A method for depositing a metal-based coating on a particulate substrate, including: i) preparing a mixture comprising the particulate substrate, a powder comprising a coating metal oxide of one or more of Ti, Al, Zn, Sn, In, Sb, Ag, Co, V, Ni, Cr, Mn, Fe, Cu, Pt, Pd, Ta, Zr, Nb, Rh, Ru, Mo, Os, Re and W, a reducing agent powder of Al metal or Al alloy, and a powder of aluminium chloride; and ii) mixing and heating the mixture to form a coating on the particulate substrate, to produce a coated substrate product.

A method for depositing a metal-based coating on a particulate substrate, including: i) preparing a mixture comprising the particulate substrate, a powder comprising a coating metal oxide of one or more of Ti, Al, Zn, Sn, In, Sb, Ag, Co, V, Ni, Cr, Mn, Fe, Cu, Pt, Pd, Ta, Zr, Nb, Rh, Ru, Mo, Os, Re and W, a reducing agent powder of Al metal or Al alloy, and a powder of aluminium chloride; and ii) mixing and heating the mixture to form a coating on the particulate substrate, to produce a coated substrate product.

A variety of polyhedral nanocages are provided having a hollow interior, ultrathin walls, and well-defined facets of metal atoms. The nanocages can include a variety of precious metals such as Pt, Au, Ru, Rh, or Ir. The metal atoms can take a face-centered cubic structure with {111} facets on the surface. The walls can be thin, sometimes less than 1 nm in thickness or only a few atomic layers in thickness. The nanocages can provide for efficient uses of valuable precious metals, among other things, in catalysis. For example, catalysts are provided exhibiting high mass activities in oxygen reduction reactions. Methods of making and methods of using the nanocages and catalysts are also provided.

A variety of polyhedral nanocages are provided having a hollow interior, ultrathin walls, and well-defined facets of metal atoms. The nanocages can include a variety of precious metals such as Pt, Au, Ru, Rh, or Ir. The metal atoms can take a face-centered cubic structure with {111} facets on the surface. The walls can be thin, sometimes less than 1 nm in thickness or only a few atomic layers in thickness. The nanocages can provide for efficient uses of valuable precious metals, among other things, in catalysis. For example, catalysts are provided exhibiting high mass activities in oxygen reduction reactions. Methods of making and methods of using the nanocages and catalysts are also provided.

A multilayer ceramic capacitor includes a ceramic base body including ceramic layers and internal electrode layers, which are stacked on each other, and a pair of external electrodes provided on the end surfaces of the ceramic base body and electrically connected to the internal electrode layers. Each of the external electrodes includes an underlying electrode layer and a resin external electrode layer stacked on the underlying electrode layer. The resin external electrode layer includes a thermosetting resin, a metal powder, and an alkyl-based silane coupling agent.

A Sm—Fe—N magnet includes Sm—Fe—N particles, wherein an inter-particle metal phase is present between at least two of the Sm—Fe—N particles, an average particle diameter of the Sm—Fe—N particles is less than 2.0 μm, and a percentage of the Sm—Fe—N particles having an aspect ratio of 2.0 or more is 10% or less, the inter-particle metal phase includes a Fe.sub.3Zn.sub.10 phase and an α-Fe phase in a particle form, and in the inter-particle metal phase, an area ratio of the Fe.sub.3Zn.sub.10 phase is 80% or more.

A Sm—Fe—N magnet includes Sm—Fe—N particles, wherein an inter-particle metal phase is present between at least two of the Sm—Fe—N particles, an average particle diameter of the Sm—Fe—N particles is less than 2.0 μm, and a percentage of the Sm—Fe—N particles having an aspect ratio of 2.0 or more is 10% or less, the inter-particle metal phase includes a Fe.sub.3Zn.sub.10 phase and an α-Fe phase in a particle form, and in the inter-particle metal phase, an area ratio of the Fe.sub.3Zn.sub.10 phase is 80% or more.

A Sm—Fe—N magnet includes Sm—Fe—N particles each having a surface, a coating layer being provided on at least a portion of the surface or on at least a portion of an interface between at least two of the Sm—Fe—N particles, or being provided on both, wherein the coating layer includes a first layer and a second layer, the first layer being situated closer to the surface or the interface than is the second layer, he first layer includes α-Fe, the second layer includes a Sm—Fe—Zn alloy, and a Zn content contained in the second layer is 1 at % or more and 20 at % or less.

A Sm—Fe—N magnet includes Sm—Fe—N particles each having a surface, a coating layer being provided on at least a portion of the surface or on at least a portion of an interface between at least two of the Sm—Fe—N particles, or being provided on both, wherein the coating layer includes a first layer and a second layer, the first layer being situated closer to the surface or the interface than is the second layer, he first layer includes α-Fe, the second layer includes a Sm—Fe—Zn alloy, and a Zn content contained in the second layer is 1 at % or more and 20 at % or less.

The present disclosure is directed at methods of preparing rare earth-based permanent magnets having improved coercivity and remanence, the method comprising one or more steps comprising: (a) homogenizing a first population of particles of a first GBM alloy with a second population of particles of a second core alloy to form a composite alloy preform, the first GBM alloy being substantially represented by the formula: AC.sub.bR.sub.xCo.sub.yCu.sub.dM.sub.z, the second core alloy being substantially represented by the formula G.sub.2Fe.sub.14B, where AC, R, M, G, b, x, y, and z are defined; (b) heating the composite alloy preform particles to form a population of mixed alloy particles; (c) compressing the mixed alloy particles, under a magnetic field of a suitable strength to align the magnetic particles with a common direction of magnetization and inert atmosphere, to form a green body; (d) sintering the green body; and (e) annealing the sintered body. Particular embodiments include magnets comprising neodymium-iron-boron core alloys, including Nd.sub.2Fe.sub.14B.