A laminated construct such as a ticket or game piece includes an internal on-demand thermally printable layer hidden between substantially opaque substrates. One of the substrates is a metallized film and the other substrate is a direct thermal print medium. The construct can be arranged in various ways including an arrangement for presenting some thermally printed information for immediate viewing and other thermally printed information that is temporarily hidden from view beneath the metallized film. The arrangements include arranging the metallized film as a plurality of island that are individually peelable apart from the direct thermal print medium for revealing the temporarily hidden information.

The present invention relates to a method of forming an image on a substrate comprising a transparent or translucent composition applied thereto, wherein the transparent or translucent composition comprises a protein in a non-denatured state, and the method comprises applying radiation to the transparent or translucent composition to denature the protein and thereby form an image on the substrate. The invention also relates to a method of preparing a substrate on which an image can be formed, and related substrates, compositions and uses thereof.

A drawing system according to an embodiment of the present disclosure includes a storage, an operation section, and a drawing section. The storage stores a characteristic function that derives output setting values of light sources on the basis of drawing coordinates, an absorbance correlation value, and gradation values in a leuco color space. The operation section derives the output setting values by inputting, to the characteristic function, the drawing coordinates, gradation values of leuco image data described in the leuco color space, and an absorbance correlation value obtained by measuring the recording medium. The drawing section includes the light sources, and controls output of the light sources on the basis of the output setting values derived by the operation section to thereby perform drawing on the recording medium.

A drawing system according to an embodiment of the present disclosure includes a storage, an operation section, and a drawing section. The storage stores a characteristic function that derives output setting values of light sources on the basis of drawing coordinates, an absorbance correlation value, and gradation values in a leuco color space. The operation section derives the output setting values by inputting, to the characteristic function, the drawing coordinates, gradation values of leuco image data described in the leuco color space, and an absorbance correlation value obtained by measuring the recording medium. The drawing section includes the light sources, and controls output of the light sources on the basis of the output setting values derived by the operation section to thereby perform drawing on the recording medium.

A thermochromic composition including a dye molecule; a matrix, wherein the matrix comprises a material having a defined melting point; and an optional developer. A process for preparing a thermochromic composition, including providing a dye; heating a matrix above its melting point; adding the heated matrix to the dye until the dye dissolves in the matrix; optionally, adding a developer; wherein the thermochromic composition exhibits a first color at a first temperature and a second color at a second temperature; wherein the first color and the second color are different; and wherein the first temperature and the second temperature are different.

A PTSM-coated expandable microsphere comprises a polymer shell enclosing an interior volume containing at least one blowing agent. The polymer shell has an outer surface with photothermal susceptor material disposed on at least a portion thereof. If heated to at least one temperature greater than 25° C., each of the expandable microspheres expands, but does not rupture, the polymer shell by a sufficient amount to at least double the interior volume. A markable comprises a substrate and a viewable layer secured thereto. The viewable layer comprises a binder material retaining the PTSM-coated expandable microspheres. A method of marking a markable article comprises imagewise exposing the PTSM-coated expandable microspheres of the markable article to at least sufficient electromagnetic radiation to cause the PTSM-coated expandable microspheres to expand thereby creating a predetermined image. A marked article preparable according to the method is also disclosed.

A PTSM-coated expandable microsphere comprises a polymer shell enclosing an interior volume containing at least one blowing agent. The polymer shell has an outer surface with photothermal susceptor material disposed on at least a portion thereof. If heated to at least one temperature greater than 25° C., each of the expandable microspheres expands, but does not rupture, the polymer shell by a sufficient amount to at least double the interior volume. A markable comprises a substrate and a viewable layer secured thereto. The viewable layer comprises a binder material retaining the PTSM-coated expandable microspheres. A method of marking a markable article comprises imagewise exposing the PTSM-coated expandable microspheres of the markable article to at least sufficient electromagnetic radiation to cause the PTSM-coated expandable microspheres to expand thereby creating a predetermined image. A marked article preparable according to the method is also disclosed.

The invention is directed towards a composition comprising: a near-infrared radiation absorbing compound; a colour-forming compound; and a heat transfer agent operable to facilitate heat transfer from the near-infrared radiation absorbing compound to the colour-forming compound; wherein the near-infrared radiation absorbing compound is present in an amount of 0.1-3.5 wt % of the total composition, and the heat transfer agent is present in an amount of 1-15 wt % of the total composition, and the heat transfer agent is present in the composition as solid particles. The invention further relates to substrates comprising the composition applied thereto, as well as methods of forming colour or an image on said substrates.

A security element (1) as well as a method for producing a security element (1). The security element (1), in particular a security strip or a security thread or a patch or a transfer film (2) or a laminating film or a print, for protecting security documents (3), includes at least one thermochromic element (11), wherein i) the at least one thermochromic element (11) has haptic properties; and/or ii) the security element (1) has at least one haptic layer (12).

A receipt roll for a receipt printer of a point of sale system, the receipt roll has a substrate for the printing of receipt information by the receipt printer, and at least one near field RF communicator carried by the substrate and configured to store a unique identifier for communicating via near field communications to a near Held communication device in near field range.