A heat shrink component includes a heat shrink layer and a heating unit in thermal contact with at least a part of the heat shrink layer and heating the heat shrink layer to a heat shrink temperature. The heat shrink component has a first dimension in an expanded state and a second dimension in a shrunk state after heating, the first dimension is larger than the second dimension. The heating unit includes an electrically conductive lead heated by an electrical current flowing through the electrically conductive lead and a heat spreading layer arranged in thermal contact with the electrically conductive lead and distributing a heat generated by the electrically conductive lead.

The invention relates to a method for manufacturing a breast prosthesis, in which a first dispersion of a first granular material is introduced into a cross-linkable silicone compound. The silicone compound subsequently is cured in order to form a prosthesis body, wherein the prosthesis body is heated to a shrinking temperature which lies above the melting point of the thermoplastic material.

A method for producing shape memory anti-counterfeiting identifier includes the following steps: a high polymer material with a shape memory function without the need of sunshine cross-linking or chemical cross-linking is directly extruded to become sheet in an extruder or is injected to be molded in an injection molding machine, and the extruded sheet can be a planar sheet or a sheet having a surface on which concave-convex patterns or characters are formed; the above sheet is then heated to the temperature higher than the vitrification temperature and lower than the melting point temperature, and the patterns or characters are pressed on the planar sheet, or the sheet on which the concave-convex patterns or characters are already formed is pressed to become planes or other patterns and characters; the sheet is then cut into small sheets, wherein one pattern or one group of characters is implied on every small sheet, and when the small sheets are again heated to the temperature higher than the vitrification temperature and lower than the melting point temperature, they will return to the extruded state.

This invention relates to shape memory block copolymers comprising: at least one switching segment having a T.sub.trans from 10 to 70° C.; and at least one soft segment, wherein at least one of the switching segments in linked to at least one of the soft segments by at least one linkage, and wherein the copolymer transforms from a first shape to a second shape by application of a first stimulus and the copolymer transforms back to the first shape from the second shape by application of a second stimulus. The shape memory block copolymers may be biocompatible and biodegradable.

Shape memory polymers (SMP) based on poly vinyl alcohol (PVA) in the presence of 2-carboxyethyl acrylate oligomers (CEA), multi-wall carbon nanotubes (MWCNTs) and cross linked by ionizing radiation were investigated. Chemical crosslinking by glutaraldehyde for PVA in the presence of CEA and MWCNTs was also studied. Radiation cross linked SMP exhibits good temperature responsive shape memory behavior as demonstrated by thermal properties of radiation investigated by dynamic mechanical analysis. Transition temperature at Tan δ of radiation cross linked SMP decreased significantly by 6 and 13° C. due to addition of MWCNTs. The developed SMP exhibited promising shape memory behavior of radiation cross linked SMP for biomedical applications between temperatures range of Tan δ. Results on the gel fraction revealed significant reduction in swelling and increase in gelation due to chemical cross linking with glutaraldehyde. The radiation cross linked SMP reached 100% gelation at an irradiation dose of 50 kGy.

The present disclosure provides a dual layer heat shrink tube having: an inner polymeric layer with a thickness t.sub.1 and an outer diameter D.sub.1; and an outer, expanded polymeric layer with a thickness t.sub.2′ and an outer diameter D.sub.2′ obtained by expanding a polymer tube from D.sub.2 to D.sub.2′ and t.sub.2 to t.sub.2′ at a selected temperature so that D.sub.2′−2(t.sub.2′)>D.sub.1, wherein a ring cut from a cross-section of the dual layer heat shrink tube, slit into a rectangle and gripped at cut ends by tension grips within a DMA, and subjected to a temperature sweep of 3° C./min at a frequency of 1 Hz from the onset of a melting endotherm of the inner polymeric layer to that of the outer, expanded polymeric layer is greater than 1° C. and less than 12° C. The disclosure further provides associated methods for preparing and using such tubes, as well as to products comprising such tubes.

[PROBLEMS] It is an object of the present invention to provide a heat-shrinkable polyester-based film roll which can reduce defects caused during a heat shrinking step due to the variation of a heat shrinkage rate in the heat-shrinkable polyester-based film roll having the longitudinal direction as the main shrinkage direction, specifically, defects of the film when covering an object by a wrap-around method and heat-shrunk. [SOLUTIONS] A heat-shrinkable polyester-based film roll, comprising a core; and a heat-shrinkable polyester-based film having a longitudinal direction as a main shrinkage direction that is wound around the core; wherein the film (roll) satisfy predetermined polyester composition, and all samples cutout every about 100 m have a heat shrinkage rate measured by immersion in hot water of 90° C. for 10 seconds of 30% or more and 80% or less and ±3% or less of an average in the longitudinal direction.

A housing structure manufacturing method and an electronic device are provided. The housing structure manufacturing method includes providing a plurality of memory polymeric materials, heating the plurality of memory polymeric materials, and forming the housing structure having a first morphology by printing the plurality of memory polymeric materials that are heated.

A process of heat shrinking an article is provided. The process includes shaping a thermoplastic vulcanizate (TPV) into an article, the TPV having: a partially vulcanized rubber dispersed in a continuous thermoplastic phase, wherein more than 5 wt % of the rubber is extractable in boiling xylene, and wherein the thermoplastic phase comprises a thermoplastic resin having a Tm>110° C. and a propylene-based elastomer (PBE) having a Tm<110° C.; and heating the article to a temperature between about 100° C. and 250° C. to shrink the article.

A structured fluoropolymer film including a plurality of structures having a height at least two times a thickness of a corresponding unstructured fluoropolymer film and at least a 20% increase in displacement induction period when compared to the corresponding unstructured fluoropolymer film when measured in a biaxial tensile curve at a temperature of about 125° C. In addition, the structured fluoropolymer film has a methane permeability of less than 500 μg*μm/cm.sup.2/min. The structured fluoropolymer film exhibits a higher resistance to strain and retain barrier properties during manufacture and/or use.