A method for preparing a thermoplastic polyurethane film having a large thickness and excellent durability, and a thermoplastic polyurethane film prepared thereby are provided.

Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.

Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.

The invention relates to a metallocene complex according to formula (I), (I) wherein R.sub.1 and R.sub.2 are independently selected from H, an alkyl or an aryl group, wherein R.sub.3 is a C1-C10 alkyl group, wherein R′ is selected from H, an alkyl group, an aryl group and wherein different R′ substituents can be connected to form a ring structure and wherein B is a 1,2 phenylene bridging moiety, which can be optionally substituted, wherein Mt is selected from Ti, Zr and Hf, X is an anionic ligand, z is the number of X groups and equals the valence of Mt minus 2. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerisation process of olefinic monomers. ##STR00001##

Articles, such as garments, including films comprising dried aqueous polyurethane dispersions are disclosed, whereby the garment has an altered stress which is exhibited during wear of the garment and/or has one or more sections of waterproof or water-resilient fabric. The film may be bonded to the fabric of the article to provide a fabric or film laminate.

Articles, such as garments, including films comprising dried aqueous polyurethane dispersions are disclosed, whereby the garment has an altered stress which is exhibited during wear of the garment and/or has one or more sections of waterproof or water-resilient fabric. The film may be bonded to the fabric of the article to provide a fabric or film laminate.

A hose is provided capable of meeting fireproof requirements per AS1055 under no flow condition. The hose has multiple layers of fire protection comprising a silicone rubber layer impregnated with additives including zinc borate and expandable graphite.

Multilayer oriented shrink films include a skin layer and a base layer; the skin layer being on one side of the base layer, characterized in that the skin layer comprises at least one amorphous styrene-butadiene block copolymer and the base layer has a thickness greater than said skin layer and includes a polypropylene terpolymer, a polybutene-1 copolymer, a polypropylene elastomeric copolymer and at least one copolymer from the group consisting of styreneethylene/butene-styrene triblock copolymers, styrene-ethylene/propylene-styrene triblock copolymers, styrene-ethylene/butene diblock copolymers, styrene-ethylene-propylene diblock copolymers, and combinations of two or more of said triblock and diblock copolymers.

Multilayer oriented shrink films include a skin layer and a base layer; the skin layer being on one side of the base layer, characterized in that the skin layer comprises at least one amorphous styrene-butadiene block copolymer and the base layer has a thickness greater than said skin layer and includes a polypropylene terpolymer, a polybutene-1 copolymer, a polypropylene elastomeric copolymer and at least one copolymer from the group consisting of styreneethylene/butene-styrene triblock copolymers, styrene-ethylene/propylene-styrene triblock copolymers, styrene-ethylene/butene diblock copolymers, styrene-ethylene-propylene diblock copolymers, and combinations of two or more of said triblock and diblock copolymers.

A polyurethane film comprising a polyurethane resin and graphene, wherein the graphene is present in an amount of 1 to 30% by weight on the total weight of the film and consists of graphene nano-platelets, wherein at least 90% has a lateral dimension (x, y) of 50 to 50000 nm and a thickness (z) of 0.34 to 50 nm, wherein the lateral dimension is always greater than the thickness (x, y>z), wherein the C/O ratio is ≥100:1, and a preparation process thereof.