A system for printing PSA on a substrate includes a rigid support structure. The system also includes a plurality of dispensing heads disposed within the rigid support structure and configured to deposit PSA solution on the substrate in response to applied pressure. Each dispensing head of the plurality of dispensing heads includes a support structure and a wicking structure disposed within the support structure and configured to hold the PSA solution, wherein the wicking structure is configured to deposit the PSA solution in a desired shape on the substrate upon contact with the substrate.

A stamping kit is disclosed. The stamping kit includes a jig, a card, and a plurality of stamps. The jig includes an upper surface, a lower surface, a front surface, a rear surface, a card slot, and a stamping slot. The card slot extends between he front surface and the rear surface, and defines a width and a height. The stamping slot extends between the upper surface and the card slot, and defines a width and a length. The card defines a width and a thickness, and is configured to slide within the card slot of the jig. Each stamp of the plurality of stamps has a proximal end configured to be engaged by a hammer, and a distal end having a character thereon. A distal portion of each stamp is configured and dimensioned to enter the stamping slot of the jig.

A stamping kit is disclosed. The stamping kit includes a jig, a card, and a plurality of stamps. The jig includes an upper surface, a lower surface, a front surface, a rear surface, a card slot, and a stamping slot. The card slot extends between he front surface and the rear surface, and defines a width and a height. The stamping slot extends between the upper surface and the card slot, and defines a width and a length. The card defines a width and a thickness, and is configured to slide within the card slot of the jig. Each stamp of the plurality of stamps has a proximal end configured to be engaged by a hammer, and a distal end having a character thereon. A distal portion of each stamp is configured and dimensioned to enter the stamping slot of the jig.

A method of applying a pattern to a nonplanar surface. A stamp has a major surface with pattern elements having a lateral dimension of greater than 0 and less than about 5 microns. The major surface of the stamp has a functionalizing molecule with a functional group selected to chemically bind to the nonplanar surface. The stamp is positioned to initiate rolling contact with the nonplanar surface, and contacts the nonplanar surface to form a self-assembled monolayer (SAM) of the functionalizing material thereon and impart the arrangement of pattern elements thereto. The major surface of the stamp is translated with respect to the nonplanar surface such that: a contact pressure is controlled at an interface between the stamping surfaces and the nonplanar surface, and a contact force at the interface is allowed to vary while the stamping surfaces and the nonplanar surface are in contact with each other.

A method of applying a pattern to a nonplanar surface. A stamp has a major surface with pattern elements having a lateral dimension of greater than 0 and less than about 5 microns. The major surface of the stamp has a functionalizing molecule with a functional group selected to chemically bind to the nonplanar surface. The stamp is positioned to initiate rolling contact with the nonplanar surface, and contacts the nonplanar surface to form a self-assembled monolayer (SAM) of the functionalizing material thereon and impart the arrangement of pattern elements thereto. The major surface of the stamp is translated with respect to the nonplanar surface such that: a contact pressure is controlled at an interface between the stamping surfaces and the nonplanar surface, and a contact force at the interface is allowed to vary while the stamping surfaces and the nonplanar surface are in contact with each other.

A method of applying a pattern to a nonplanar surface with a radius of curvature. A stamp with a major surface has a relief pattern of pattern elements extending away from a base surface. Each pattern element has a stamping surface with a lateral dimension 0 to 5 microns. An ink applied on the stamping surface includes a functionalizing molecule with a functional group that chemically binds to the nonplanar surface. The stamp is positioned to initiate rolling contact between the nonplanar surface and the major surface of the stamp. The stamping surface of the pattern elements contacts the nonplanar surface to form a self-assembled monolayer of the functionalizing material on the nonplanar surface and impart the arrangement of pattern elements. A relative position of the stamping surface is controlled with respect to the nonplanar surface while the major surface of the stamp contacts the nonplanar surface.

A method of applying a pattern to a nonplanar surface. A stamp has a major surface with pattern elements having a lateral dimension of greater than 0 and less than about 5 microns. The major surface of the stamp has a functionalizing molecule with a functional group selected to chemically bind to the nonplanar surface. The stamp is positioned to initiate rolling contact with the nonplanar surface, and contacts the nonplanar surface to form a self-assembled monolayer (SAM) of the functionalizing material thereon and impart the arrangement of pattern elements thereto. The major surface of the stamp is translated with respect to the nonplanar surface such that: a contact pressure is controlled at an interface between the stamping surfaces and the nonplanar surface, and a contact force at the interface is allowed to vary while the stamping surfaces and the nonplanar surface are in contact with each other.

A method of applying a pattern to a nonplanar surface. A stamp has a major surface with pattern elements having a lateral dimension of greater than 0 and less than about 5 microns. The major surface of the stamp has a functionalizing molecule with a functional group selected to chemically bind to the nonplanar surface. The stamp is positioned to initiate rolling contact with the nonplanar surface, and contacts the nonplanar surface to form a self-assembled monolayer (SAM) of the functionalizing material thereon and impart the arrangement of pattern elements thereto. The major surface of the stamp is translated with respect to the nonplanar surface such that: a contact pressure is controlled at an interface between the stamping surfaces and the nonplanar surface, and a contact force at the interface is allowed to vary while the stamping surfaces and the nonplanar surface are in contact with each other.

A method of applying a pattern to a nonplanar surface. A stamp has a major surface with pattern elements having a lateral dimension of greater than 0 and less than about 5 microns. The major surface of the stamp has a functionalizing molecule with a functional group selected to chemically bind to the nonplanar surface. The stamp is positioned to initiate rolling contact with the nonplanar surface, and contacts the nonplanar surface to form a self-assembled monolayer (SAM) of the functionalizing material thereon and impart the arrangement of pattern elements thereto. The major surface of the stamp is translated with respect to the nonplanar surface such that: a contact force is controlled at an interface between the stamping surfaces and the nonplanar surface, and the contact pressure at the interface is allowed to vary while the stamping surfaces and the nonplanar surface are in contact with each other.

A method of applying a pattern to a nonplanar surface. A stamp has a major surface with pattern elements having a lateral dimension of greater than 0 and less than about 5 microns. The major surface of the stamp has a functionalizing molecule with a functional group selected to chemically bind to the nonplanar surface. The stamp is positioned to initiate rolling contact with the nonplanar surface, and contacts the nonplanar surface to form a self-assembled monolayer (SAM) of the functionalizing material thereon and impart the arrangement of pattern elements thereto. The major surface of the stamp is translated with respect to the nonplanar surface such that: a contact force is controlled at an interface between the stamping surfaces and the nonplanar surface, and the contact pressure at the interface is allowed to vary while the stamping surfaces and the nonplanar surface are in contact with each other.