A power tool structure including a main body, a socket, a positioning ball, a pressing ring, a locking mechanism and a head is provided. The socket is connected to the main body and includes an arc space and a through hole passing through an annular wall of the socket to communicate with the arc space. The positioning ball is movably received in the through hole. The pressing ring includes a track. The locking mechanism sleeves on the pressing ring and is coupled to the pressing ring. The locking mechanism includes a coupling portion corresponding to the track, and the locking mechanism is forced to rotate so as to switch between a first position and a second position relative to the pressing ring, thereby allowing the locking mechanism to selectively press against the positioning ball. The head is pivotally inserted in the socket and includes a positioning portion.