A cemented carbide having an eta phase and a Ni—Al binder is provided. The binder includes intermetallic γ′-Ni.sub.3Al-precipitates embedded in a substitutional solid solution matrix including Al and Ni. Further, the cemented carbide has a surface zone free from eta phase. A method of making a cutting tool is also provided.

The present disclosure relates to a cutting tool including a cemented carbide substrate having WC, gamma phase and a binder phase. The substrate is provided with a binder phase enriched surface zone, which is depleted of gamma phase, wherein no graphite and no ETA phase is present in the microstructure and wherein the binder phase is a high entropy alloy.

Methods of making sintered articles from powder metal carbide compositions by additive manufacturing techniques are described herein. Sintered carbide articles fabricated by such additive manufacturing techniques, in some embodiments, exhibit densities equaling articles formed according to conventional techniques employed in powder metallurgy. For example, a method of manufacturing an article comprises providing sintered cemented carbide powder comprising a hard particle phase including tungsten carbide and a metallic binder phase and forming the sintered cemented carbide powder into a green article by one or more additive manufacturing techniques. The green article is sintered to provide a sintered article having density greater than 90% theoretical full density, wherein the green article has a density less than 50% theoretical full density prior to sintering.

Methods of making sintered articles from powder metal carbide compositions by additive manufacturing techniques are described herein. Sintered carbide articles fabricated by such additive manufacturing techniques, in some embodiments, exhibit densities equaling articles formed according to conventional techniques employed in powder metallurgy. For example, a method of manufacturing an article comprises providing sintered cemented carbide powder comprising a hard particle phase including tungsten carbide and a metallic binder phase and forming the sintered cemented carbide powder into a green article by one or more additive manufacturing techniques. The green article is sintered to provide a sintered article having density greater than 90% theoretical full density, wherein the green article has a density less than 50% theoretical full density prior to sintering.

The present disclosure relates to a cutting tool including a cemented carbide substrate having WC, gamma phase and a binder phase. The substrate is provided with a binder phase enriched surface zone, which is depleted of gamma phase, wherein no graphite and no ETA phase is present in the microstructure and wherein the binder phase is a high entropy alloy.

A cemented carbide including an eta phase and a Ni—Al binder is provided. The Ni—Al binder includes intermetallic y′-Ni.sub.3Al-precipitates embedded in a substitutional solid solution matrix of Al and Ni. A weight ratio Al/Ni of between 0.03 to 0.10, wherein a total amount of Ni and Al is between 70 to 95 wt % of the total binder A method of making a cutting tool is also provided.

A cemented carbide including an eta phase and a NiAl binder is provided. The NiAl binder includes intermetallic y-Ni.sub.3Al -precipitates embedded in a substitutional solid solution matrix of Al and Ni. A weight ratio Al/Ni of between 0.03 to 0.10, wherein a total amount of Ni and Al is between 70 to 95 wt % of the total binder A method of making a cutting tool is also provided.

Methods of making sintered articles from powder metal carbide compositions by additive manufacturing techniques are described herein. Sintered carbide articles fabricated by such additive manufacturing techniques, in some embodiments, exhibit densities equaling articles formed according to conventional techniques employed in powder metallurgy. For example, a method of manufacturing an article comprises providing sintered cemented carbide powder comprising a hard particle phase including tungsten carbide and a metallic binder phase and forming the sintered cemented carbide powder into a green article by one or more additive manufacturing techniques. The green article is sintered to provide a sintered article having density greater than 90% theoretical full density, wherein the green article has a density less than 50% theoretical full density prior to sintering.

Methods of making sintered articles from powder metal carbide compositions by additive manufacturing techniques are described herein. Sintered carbide articles fabricated by such additive manufacturing techniques, in some embodiments, exhibit densities equaling articles formed according to conventional techniques employed in powder metallurgy. For example, a method of manufacturing an article comprises providing sintered cemented carbide powder comprising a hard particle phase including tungsten carbide and a metallic binder phase and forming the sintered cemented carbide powder into a green article by one or more additive manufacturing techniques. The green article is sintered to provide a sintered article having density greater than 90% theoretical full density, wherein the green article has a density less than 50% theoretical full density prior to sintering.

Methods of making sintered articles from powder metal carbide compositions by additive manufacturing techniques are described herein. Sintered carbide articles fabricated by such additive manufacturing techniques, in some embodiments, exhibit densities equaling articles formed according to conventional techniques employed in powder metallurgy. For example, a method of manufacturing an article comprises providing sintered cemented carbide powder comprising a hard particle phase including tungsten carbide and a metallic binder phase and forming the sintered cemented carbide powder into a green article by one or more additive manufacturing techniques. The green article is sintered to provide a sintered article having density greater than 90% theoretical full density, wherein the green article has a density less than 50% theoretical full density prior to sintering.