An oriented film includes an orientated semi-aromatic polyester layer and a thermally conductive filler dispersed in the orientated semi-aromatic polyester layer. The thermally conductive filler is at least 20% wt. of the oriented film.

A composite member and a method for manufacturing polymeric material article are presented. The method comprising providing polymeric resin, providing selected amount of filler material, mixing filler material into the polymeric matrix to provide a polymeric filler mixture, compressing said polymeric filler mixture under pressure in the range of up to 350 bar, and curing said polymeric filler mixture to provide stable polymeric material. The resulting composite member is typically characterizes by having average filler to filler particle gap below 20 nm and substantially does not have air voids therein.

The invention provides a method for 3D printing a heat sink (100) by means of fused deposition modelling, the method comprising layer-wise depositing a 3D printable material to provide a plurality of layers (322) of a 3D printed material (202) whereby a heat receiving face (101) of the heat sink (100) is created, the plurality of layers (322) of 3D printed material (202) being configured parallel to planes (325) perpendicular to the heat receiving face (101), wherein the 3D printable material comprises particles embedded in the 3D printable material, wherein the particles have an anisotropic thermal conductivity, wherein the particles are available in the 3D printable material in an amount selected from the range of 5-40 vol. % relative to the total volume of the 3D printable material, and wherein the layers (322) of 3D printed material (202) have layer heights (H) selected from the range of at maximum 800 μm.

Shape memory polymer (SMP) epoxies and composites, and methods of manufacturing the same, are provided. A three-dimensional (3D) printing technique can be used to fabricate a pure thermoset SMP epoxy. A cryogenic sprayer assisted extrusion type 3D printing method can be used to print SMP epoxies and composites of an SMP epoxy and a nanomaterial additive, such as graphene nanoplatelets (GNP).

An energetic composite comprises a metal powder; poly(vinylidene fluoride) (PVDF); and poly(lactic acid) (PLA). The metal powder comprises micrometer- or nanometer-sized particles, and the ratio of PVDF to PLA is between about 1:3 to 3:1. The metal powder comprises between about 4-32% wt of the energetic composite, and the metal powder consists of aluminum (Al), magnesium (Mg), or boron (B). A method of making an energetic composite material, comprises melt-blending a metal powder with poly(vinylidene fluoride) (PVDF) and poly(lactic acid) (PLA).

An extruded thermoplastic product having a surface abrasive to insects. The extruded product is formed from a dry powder composition being comprised of a thermoplastic polymer, a plurality of pelletized diatomaceous earth, and a plurality of expandable microballoons. The composition is mixed and heated in an extrusion machine before being forced into a die of selected profile. Cooling the material immediately after being removed from the die allows the diatomaceous earth to remain at the surface of the material. The material with the surface abrasive to insects is used is used as a component in a product, such as conventional weatherization products, for placement in a building opening that insects use as ingress to the building. Products contemplated for use with the extrusion include door sweeps, door and window seals, and thresholds.

An oriented film includes an orientated semi-aromatic polyester layer and a thermally conductive filler dispersed in the orientated semi-aromatic polyester layer. The thermally conductive filler is at least 20% wt. of the oriented film.

A general method of manufacturing high strength ultrafine grained nanostructured carbon and carbide materials that combines densification of nanoparticles with heat treatments or other means of supplying energy to cause fusion of structures that interlink and weld the nanoparticles together. Coatings films, nanopaper, nanopaper laminates, fibers, and extended objects can be manufactured by applying the disclosed methods. The nanomaterials are useful for additive manufacturing of rapid prototyped objects. A variety of nanoparticle starting materials are divulged including but not limited to double walled carbon nanotubes, fluorinated graphene nanosheets, silicon nanowires, and boron nanoplatelets. Articles can be manufactured with spark plasma synthesis, capacitive discharge sintering, hot press apparatus and green bodies can be processed in furnaces. The nanomaterials and ultra high strength articles manufactured from them will have applications including laparoscopic instruments, structural composites, heat sinks, EMI shielding, ballistic protection and aerospace components.

An oriented film includes an orientated semi-aromatic polyester layer and a thermally conductive filler dispersed in the orientated semi-aromatic polyester layer. The thermally conductive filler is at least 20% wt. of the oriented film.

An oriented film includes an orientated semi-aromatic polyester layer and a thermally conductive filler dispersed in the orientated semi-aromatic polyester layer. The thermally conductive filler is at least 20% wt. of the oriented film.