A polyolefin-based film comprising at least one layer permitting printing as a result of laser irradiation; wherein not less than 100 ppm but not greater than 3000 ppm of pigment permitting printing as a result of laser irradiation is present in all layers of the film; haze thereof is not less than 1% but not greater than 30%; and unevenness in thickness thereof in either a machine direction or a transverse direction is not less than 0.1% but not greater than 25%. An object is to provide a film capable of being printed in distinct fashion by a laser, that excels with respect to unevenness in thickness, and that is of high transparency, and at the same time provide packaging which employs such film and on which printing has been directly carried out.

A polyolefin-based film comprising at least one layer permitting printing as a result of laser irradiation; wherein not less than 100 ppm but not greater than 3000 ppm of pigment permitting printing as a result of laser irradiation is present in all layers of the film; haze thereof is not less than 1% but not greater than 30%; and unevenness in thickness thereof in either a machine direction or a transverse direction is not less than 0.1% but not greater than 25%. An object is to provide a film capable of being printed in distinct fashion by a laser, that excels with respect to unevenness in thickness, and that is of high transparency, and at the same time provide packaging which employs such film and on which printing has been directly carried out.

A shrink sleeve label is provided. Broadly, the shrink sleeve label includes an unshrunken shrink film and a varnish applied to the shrink film. The varnish is applied to the shrink film in an application area to reduce shrinking of the shrink film in the area where the varnish is applied. Additionally, the shrink sleeve label includes a secondary label that is applied to a surface of the shrink film. Further, a method of manufacturing a shrink sleeve label is provided. Broadly, the method includes providing a shrink film and seaming the shrink film into a tubular shape. Additionally, the method includes providing a secondary label and applying the secondary label to the shrink film. The secondary label is applied to the shrink film before the shrink film is applied to an article.

A shrink sleeve label is provided. Broadly, the shrink sleeve label includes an unshrunken shrink film and a varnish applied to the shrink film. The varnish is applied to the shrink film in an application area to reduce shrinking of the shrink film in the area where the varnish is applied. Additionally, the shrink sleeve label includes a secondary label that is applied to a surface of the shrink film. Further, a method of manufacturing a shrink sleeve label is provided. Broadly, the method includes providing a shrink film and seaming the shrink film into a tubular shape. Additionally, the method includes providing a secondary label and applying the secondary label to the shrink film. The secondary label is applied to the shrink film before the shrink film is applied to an article.

The invention relates to providing a method for obtaining a multilayer film for thermally inducible shrink labels, products thereof and use of such products. The invention provides a multilayer film for labelling, the multilayer film comprising a first skin layer, a second skin layer and a core layer between the first skin layer and the second skin layer, wherein at least one of the first skin layer and the second skin layer comprises cyclic olefin copolymer and the core layer comprises copolymer of ethylene and butyl acrylate or propylene terpolymer.

Multilayer oriented shrink films include a base layer and at least one skin layer on at least one side of the base layer. The at least one skin layer includes at least one amorphous styrene-butadiene block copolymer or at least one amorphous cyclic olefin copolymer. The base layer has a thickness greater than the at least one skin layer and includes a blend of: (a) at least one styrene block copolymer selected from the group consisting of styrene-ethylene/butene-styrene triblock copolymers, styrene-ethylene/propylene-styrene triblock copolymers, styrene-ethylene/butene diblock copolymers and styrene-ethylene-propylene diblock copolymers and combinations thereof; and (b) at least one propylene polymer selected from the group consisting of polypropylene terpolymers with ethylene and butene-1, propylene ethylene copolymers, propylene butene-1 copolymers and combinations thereof.

Multilayer oriented shrink films include a base layer and at least one skin layer on at least one side of the base layer. The at least one skin layer includes at least one amorphous styrene-butadiene block copolymer or at least one amorphous cyclic olefin copolymer. The base layer has a thickness greater than the at least one skin layer and includes a blend of: (a) at least one styrene block copolymer selected from the group consisting of styrene-ethylene/butene-styrene triblock copolymers, styrene-ethylene/propylene-styrene triblock copolymers, styrene-ethylene/butene diblock copolymers and styrene-ethylene-propylene diblock copolymers and combinations thereof; and (b) at least one propylene polymer selected from the group consisting of polypropylene terpolymers with ethylene and butene-1, propylene ethylene copolymers, propylene butene-1 copolymers and combinations thereof.

A hose includes an outer cover layer and at least one ply disposed inward from the outer cover layer, characterized in that the outer cover layer is a shrink sleeve, and where the at least one ply is formed from a reinforced silicone rubber sheet which includes a reinforcement. The hose may further include an inner layer disposed within the at least one ply, and which defines a lumen. The shrink sleeve may be a polyolefin shrink sleeve. The layers are tensioned together with the shrink sleeve. The hose may be prepared by a shrink tension method without the use of a tape wrap. A method of preparing the above hose may include wrapping the inner layer around a mandrel, wrapping the at least one at least one ply around the inner layer, pulling the shrink sleeve over the at least one at least one ply, and vulcanizing the hose.

An epoxy resin composition including an epoxy resin, an epoxy resin curing agent containing an amine-based curing agent, and an unsaturated fatty acid amide having from 14 to 24 carbons, a gas barrier laminate and a retort food packaging material using the epoxy resin composition, an odor-proofing or aroma-retaining packaging material, an odor-proofing or aroma-retaining method of sealing an article containing an odorous component or an aromatic component in the packaging material, a heat-shrinkable label, the production method of the heat-shrinkable label, a heat-shrunken label and a bottle having the heat-shrunken label, and a CO.sub.2 transmission prevention method.

An epoxy resin composition including an epoxy resin, an epoxy resin curing agent containing an amine-based curing agent, and an unsaturated fatty acid amide having from 14 to 24 carbons, a gas barrier laminate and a retort food packaging material using the epoxy resin composition, an odor-proofing or aroma-retaining packaging material, an odor-proofing or aroma-retaining method of sealing an article containing an odorous component or an aromatic component in the packaging material, a heat-shrinkable label, the production method of the heat-shrinkable label, a heat-shrunken label and a bottle having the heat-shrunken label, and a CO.sub.2 transmission prevention method.