There are provided a metal-resin joint having high bonding strength and a manufacturing method thereof. A metal-resin joint 10 of the present disclosure includes an anchor portion 34 provided on a metal bonding surface 32 of a metal member 30. The anchor portion 34 has a pair of protrusion strips 35 and 35 protruding from the metal bonding surface 32 with a gap, a recessed groove 36 provided between the pair of protrusion strips 35 and 35, and a plurality of partitions 37 protruding from a groove bottom of the recessed groove 36. The plurality of partitions 37 are provided to be inclined toward one side Y1 in a direction in which the pair of protrusion strips 35 and 35 extend as going toward a distal end side, and to be side by side in a direction Y in which the pair of protrusion strips 35 and 35 extend.

A connector may couple to a non-cylindrical composite tubing having at least two lateral sides disposed in parallel and an open end. The connector may comprise first and second bonding plates adhered to an inner surface of the two lateral sides via an epoxy adhesive uniformly distributed. The first and second bonding plates may each have a distal lateral face defining a plurality of first threaded holes accessible at the open end of the composite tubing. The connector may also comprise an end plate having a plurality of first and second slotted holes disposed substantially in parallel and each aligned with an associating one of the first threaded holes. The connector may also comprise end plate fasteners loosely inserted through the first and second slotted holes and engaged with the first threaded holes. The end plate may also comprise one or more attachment points.

A bonded composite joint includes a first carbon fiber-reinforced polymer (CFRP) panel; a second CFRP panel; a corrugated structure placed between the first and second CFRP panels; and an adhesive placed between the first and second CFRP panels and in contact with the corrugated structure. The corrugated structure has a shape defined by a given wavelength λ.

A CFRP material with an Al alloy sheet attached to or a CFRTP material with an Al alloy sheet attached to is prepared by joining an Al alloy sheet with a CFRP material or a CFRTP material by adhesion or by injection molding. The surface of this Al alloy sheet and a surface of metal material such as Ti, etc., are subjected to chemical treatment. After this chemical treatment, the CFRP material with an Al alloy sheet attached to or the CFRTP material with an Al alloy sheet attached to and the metal material are inserted into a metallic mold for injection molding so as to have a gap therebetween. High crystalline thermoplastic resin is injected into this gap to join the metal material with the Al alloy sheet, thus obtaining a laminated composite.

An object is to provide a metal-resin bonded member that is easy to manufacture and has high bonding strength. The metal-resin bonded member includes a metal body having an iron oxide layer on the surface and a resin body bonded to the metal body via the iron oxide layer. The iron oxide layer has a thickness of 50 nm to 10 μm. The iron oxide layer comprises 60-40 at % Fe and 40-60 at % O at the outermost surface side. The iron oxide layer contains magnetite (Fe.sub.3O.sub.4). The iron oxide layer is formed by heating the surface of an iron-based substrate at 200-850° C. in an oxidation atmosphere. The resin body is composed of polyphenylene sulfide (PPS). The bonding of the metal body and the resin body via the iron oxide layer can be carried out by insert molding, thermal adhesion utilizing friction heating, etc.

A method of manufacturing a composite member including an aluminum member and a resin member bonded to each other, the method including: performing blasting on a surface of the aluminum member; modifying the surface of the aluminum member into aluminum hydroxide, the modifying including causing the surface of the aluminum member having undergone blasting to react with water by using at least one of heat and plasma; and directly bonding the resin member to the surface of the aluminum member modified to the aluminum hydroxide.

According to an aspect of the present disclosure, A method of manufacturing a composite member including an aluminum member and a resin member that are bonded to each other, the method including: blasting on a surface of the aluminum member to form asperities on the surface of the aluminum member; performing hydrothermal treatment on the surface of the aluminum member having the asperities to modify a surface of the asperities into aluminum hydroxide and form a surface nano structure on the surface of the asperities; applying a binder containing a triazine thiol derivative to the surface of the asperities of the aluminum member modified into aluminum hydroxide and having the surface nano structure to form a coating to be bonded to the aluminum member; and bonding the coating and the resin member.

A method of directly joining a polymer to a metal along a joint interface through the formation of C—O—M chemical bonds, where M represents an element in the metal to be joined. The method includes heating the metal to a predetermined temperature above a glass transition temperature of the polymer and less than a flash ignition temperature of the polymer and less than a metal melting temperature of the metal; and applying force to the joint interface of the metal and the polymer to generate intimate atomic contact between the metal and the polymer to create C—O—M chemical bonds between the metal and the polymer.

The method of metal-thermoplastic resin direct bonding is characterized by comprising a first step for irradiating a surface of the metal material with a pulse laser under an oxidizing atmosphere to form a surface modification region, a second step for causing the thermoplastic resin material to abut against the surface modification region to form a bonding interface, and a third step for heating up the bonding interface by laser irradiation to achieve bonding, the first step including forming metal oxide particle clusters obtained when metal oxide particles having a particle diameter of 5-500 nm to be continuously bonded at the surface modification region, so that the maximum height (Sz) of a surface of the metal oxide particle clusters is 50 nm-3 .Math.m.

A laser welded structure is formed by laser welding together a resin molded body formed from a thermoplastic polymer alloy containing a crystalline resin and an amorphous resin and a metal body made of a metal. A glass transition temperature of the amorphous resin is lower than a melting start temperature of the crystalline resin.