and a plurality of electrical resistors disposed around a second part of the reactor for heating the second part of the reactor; whereby, as a result of the pyrolysis occurring within the reactor, the syngas is conducted toward the combustion chamber while the carbonized material is conducted outwardly from the reactor through the output pipe.

The present invention relates to a composite treatment and recovery technique of polluted water body and soil. Iron-rich straw biomass, after being crushed, is mixed and granulated with sludge, and is pyrolytic charred by programmed heating, to obtain bulk loaded zero-valent iron biochar and sludge biochar composite particles, which are packed as fillers in a filled bed or as filters in filter cells of a fixed bed, for effective recovery of complex polluted water, polluted by heavy metals, organics, nitrogen, phosphorus, and the like.

The present invention relates to a method for treating contaminated soil. A method for treating contaminated soil according to the present invention comprises: a flushing step of inserting a spraying rod including a nozzle into soil to spray a flushing liquid or an oxidizing liquid thereto; a first collection step of collecting floating material from the soil after the flushing step; a first phase separation step of separating the floating material collected in the first collection step into a liquid phase material and a solid phase material; a heating step of inserting a heating member into the solid fraction separated in the phase separation step to heat the solid fraction; a second collection step of collecting steam generated by the heating step; and a pyrolysis step of separating a gas phase material from the floating material from the floating material separated in the second collection step and performing heat treatment.

A method for remediating contaminated soil and groundwater includes selecting a treatment material and creating a smolderable mixture of a contaminant, the treatment material, and soil.