In the pneumatic tire including a sealant layer containing an adhesive sealant on an inner surface of a tread portion, when a thickness of the sealant layer at 0° C. is G.sub.0, a thickness of the sealant layer at 50° C. is G.sub.50, a width of the sealant layer at 0° C. is W.sub.0, and a width of the sealant layer at 50° C. is W.sub.50, a rate of change R.sub.G of thickness expressed by R.sub.G=(|G.sub.50−G.sub.0|/G.sub.0)×100 is set to 3% or less, and a rate of change R.sub.W of width expressed by R.sub.W=(|W.sub.50−W.sub.0|/W.sub.0)×100 is set to 3% or less.

In the pneumatic tire including a sealant layer containing an adhesive sealant on an inner surface of a tread portion, when a thickness of the sealant layer at 0° C. is G.sub.0, a thickness of the sealant layer at 50° C. is G.sub.50, a width of the sealant layer at 0° C. is W.sub.0, and a width of the sealant layer at 50° C. is W.sub.50, a rate of change R.sub.G of thickness expressed by R.sub.G=(|G.sub.50−G.sub.0|/G.sub.0)×100 is set to 3% or less, and a rate of change R.sub.W of width expressed by R.sub.W=(|W.sub.50−W.sub.0|/W.sub.0)×100 is set to 3% or less.

Disclosed herein is an intrinsically self-healing composite based upon in situ thermal remendability of an embedded polymeric interphase. The fiber-reinforced composite (FRC) material may incorporate a thermoset polymer with a defined glass transition temperature (T.sub.g) and/or a thermoplastic material of amorphous or semi-crystalline nature. The polymeric interphase can be incorporated as a plurality of particles, fibers, meshes, films, or 3D-printed structures. The self-healing composite includes a resistive heating component as a structural element that minimizes electrical energy demand and impact on mechanical integrity. Healing occurs in situ via resistive heating and can be enabled below, at, or above the glass-transition temperature of the FRC matrix, demonstrating viability for in-service repair under sustained loads. In addition to providing rapid healing functionality, the polymeric interphase increases inherent resistance to interlaminar fracture. Repeated heal cycles have been achieved in a double cantilever beam (DCB) fracture test without significant degradation in performance.

Disclosed herein is an intrinsically self-healing composite based upon in situ thermal remendability of an embedded polymeric interphase. The fiber-reinforced composite (FRC) material may incorporate a thermoset polymer with a defined glass transition temperature (T.sub.g) and/or a thermoplastic material of amorphous or semi-crystalline nature. The polymeric interphase can be incorporated as a plurality of particles, fibers, meshes, films, or 3D-printed structures. The self-healing composite includes a resistive heating component as a structural element that minimizes electrical energy demand and impact on mechanical integrity. Healing occurs in situ via resistive heating and can be enabled below, at, or above the glass-transition temperature of the FRC matrix, demonstrating viability for in-service repair under sustained loads. In addition to providing rapid healing functionality, the polymeric interphase increases inherent resistance to interlaminar fracture. Repeated heal cycles have been achieved in a double cantilever beam (DCB) fracture test without significant degradation in performance.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and a means for molecular scale healing is disclosed; the composition has the ability to resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer serves to bring surfaces of a structural defect into approximation, whereafter use of the means for molecular scale healing allowed for movement of the healing means into the defect and thus obtain molecular scale healing. The means for molecular scale healing can be a thermoplastic such as fibers, particles or spheres which are used by heating to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. Compositions of the invention have the ability to not only close macroscopic defects, but also to do so repeatedly even if another wound/damage occurs in a previously healed/repaired area.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and a means for molecular scale healing is disclosed; the composition has the ability to resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer serves to bring surfaces of a structural defect into approximation, whereafter use of the means for molecular scale healing allowed for movement of the healing means into the defect and thus obtain molecular scale healing. The means for molecular scale healing can be a thermoplastic such as fibers, particles or spheres which are used by heating to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. Compositions of the invention have the ability to not only close macroscopic defects, but also to do so repeatedly even if another wound/damage occurs in a previously healed/repaired area.

A sealant layer assembly which allows a sealant layer to be applied on a tire outside of tire production plants. The assembly comprises a sealant layer to be applied on the surface of an inner liner layer facing the inner cavity of a tire, a net layer arranged on a first surface of the sealant layer, and at least one non-stick protective layer arranged either on a second surface of the sealant layer opposite the first surface or on the net layer.

A sealant layer assembly which allows a sealant layer to be applied on a tire outside of tire production plants. The assembly comprises a sealant layer to be applied on the surface of an inner liner layer facing the inner cavity of a tire, a net layer arranged on a first surface of the sealant layer, and at least one non-stick protective layer arranged either on a second surface of the sealant layer opposite the first surface or on the net layer.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and methods for molecular scale healing are provided. The composition can resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer can provide molecular scale healing in a structural defect. The methods for molecular scale healing can include heating a composition including a thermoplastic such as fibers, particles or spheres to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. The compositions have the ability to close macroscopic defects repeatedly even if another wound/damage occurs in a previously healed/repaired area.

A composition comprising thermoset polymer, shape memory polymer to facilitate macro scale damage closure, and methods for molecular scale healing are provided. The composition can resolve structural defects by a bio-mimetic close-then heal process. In use, the shape memory polymer can provide molecular scale healing in a structural defect. The methods for molecular scale healing can include heating a composition including a thermoplastic such as fibers, particles or spheres to a level at or above the thermoplastic's melting point, then cooling of the composition below the melting temperature of the thermoplastic. The compositions have the ability to close macroscopic defects repeatedly even if another wound/damage occurs in a previously healed/repaired area.