Provided is a thermosensitive recording medium having a sufficient water resistance to moisture and humidity, such as for outdoor use in rainy weather and the like, and also having a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like. As the protective layer comprises a specific silane-modified acrylic resin which is an aqueous emulsion of core-shell type p articles, in a thermosensitive recording medium having a thermosensitive recording layer on a substrate and a protective layer on the thermosensitive recording layer, the thermosensitive re cording medium has a sufficient water resistance and also has a superior color developing sensitivity, print image quality when printing at high speed, ink fixability and solvent resistance and the like.

Provided is a thermosensitive recording medium having excellent oil resistance among various performances required for the thermosensitive recording medium. The thermosensitive recording medium has a thermosensitive recording layer comprising a colorless or pale colored electron donating leuco dye and an electron accepting color developing agent on a substrate, wherein the thermosensitive recording layer contains N-[2-(3-phenylureido)phenyl] benzenesulfonamide and an urea-based compound represented by the general formula 1 as the electron accepting color developing agents,

##STR00001##

wherein R.sup.1 represents a substituted or unsubstituted alkyl group, aralkyl group or aryl group, and R.sup.2 represents a hydrogen atom or an alkyl group.

An object of the present invention is to provide a recording material or a recording sheet using, as a color-developing agent, a non-phenol-based compound good in color developing performance and the like. A compound represented by the following formula (I) is used as the color-developing agent: ##STR00001##
(wherein X represents CH.sub.2 or the like; R.sup.1 to R.sup.3 each independently represent a hydrogen atom, a halogen atom or the like; n1 and n3 each independently represent any integer of 1 to 5; two groups represented by R.sup.3 adjacent to each other on a benzene ring optionally bond to each other to form an optionally substituted 6-membered ring; and n2 represents any integer of 1 to 4).

A thermochromic composition including a dye molecule; a matrix, wherein the matrix comprises a material having a defined melting point; and an optional developer. A process for preparing a thermochromic composition, including providing a dye; heating a matrix above its melting point; adding the heated matrix to the dye until the dye dissolves in the matrix; optionally, adding a developer; wherein the thermochromic composition exhibits a first color at a first temperature and a second color at a second temperature; wherein the first color and the second color are different; and wherein the first temperature and the second temperature are different.

The presently claimed invention relates to a color developer, a process for its manufacture and its use as a component in heat sensitive recording material. The heat sensitive recording material is useful for thermographic printing.

A description is given of a heat-sensitive recording material, comprising phenol-free organic color developers, more particularly comprising a color developer mixture comprising phenol-free organic color developers, of a heat-sensitive recording layer and also of a coating composition for producing it, of the use of the heat-sensitive recording material, of the use of an organic color developer of a formula I for improving the resistance of the printed image of a heat-sensitive recording material, and of a method for producing heat-sensitive recording material.

The present invention relates to an N-(4-((4-(3-phenylureido)phenyl)sulfonyl)phenyl)benzenesulfonamide in the polymorphic form ω.sup.18.9, characterised by an x-ray powder diffractogram having the Bragg angles (2θ/CuK.sub.α) 10.9, 11.7, 14.6, 15.0, 15.8, 16.6, 17.6, 18.9, 19.4, 20.9, 21.2, 22.0, 23.3, 24.4, 24.7, 26.1, 27.4, 29.4, 34.2,

or in the polymorphic form α.sup.21.2, characterised by an x-ray powder diffractogram having the Bragg angles (2θ/CuK.sub.α) 8.7, 9.8, 10.8, 13.2, 13.9, 14.9, 15.2, 16.0, 17.4, 17.7, 18.7, 20.4, 21.2, 21.6, 22.3, 23.0, 23.3, 23.9, 24.4, 25.0, 25.8, 26.6, 28.1, 28.9, 29.4, 30.1, 30.6, 31.8, 34.5, 35.3, 35.6, 36.9, a method for production thereof, use thereof as a colour developer in a heat-sensitive recording material, and a heat-sensitive recording material comprising N-(4-((4-(3-phenylureido)phenyl)sulfonyl)phenyl)benzenesulfonamide in the polymorphic form ω.sup.18.9 or in the polymorphic form α.sup.21.2.

In one aspect, the present invention relates to a thermosensitive recording medium comprising at least: —a support layer; —a thermosensitive colouring layer over the support layer, the thermosensitive colouring layer containing a leuco dye; and —a protective layer over the thermosensitive colouring layer; wherein the thermosensitive colouring layer comprises a developer having the general formula (I) below: wherein R.sub.1 to R.sub.3 each independently represent a hydrogen atom, a halogen atom, a C1-C6 alkyl group, a C1-C6 alkoxyl group, a C1-C6 fluoroalkyl group; characterized in that the protective layer comprises particles of wax with an average particle size of at least 0.05 μm and at most 2.0 μm. In further aspects, the present invention relates to a label for attachment to a product comprising the thermosensitive recording medium of the invention, and to a consumer product package to which a thermosensitive recording medium or a label of the invention has been attached. ##STR00001##

A thermosensitive recording medium includes a support, and a thermosensitive recording layer disposed on or above the support, wherein the thermosensitive recording layer includes a non-phenolic color developer and a sensitizer that includes fatty acid amide, and wherein an amount of the fatty acid amide in the sensitizer is 60% by mass or greater.

The invention relates to a self-adhesive, heat-sensitive recording material, comprising a carrier substrate, a heat-sensitive, color-forming layer that is applied on one side of the carrier substrate and contains at least a non-phenolic color developer in and at least one color former, a siliconized layer on the upper side of the heat-sensitive, color-forming layer that is applied on the carrier substrate, as well as an adhesive layer on the side of the carrier substrate facing away from the heat-sensitive, color-forming layer.