The present invention aims to provide a heat-shrinkable polyester film roll having decreased generation of wrinkles or longitudinal shrink mark. The present invention provides a film roll of a heat shrinkable polyester film, wherein a polyester of the polyester film contains recycled raw material from a PET bottle and an acid component of the polyester comprises isophthalic acid, and the film roll satisfies a specific average value of a shrinkage, specific isophthalic acid ratio, and specific thickness unevenness.

The invention relates to a method of manufacturing a sandwich panel comprises the steps of: a) providing a plate-shaped assembly of a first cover part and a second cover part and between these cover parts a core part of a thermoplastic material containing a physical blowing agent, b) heating the assembly resulting from step a) under pressure between press tools in a press to a foaming temperature below the glass transition temperature of the thermoplastic material in the core part, thereby effecting adhesion of the foamed core part to the first and second cover parts c) foaming the thermoplastic material in the core part under pressure and at the foaming temperature wherein the spacing between the press tools is increased; d) a cooling step of cooling the foamed sandwich panel resulting from step c), while the sandwich panel is maintained under pressure between the press tools; e) removing the thus cooled sandwich panel from the press; and f) drying the sandwich panel thus obtained; wherein the cooling step d) comprises.a first substep d1) of cooling the foamed assembly from the foaming temperature to an intermediate temperature in the range of 70-100° C. at a first cooling rate and a second substep d2) of cooling the foamed assembly from the intermediate temperature to ambient temperature at a second cooling rate, the second cooling rate is less than the first cooling rate.

A high-strength absorbable internal fixation bone screw for a fracture. The bone screw is made of a degradable oriented polylactic acid section. A raw material for the oriented polylactic acid section is a poly(L-lactic acid). The specific optical rotation of the poly(L-lactic acid) is −155° to −160°. The section is made of the poly(L-lactic acid) through the processes of making a billet, orientation strengthening and quenching in order. The method for making the billet is plastic injection molding. The method for orientation strengthening is forging and pressing or extrusion. The section is turned, finely milled, or directly molded into the bone screw. The bone screw has high strength and a low rate of mechanical strength loss, ensures mechanical support during bone healing and sufficient healing time for an injured bone, has good biocompatibility, and can be degraded and absorbed.

The invention relates to a method of manufacturing a sandwich panel comprises the steps of:

a) providing a plate-shaped assembly of a first cover part and a second cover part and between these cover parts a core part of a thermoplastic material containing a physical blowing agent,

b) heating the assembly resulting from step a) under pressure between press tools in a press to a foaming temperature below the glass transition temperature of the thermoplastic material in the core part, thereby effecting adhesion of the foamed core part to the first and second cover parts

c) foaming the thermoplastic material in the core part under pressure and at the foaming temperature wherein the spacing between the press tools is increased;

d) a cooling step of cooling the foamed sandwich panel resulting from step c), while the sandwich panel is maintained under pressure between the press tools;

e) removing the thus cooled sandwich panel from the press; and

f) drying the sandwich panel thus obtained;

wherein the cooling step d) comprises a first substep d1) of cooling the foamed assembly from the foaming temperature to an intermediate temperature in the range of 70-100° C. at a first cooling rate and a second substep d2) of cooling the foamed assembly from the intermediate temperature to ambient temperature at a second cooling rate, the second cooling rate is less than the first cooling rate.

The invention provides a heat-shrinkable polyester film roll obtained by winding a heat-shrinkable polyester film on a paper tube with primary shrinkage in the longitudinal direction and a shrinkage rate of 40% or more, wherein the film has a winding length of 1000 to 30000 m, a width of 50 to 1500 mm, and a thickness of 5-30 μm, the thickness irregularity of the film roll in the width direction is 20% or less, the paper tube has an inner diameter of 3 inches with a 0.5 mm or less difference in clearance and a 1700 N/100 mm or more flat compressive strength in the width direction after the film is removed from the film roll, the mean value of the winding hardness of the surface layer part of the film roll in the width direction is 500-850, and the natural shrinkage rate in the longitudinal direction is 2.0% or less.

In various exemplary embodiments, the present disclosure provides a process for the conversion of certain polymers into diamond and diamond-like materials using laser pulse annealing. The process includes transforming the polymer to carbon, melting the carbon and quenching the carbon melt into to form Q-carbon, diamond, and/or graphene. The process can be applied to a polymer film such aa a polytetrafluoroethylene (PTFE) tape. An object can be coated with the polymer film which can then be converted to Q-carbon, diamond, and/or graphene using laser pulse annealing. A process is also provided for making a three-dimensional object using a combination of, for example, 3D printing the polymer and converting each layer of polymer into Q-carbon, diamond and/or graphene.

A method for post-treating a three-dimensional object produced by selectively solidifying, layer by layer, of a building material in powder form and/or post-treating unsolidified building material in which the three-dimensional object is embedded. The three-dimensional object and/or the unsolidified building material may be treated with a liquid. The liquid may comprises a liquid carrier substance and at least one further substance that reduces surface tension of the carrier substance.

Methods for in-situ solution heat treating an additively manufactured metallic component in order to increase the mechanical properties thereof and systems to perform the same. The method can include depositing filler material on a substrate forming a deposition layer, measuring the temperature of a heat affected zone corresponding to the deposition layer, and solution heat treating the deposition layer subsequent to the depositing and proximate to the deposition head. The solution heat treating can include heating the deposition layer to a solution temperature so as to achieve solution heat treatment and controlling the cooling rate of the deposition layer to at or above the critical cooling rate of the filler material until a target temperature is reached. Optionally, the method can include inducing an electron flow in the deposition layer to electromagnetically stir molten filler material in the heat affected zone.

The present disclosure relates to a process for dyeing a hydrolysis-resistant polyester film. The process comprises dyeing of a hydrolysis resistant polyester film in a dye bath comprising at least one coloring agent (dye), at least one polyhydric alcohol, and optionally at least one UV absorber to obtain a dyed film. The dyed film is subjected to quenching followed by cleaning and drying to obtain a dyed hydrolysis-resistant polyester film. The process of the present disclosure is simple, economical, improve hydrolysis resistance, and also retains the mechanical properties of the film when exposed to harsh environmental conditions.

In various exemplary embodiments, the present disclosure provides a process for the conversion of certain polymers into diamond and diamond-like materials using laser pulse annealing. The process includes transforming the polymer to carbon, melting the carbon and quenching the carbon melt into to form Q-carbon, diamond, and/or graphene. The process can be applied to a polymer film such as a polytetrafluoroethylene (PTFE) tape. An object can be coated with the polymer film which can then be converted to Q-carbon, diamond, and/or graphene using laser pulse annealing. A process is also provided for making a three-dimensional object using a combination of, for example, 3D printing the polymer and converting each layer of polymer into Q-carbon, diamond and/or graphene.