Alcoholic spirits may be artificially aged under highly pressurized carbon dioxide. The carbon dioxide may form carbonic acid, which may cause various esters to form in the presence of wood as well as to mellow the flavor when no wood is present. Wood may be pretreated with ozone, which may extract lignin which may further convert to vanillin during pressurized CO2 treatment, giving a vanilla note. After processing with pressurized CO2, a post-treatment of ozone may be given to the spirit, which may cause a mild oxidation and further mellowing of the spirit.

Naturally-occurring cellulose-based material, such as wood, bamboo, grass, or reed, can be subjected to one or more chemical treatments to remove at least some lignin therefrom. The resulting partially-delignified material can be partially dried or fully dried and then rehydrated to yield a moldable cellulose-based material. The moldable material can be formed from a substantially flat planar configuration into a non-planar three-dimensional configuration. Once formed into a desired configuration, the moldable material can be fully dried to set its shape, thereby forming a rigid molded piece. In some embodiments, the molded piece can be used as a structural material, for example, to form a load-bearing structure or part of a composite load-bearing structure.

The present invention relates to the creation of thermally insulating materials derived from cellulosic materials by selectively depolymerizing the materials anatomy. Cellulosic materials may be comprised of three main biopolymers: lignin, hemicellulose, and cellulose. The present invention relates to the chemical and physical removal of lignin and hemicellulose, while leaving the cellulose unaltered to induce increased porosity within the material and the material's macrostructure matrix for use as thermal and acoustic insulation. The increased porosity will be due to the creation of closed cell voids within the cellulosic matrix. These voids will increase the thermal and acoustic insulating performance of the cellulosic materials. The selective removal of secondary biopolymers from cellulosic materials allow for isolation of other value added products that can be regenerated through fewer reactions/steps. This is a novel advantage over other similar processes that dissolve cellulose completely, making it harder to extract and isolate secondary off-stream products.

Methods for producing structural materials from lumber are provided. The methods use an oxygen pre-treatment or a carbonate pre-treatment followed by densification via thermal compression to produce structural materials with strong mechanical properties. The pre-treatments are able to partially delignify the lumber without substantially adversely affecting the mechanical properties of the subsequently densified wood.

The present disclosure relates to wood template-supported phase change material (PCM) composites having thermal energy storage applications. A wood template-supported PCM composite may include a wood template that has had at least a portion of its xylan and/or lignin removed and saturated with a PCM. The PCM may be stabilized with a cross linkable network for improved infiltration into the wood template. The wood template-supported PCM composite may be formed by extracting xylan and/or lignin from the wood to create a wood template, densifying at least a portion of the wood template, and inserting a PCM into the wood template.

Alcoholic spirits may be artificially aged under highly pressurized carbon dioxide. The carbon dioxide may form carbonic acid, which may cause various esters to form in the presence of wood as well as to mellow the flavor when no wood is present. Wood may be pretreated with ozone, which may extract lignin which may further convert to vanillin during pressurized CO2 treatment, giving a vanilla note. After processing with pressurized CO2, a post-treatment of ozone may be given to the spirit, which may cause a mild oxidation and further mellowing of the spirit.

The invention provides a method for extraction of at least one extract compound from a material, comprising: a. contacting carbon dioxide with the material to dissolve an amount of the at least one extract compound from the material into the carbon dioxide; b. contacting the carbon dioxide comprising the at least dissolved extract compound with a sorbent to sorb the at least one extract compound onto the sorbent and for regenerating the carbon dioxide; c. recirculating the regenerated carbon dioxide; and d. repeating said recirculating at a constant density of said carbon dioxide of between 100 and 1000 kg/m.sup.3, and repeating said recirculating for at least 10 cycles.

A flexible structure is formed by subjecting cellulose-based natural wood material to a chemical treatment that partially removes hemicellulose and lignin therefrom. The treated wood has a unique 3-D porous structure with numerous channels, excellent biodegradability and biocompatibility, and improved flexibility as compared to the natural wood. By further modifying the treated wood, the structure can be adapted to particular applications. For example, nanoparticles, nanowires, carbon nanotubes, or any other coating or material can be added to the treated wood to form a hybrid structure. In some embodiments, open lumina within the structure can be at least partially filled with a non-wood substance, such as a flexible polymer, or with entangled cellulose nanofibers. The unique architecture and superior properties of the flexible wood allow for its use in various applications, such as, but not limited to, structural materials, solar thermal devices, flexible electronics, tissue engineering, thermal management, and energy storage.

The present invention concerns a process for manufacturing a fraction comprising carboxylic acid anhydride by reaction of a fraction comprising carboxylic acid with a ketene, and the use of the fraction comprising carboxylic acid anhydride in a process for acylation of polysaccharides.

A super strong and tough densified wood structure is formed by subjecting a cellulose-based natural wood material to a chemical treatment that partially removes lignin therefrom. The treated wood retains lumina of the natural wood, with cellulose nanofibers of cell walls being aligned. The treated wood is then pressed in a direction crossing the direction in which the lumina extend, such that the lumina collapse and any residual fluid within the wood is removed. As a result, the cell walls become entangled and hydrogen bonds are formed between adjacent cellulose nanofibers, thereby improving the strength and toughness of the wood among other mechanical properties. By further modifying, manipulating, or machining the densified wood, it can be adapted to various applications.