Methods of using and repairing seal caps as well as constructions comprising seal caps, including in some embodiments seal caps which may be useful in sealing fasteners that protrude into fuel storage cells in aircraft. In some embodiments, methods include the use of optically translucent seal cap and application of a second quantity of sealant to fill voids observed within the interior of the seal cap after cure of a first quantity of sealant.

In an example of a three-dimensional (3D) printing method, a build material (consisting of an inorganic particle and a polymer attached thereto) is applied. The polymer is a continuous coating having a thickness from about 3 nm to about 1500 nm, or nano-beads having an average diameter from about 3 nm to about 1500 nm. The build material is heated to a temperature from about 5° C. to about 50° C. below the polymer's melting point. A coalescent dispersion (including a coalescent agent and inorganic nanoparticles) is selectively applied on a portion of the build material, and the applied build material and coalescent dispersion are exposed to electromagnetic radiation. The coalescent dispersion absorbs the electromagnetic radiation and heats up the portion of the build material in contact therewith to fuse the portion of the build material in contact with the coalescent dispersion and to form a layer of a 3D object.

In an example of a three-dimensional (3D) printing method, a build material (consisting of an inorganic particle and a polymer attached thereto) is applied. The polymer is a continuous coating having a thickness from about 3 nm to about 1500 nm, or nano-beads having an average diameter from about 3 nm to about 1500 nm. The build material is heated to a temperature from about 5° C. to about 50° C. below the polymer's melting point. A coalescent dispersion (including a coalescent agent and inorganic nanoparticles) is selectively applied on a portion of the build material, and the applied build material and coalescent dispersion are exposed to electromagnetic radiation. The coalescent dispersion absorbs the electromagnetic radiation and heats up the portion of the build material in contact therewith to fuse the portion of the build material in contact with the coalescent dispersion and to form a layer of a 3D object.

A method for producing a molded article by injection molding may include using a heat-curable 1K polyurethane (PU) composition, as well as the molded articles obtained using said method.

A masterbatch (C) containing thermally expandable microcapsules (A) and a carrier resin composition (B) is provided. The carrier resin composition (B) contains a carrier resin (B1) and a plasticizer (B2), the carrier resin (B1) being an acrylic resin having a weight average molecular weight of 8,000 or more and 350,000 or less, and the plasticizer (B2) being an acrylic plasticizer having a weight average molecular weight of 1,000 or more and 20,000 or less. The carrier resin composition (B) is substantially compatible with a polycarbonate resin and has a shear viscosity of 1.0 Pa.Math.s or more and 1.510.sup.6 Pa.Math.s or less at 80 C. The occurrence of whitening is suppressed and a good appearance can be obtained in an injection molded foam made with the masterbatch. A polycarbonate resin composition, an injection molded foam, and a method for producing an injection molded foam are provided.

A plastic film is produced by blending a polymer with particles encapsulating an oxidizing agent, such as hydrogen peroxide. Optionally, an oxodegradable and/or oxo biodegradable additive that promotes degradation of the polymer in the presence of oxygen may be blended into the plastic film. The presence of the oxidizing agent within the plastic film ensures degradation of an article of manufacture, e.g., a plastic bag, when it is disposed of in an anaerobic environment, such as a landfill. In some embodiments, the particles are microcapsules and/or nanocapsules each having a polymer shell encapsulating a core that includes the oxidizing agent. In some embodiments, the particles are microparticles and/or nanoparticles each having a matrix in which the oxidizing agent is encapsulated.

Methods of using and repairing seal caps as well as constructions comprising seal caps, including in some embodiments seal caps which may be useful in sealing fasteners that protrude into fuel storage cells in aircraft. In some embodiments, methods include the use of optically translucent seal cap and application of a second quantity of sealant to fill voids observed within the interior of the seal cap after cure of a first quantity of sealant.

A mobile autonomous printer includes a body, a plurality of hollow arms extending outwardly from the body, a pump system in each of the plurality of hollow arms, wherein the pump system in each of the plurality of hollow arms is switchable to extrude or take in material, and a vessel disposed within the body for mixing materials prior to deposition. Articulation of the hollow arms provides for mobility of the mobile autonomous printer. A method of building a structure includes printing portions of the structure using a plurality of printers and embedding the plurality of printers into the structure. The printers embedded in the structure may function as a network of switchable pumps. Distinct conduits constructed into the structure supply chemically reacting constituents of the material that forms the structure.

A masterbatch (C) containing thermally expandable microcapsules (A) and a carrier resin composition (B) is provided. The carrier resin composition (B) contains a carrier resin (B1) and a plasticizer (B2), the carrier resin (B1) being an acrylic resin having a weight average molecular weight of 8,000 or more and 350,000 or less, and the plasticizer (B2) being an acrylic plasticizer having a weight average molecular weight of 1,000 or more and 20,000 or less. The carrier resin composition (B) is substantially compatible with a polycarbonate resin and has a shear viscosity of 1.0 Pa.Math.s or more and 1.510.sup.6 Pa.Math.s or less at 80 C. The occurrence of whitening is suppressed and a good appearance can be obtained in an injection molded foam made with the masterbatch. A polycarbonate resin composition, an injection molded foam, and a method for producing an injection molded foam are provided.

An article having at least one microneedle (160, 260) is provided. The microneedle includes a base (162), an elongated body (161) having a central axis (130) and a body diameter (168), a tip portion (166), and a hollow channel (170). The a tip portion includes a tip (164), a first bevel face (140) oriented diagonally with respect to the central axis and extending through at least 75% of the body diameter, a second bevel face (146) oriented substantially perpendicular to the central axis and intersecting the first bevel face, and a bevel opening defined by a first edge (174) of the first bevel face and a second edge (176) of the second bevel face. The hollow channel extends axially into the body from the bevel opening (172).