Aspects of this disclosure include a method for repairing a component having narrow passage, a three-dimensional printer, and composition for three-dimensional printing. One embodiment of the method may comprise mixing a filler material for three-dimensional printing with a carrier fluid, and applying a controlled electromagnetic field to bias the filler material towards a repair location in a narrow passage of a component. The method may further comprise coating a ferromagnetic material with the filler material to form a microcapsule, wherein the ferromagnetic material is adapted to interact with the controlled electromagnetic field to attract the microcapsule to the repair location. 3D printing techniques may be used to coat the ferromagnetic core with the filler material.

Aspects of this disclosure include a method for repairing a component having narrow passage, a three-dimensional printer, and composition for three-dimensional printing. One embodiment of the method may comprise mixing a filler material for three-dimensional printing with a carrier fluid, and applying a controlled electromagnetic field to bias the filler material towards a repair location in a narrow passage of a component. The method may further comprise coating a ferromagnetic material with the filler material to form a microcapsule, wherein the ferromagnetic material is adapted to interact with the controlled electromagnetic field to attract the microcapsule to the repair location. 3D printing techniques may be used to coat the ferromagnetic core with the filler material.

A method for depositing a metal-based coating on a particulate substrate, including: i) preparing a mixture comprising the particulate substrate, a powder comprising a coating metal oxide of one or more of Ti, Al, Zn, Sn, In, Sb, Ag, Co, V, Ni, Cr, Mn, Fe, Cu, Pt, Pd, Ta, Zr, Nb, Rh, Ru, Mo, Os, Re and W, a reducing agent powder of Al metal or Al alloy, and a powder of aluminium chloride; and ii) mixing and heating the mixture to form a coating on the particulate substrate, to produce a coated substrate product.

A multilayer ceramic capacitor includes a ceramic base body including ceramic layers and internal electrode layers, which are stacked on each other, and a pair of external electrodes provided on the end surfaces of the ceramic base body and electrically connected to the internal electrode layers. Each of the external electrodes includes an underlying electrode layer and a resin external electrode layer stacked on the underlying electrode layer. The resin external electrode layer includes a thermosetting resin, a metal powder, and an alkyl-based silane coupling agent.

A magnetic material is formed of an aggregate of magnetic particles. When a magnetic particle is rotated by 360/n degrees (n is an any integer equal to or greater than 6) around a gravity center position of the magnetic particle in a planar region, an area of the magnetic particle after the rotation overlaps with an area of the magnetic particle before the rotation by 90% or more. In the planar region, gravity center positions of from nine to eleven magnetic particles are on a band portion in a rectangular shape. For the magnetic particles in the planar region, when a number-based 50% cumulative frequency distribution of maximum lengths in a direction passing through respective gravity center positions is defined as α, a 10% cumulative frequency distribution is equal to or greater than 0.6α, and a 90% cumulative frequency distribution is equal to or less than 1.4α.

A magnetic material is formed of an aggregate of magnetic particles. When a magnetic particle is rotated by 360/n degrees (n is an any integer equal to or greater than 6) around a gravity center position of the magnetic particle in a planar region, an area of the magnetic particle after the rotation overlaps with an area of the magnetic particle before the rotation by 90% or more. In the planar region, gravity center positions of from nine to eleven magnetic particles are on a band portion in a rectangular shape. For the magnetic particles in the planar region, when a number-based 50% cumulative frequency distribution of maximum lengths in a direction passing through respective gravity center positions is defined as α, a 10% cumulative frequency distribution is equal to or greater than 0.6α, and a 90% cumulative frequency distribution is equal to or less than 1.4α.

A magnetic material includes magnetic particles. When a magnetic particle is rotated by 360/n degrees (n is an any integer equal to or greater than 2) around a gravity center position of the particle in a planar region, an area of the particle after the rotation overlaps with an area of the particle before the rotation by 90% or more. In the planar region, gravity center positions of from nine to eleven particles are present on a band portion in a rectangular shape. For the particles in the planar region, when a number-based 50% cumulative frequency distribution of maximum lengths in a direction passing through respective gravity center positions is defined as α, a 10% cumulative frequency distribution is equal to or greater than 0.9α, and a 90% cumulative frequency distribution is equal to or less than 1.1α. A surface of the particle is covered with an insulating film.

A magnetic material includes magnetic particles. When a magnetic particle is rotated by 360/n degrees (n is an any integer equal to or greater than 2) around a gravity center position of the particle in a planar region, an area of the particle after the rotation overlaps with an area of the particle before the rotation by 90% or more. In the planar region, gravity center positions of from nine to eleven particles are present on a band portion in a rectangular shape. For the particles in the planar region, when a number-based 50% cumulative frequency distribution of maximum lengths in a direction passing through respective gravity center positions is defined as α, a 10% cumulative frequency distribution is equal to or greater than 0.9α, and a 90% cumulative frequency distribution is equal to or less than 1.1α. A surface of the particle is covered with an insulating film.

Some variations provide a composition for additive manufacturing (3D printing) of metals, comprising: from 10 vol % to 70 vol % of a photocurable liquid resin; from 10 vol % to 70 vol % of metal or metal alloy particles, optionally configured with a photoreflective surface; and from 0.01 vol % to 10 vol % of a photoinitiator. Other variations provide a composition for additive manufacturing of metals, comprising: from 1 vol % to 70 vol % of a photocurable liquid resin; from 0.1 vol % to 98 vol % of an organometallic compound containing a first metal; from 1 vol % to 70 vol % of metal or metal alloy particles containing a second metal (which may be the same as or different than the first metal); and from 0.01 vol % to 10 vol % of a photoinitiator. Many examples of metals, photocurable resins, organometallic compounds, photoinitiators, and optional additives are disclosed, and methods of making and using the composition are described.

Some variations provide a metal matrix nanocomposite composition comprising metal-containing microparticles and nanoparticles, wherein the nanoparticles are chemically and/or physically disposed on surfaces of the microparticles, and wherein the nanoparticles are consolidated in a three-dimensional architecture throughout the composition. The composition may serve as an ingot for producing a metal matrix nanocomposite. Other variations provide a functionally graded metal matrix nanocomposite comprising a metal-matrix phase and a reinforcement phase containing nanoparticles, wherein the nanocomposite contains a gradient in concentration of the nanoparticles. This nanocomposite may be or be converted into a master alloy. Other variations provide methods of making a metal matrix nanocomposite, methods of making a functionally graded metal matrix nanocomposite, and methods of making a master alloy metal matrix nanocomposite. The metal matrix nanocomposite may have a cast microstructure. The methods disclosed enable various loadings of nanoparticles in metal matrix nanocomposites with a wide variety of compositions.