Disclosed are an R-T-B-based permanent magnet material, a preparation method therefor and the use thereof. The R-T-B-based permanent magnet material comprises R, B, M, Fe, Co, X and inevitable impurities, wherein: (1) R is a rare earth element, and the R includes at least Nd and RH, M being one or more of Ti, Zr and Nb, and X including Cu, “Al and/or Ga”; and (2) in percentage by weight, R: 30.5-32.0 wt%, B: 0.95-0.99 wt%, M: 0.3-0.6 wt%, X: 0.8-1.8 wt%, and Cu: 0.35-0.50 wt%, and the balance is Fe, Co and inevitable impurities. According to the present invention, under the condition of 0.3-0.6 wt% of a high melting point metal, a permanent magnet material with an excellent magnet performance and a good squareness is obtained.

Disclosed are an R-T-B-based permanent magnet material, a preparation method therefor and the use thereof. The R-T-B-based permanent magnet material comprises R, B, M, Fe, Co, X and inevitable impurities, wherein: (1) R is a rare earth element, and the R includes at least Nd and RH, M being one or more of Ti, Zr and Nb, and X including Cu, “Al and/or Ga”; and (2) in percentage by weight, R: 30.5-32.0 wt%, B: 0.95-0.99 wt%, M: 0.3-0.6 wt%, X: 0.8-1.8 wt%, and Cu: 0.35-0.50 wt%, and the balance is Fe, Co and inevitable impurities. According to the present invention, under the condition of 0.3-0.6 wt% of a high melting point metal, a permanent magnet material with an excellent magnet performance and a good squareness is obtained.

A method for manufacturing an R-T-B based sintered magnet according the present disclosure comprises: a step for preparing a coarse ground powder which is made from an alloy for R-T-B based sintered magnets and which has an average particle size of 10-500 μm; a step for obtaining a fine powder having an average particle size of 2.0-4.5 μm, by feeding the coarse ground powder to a jet mill device that has a grinding chamber filled with inert gas and grinding the coarse ground powder; and a step for producing a sintered body of the fine powder, wherein the inert gas has been humidified, and the oxygen content of the R-T-B based sintered magnet is 1000-3500 ppm by mass.

A method for manufacturing an R-T-B based sintered magnet according the present disclosure comprises: a step for preparing a coarse ground powder which is made from an alloy for R-T-B based sintered magnets and which has an average particle size of 10-500 μm; a step for obtaining a fine powder having an average particle size of 2.0-4.5 μm, by feeding the coarse ground powder to a jet mill device that has a grinding chamber filled with inert gas and grinding the coarse ground powder; and a step for producing a sintered body of the fine powder, wherein the inert gas has been humidified, and the oxygen content of the R-T-B based sintered magnet is 1000-3500 ppm by mass.

The present disclosure is directed at methods of preparing rare earth-based permanent magnets having improved coercivity and remanence, the method comprising one or more steps comprising: (a) homogenizing a first population of particles of a first GBM alloy with a second population of particles of a second core alloy to form a composite alloy preform, the first GBM alloy being substantially represented by the formula: AC.sub.bR.sub.xCo.sub.yCu.sub.dM.sub.z, the second core alloy being substantially represented by the formula G.sub.2Fe.sub.14B, where AC, R, M, G, b, x, y, and z are defined; (b) heating the composite alloy preform particles to form a population of mixed alloy particles; (c) compressing the mixed alloy particles, under a magnetic field of a suitable strength to align the magnetic particles with a common direction of magnetization and inert atmosphere, to form a green body; (d) sintering the green body; and (e) annealing the sintered body. Particular embodiments include magnets comprising neodymium-iron-boron core alloys, including Nd.sub.2Fe.sub.14B.

The present disclosure is directed at methods of preparing rare earth-based permanent magnets having improved coercivity and remanence, the method comprising one or more steps comprising: (a) homogenizing a first population of particles of a first GBM alloy with a second population of particles of a second core alloy to form a composite alloy preform, the first GBM alloy being substantially represented by the formula: AC.sub.bR.sub.xCo.sub.yCu.sub.dM.sub.z, the second core alloy being substantially represented by the formula G.sub.2Fe.sub.14B, where AC, R, M, G, b, x, y, and z are defined; (b) heating the composite alloy preform particles to form a population of mixed alloy particles; (c) compressing the mixed alloy particles, under a magnetic field of a suitable strength to align the magnetic particles with a common direction of magnetization and inert atmosphere, to form a green body; (d) sintering the green body; and (e) annealing the sintered body. Particular embodiments include magnets comprising neodymium-iron-boron core alloys, including Nd.sub.2Fe.sub.14B.

A method for producing an RFeB system sintered magnet according to the present invention includes: a process (S1) of preparing a lump of HDDR-treated raw material alloy that contains a polycrystalline substance including crystal grains having an average grain size of 1 μm or less in terms of an equivalent circle diameter calculated from an electron micrograph image, by an HDDR treatment including steps of heating a lump of RFeB system alloy containing 26.5 to 29.5% by weight of the rare-earth element R, in a hydrogen atmosphere at a temperature between 700 and 1,000° C., and changing the atmosphere to vacuum while maintaining the temperature within a range from 750 to 900° C.; a process (S2) of preparing a lump of raw material alloy having a high rare-earth content by heating the lump of HDDR-treated raw material alloy at a temperature between 700 and 950° C. in a state where the HDDR-treated raw material alloy is in contact with a contact substance including a second alloy that contains the rare-earth element R at a higher content ratio than a content ratio of the rare-earth element R in the RFeB system alloy; a process (S3) of preparing raw material alloy powder by fine pulverization of the lump of raw material alloy having a high rare-earth content into powder having an average particle size of 1 μm or less; an orienting process (S4) including steps of placing the raw material alloy powder in a mold, and applying a magnetic field to the raw material alloy powder without conducting compression molding; and a sintering process (S5) including a step of heating the oriented raw material alloy powder at a temperature between 850 and 1,050° C.

The present invention provides a rare-earth sintered magnet that is characterized in that: R (R indicates one or more elements selected from rare-earth elements, wherein Nd is essential), T (T indicates one or more elements selected from iron-group elements, wherein Fe is essential), X (X indicates one or two elements selected from B and C, wherein B is essential), M.sup.1 (M.sup.1 indicates one or more elements selected from Al, Si, Cr, Mn, Cu, Zn, Ga, Ge, Mo, Sn, W, Pb, and Bi), 0.1 mass % or less of O, 0.05 mass % or less of N, and 0.07 mass % or less of C are contained; the average crystal grain size is 4.0 μm or less; and relational expression (1) 0.26×D+97≤Or≤0.26×D+99 is satisfied assuming that the degree of orientation is Or [%] and that the average crystal grain size is D [μm]. With this rare-earth sintered magnet, it is possible to achieve superior magnetic characteristics in which both high Br and high H.sub.cJ are achieved.

The present invention provides a rare-earth sintered magnet that is characterized in that: R (R indicates one or more elements selected from rare-earth elements, wherein Nd is essential), T (T indicates one or more elements selected from iron-group elements, wherein Fe is essential), X (X indicates one or two elements selected from B and C, wherein B is essential), M.sup.1 (M.sup.1 indicates one or more elements selected from Al, Si, Cr, Mn, Cu, Zn, Ga, Ge, Mo, Sn, W, Pb, and Bi), 0.1 mass % or less of O, 0.05 mass % or less of N, and 0.07 mass % or less of C are contained; the average crystal grain size is 4.0 μm or less; and relational expression (1) 0.26×D+97≤Or≤0.26×D+99 is satisfied assuming that the degree of orientation is Or [%] and that the average crystal grain size is D [μm]. With this rare-earth sintered magnet, it is possible to achieve superior magnetic characteristics in which both high Br and high H.sub.cJ are achieved.

The present disclosure relates generally to a method for improving the performance of sintered NdFeB magnet. A method of preparing a sintered NdFeB magnet therefore comprises the steps of: a) preparing alloy flakes from a raw material of the NdFeB magnet by a strip casting process; and b) preparing a coarse alloy powder from the alloy flakes by a hydrogen decrepitation process, the hydrogen decrepitation process including treatment of the alloy flakes under a hydrogen pressure of 0.10 MPa to 0.25 MPa for a duration of 1 to 3.5 hours, then degassing the hydrogen at a predetermined temperature between 300° C. to 400° C. for a duration time of 0.5 to 5 hours, and then mixing the resulting coarse alloy powder with a lubricant.