A tool-less method for making molds, cores, and temporary tools includes the steps of providing a volumetric build system, making a CAD model of a three-dimensional object, selecting a build material including an untreated sand, selecting a binder comprising a polymeric carbohydrate, and applying, by the volumetric build system, the binder onto the build material to three dimensionally print the object, wherein the object is adapted for being a mold, a core, or a temporary tool.

Investment casting shell composition binders comprising hydrophilic fibrils having an average diameter between about 1 nm and about less than 1 μm can be used for the preparation of investment casting shell compositions or slurries. The investment casting shell binders and compositions can be used in an investment casting process to produce investment casting shells with improved shell build thickness and strength.

A powder binder product for use in making a slurry for investment casting molds comprising Nano-sized powders; and an organic polymer powder, wherein it does not require aqueous colloidal silica to produce slurries used to build investment casting molds. The Nano-sized powders comprise fumed alumina, boehmite, fumed silica, or fumed titanium oxide or combinations thereof. The coarse refractory powder, combined with the powder binder for mold manufacture, comprises milled zircon, tabular alumina or fused alumina, fused silica, alumino-silicate, zirconia, and yttria or combinations thereof. The organic polymer in a powder binder comprises a cellulose-based material. A powder investment casting binder, that once fired, consists of up to 96 weight percent aluminum oxide.

A powder binder product for use in making a slurry for investment casting molds comprising Nano-sized powders; and an organic polymer powder, wherein it does not require aqueous colloidal silica to produce slurries used to build investment casting molds. The Nano-sized powders comprise fumed alumina, boehmite, fumed silica, or fumed titanium oxide or combinations thereof. The coarse refractory powder, combined with the powder binder for mold manufacture, comprises milled zircon, tabular alumina or fused alumina, fused silica, alumino-silicate, zirconia, and yttria or combinations thereof. The organic polymer in a powder binder comprises a cellulose-based material. A powder investment casting binder, that once fired, consists of up to 96 weight percent aluminum oxide.

Investment casting shell composition binders comprising hydrophilic fibrils having an average diameter between about 1 nm and about less than 1 ?m can be used for the preparation of investment casting shell compositions or slurries. The investment casting shell binders and compositions can be used in an investment casting process to produce investment casting shells with improved shell build thickness and strength.

The subject matter of the present invention is a binder system containing blocked tertiary amines or amidines as co-catalysts for a polyurethane cold-box application. It also relates to the molding material mixtures produced using such a binder system further comprising volatile tertiary amines, a method for producing the molding material mixtures, and the cores and molds made from the molding material mixtures according to the cold-box process.