Provided is an on-press development type lithographic printing plate precursor having a support, an image-recording layer, and an outermost layer in this order, in which the outermost layer has a sea-island structure consisting of a discontinuous phase that contains a hydrophobic polymer and a continuous phase that contains a water-soluble polymer. Also provided are a method of preparing a lithographic printing plate and a lithographic printing method in which the on-press development type lithographic printing plate precursor is used.

A lithographic printing plate precursor including a hydrophilized aluminum support, and a water-soluble or water-dispersible negative type image recording layer provided on the aluminum support, in which an arithmetic average height Sa of a surface of an outermost layer on a side where the image recording layer is provided is in a range of 0.3 μm to 20 μm; a method of producing a lithographic printing plate precursor; a lithographic printing plate precursor laminate formed of the lithographic printing plate precursor; a plate-making method for a lithographic printing plate; and a lithographic printing method.

Provided is a lithographic printing method including a preparing step of preparing a lithographic printing plate precursor which includes an aluminum support, and an image recording layer containing an acid color developing agent and an acid generator on the aluminum support, an exposing step of exposing the lithographic printing plate precursor, a developing step of supplying acidic dampening water to the exposed lithographic printing plate precursor and removing a non-image area of the image recording layer, and a printing step, in which the aluminum support includes an anodized aluminum film, the anodized film has micropores, and a value ΔS is 15% or greater and 60% or less.

An object of the present invention is to provide a lithographic printing plate precursor which has excellent on-press developability and is capable of suppressing generation of slip stains and from which a lithographic printing plate with satisfactory printing durability is obtained, and a method of producing a lithographic printing plate and a printing method using the lithographic printing plate precursor. The lithographic printing plate precursor of the present invention is a lithographic printing plate precursor including an aluminum support, and an image recording layer, in which the aluminum support includes an aluminum plate and an anodized aluminum film disposed on the aluminum plate, the anodized film is positioned on a side of the image recording layer with respect to the aluminum plate, the anodized film has micropores extending from a surface of the anodized film on the side of the image recording layer in a depth direction, the micropores have an opening ratio of 20% to 70%, a steepness a45 on the surface of the anodized film on the side of the image recording layer is in a range of 3% to 25%, and an arithmetic average roughness Ra on the surface of the anodized film on the side of the image recording layer is in a range of 0.25 to 0.60 μm.

Lithographic printing plate precursors have an aluminum-containing substrate prepared using two anodizing processes to provide an inner aluminum oxide layer of average dry thickness of 300-3,000 nm and a multiplicity of inner micropores of average inner micropore diameter of ≤100 nm. An outer aluminum oxide layer is provided with a multiplicity of outer micropores of average outer micropore diameter of 15-30 nm and a dry thickness of 30-650 nm. A hydrophilic layer is disposed on the outer aluminum oxide layer at 0.0002-0.1 g/m.sup.2 and has a (1) compound having an ethylenically unsaturated polymerizable groups; a —OM group connected directly to a phosphorus atom, wherein M represents hydrogen, sodium, potassium, or aluminum; and (2) one or more hydrophilic polymers having (a) recurring units comprising an amide group, and (b) recurring units having an —OM′ group that is directly connected to a phosphorus atom, wherein M′ represents hydrogen, sodium, potassium, or aluminum.

Provided is an on-press development type lithographic printing plate precursor including an aluminum support and an image-recording layer on the aluminum support, in which the image-recording layer contains an infrared absorber, a polymerization initiator, a polymerizable compound, and an addition polymerization-type resin having a hydrophilic structure, a water contact angle on a surface of the aluminum support on a side of the image-recording layer that is determined by an airborne water droplet method is 110° or less, and the polymerizable compound includes a polymerizable compound having 7 or more functional groups. Also provided are a method for preparing a lithographic printing plate and a lithographic printing method using the lithographic printing plate precursor.

Lithographic printing plate precursors are prepared with a unique aluminum-containing substrate prepared using two separate anodizing processes to provide an inner aluminum oxide layer of average dry thickness (T.sub.i) of 300-3,000 nm and a multiplicity of inner micropores of average inner micropore diameter (D.sub.i) of ≤100 nm. An outer aluminum oxide layer is also provided to have a multiplicity of outer micropores of average outer micropore diameter (D.sub.o) of 15-30 nm and a dry thickness (T.sub.o) of 30-650 nm. A hydrophilic layer disposed on the outer aluminum oxide layer at 0.0002-0.1 g/m.sup.2 has at least a hydrophilic copolymer composed of (a) recurring units having an amide group and (b) recurring units comprising an —OM group directly connected to a phosphorus atom, wherein M represents a hydrogen, sodium, potassium, or aluminum atom.

An object of the present invention is to provide a lithographic printing plate precursor from which a lithographic printing plate with excellent oil-based cleaner printing durability is obtained, a method of producing a lithographic printing plate, a printing method, and a method of producing an aluminum support. The lithographic printing plate precursor of the present invention is a lithographic printing plate precursor including an aluminum support, and an image recording layer disposed on the aluminum support, in which the aluminum support includes an aluminum plate and an anodized aluminum film disposed on the aluminum plate, the image recording layer is disposed on the aluminum support on a side of the anodized film, and an area ratio of projections with a height of 0.80 μm or greater from an average level, which is obtained by measuring a surface of the aluminum support on a side of the image recording layer in an area of 400 μm×400 μm using a non-contact three-dimensional roughness meter, is 20% or less.

Lithographic printing plate precursors have an aluminum-containing substrate prepared using two anodizing processes to provide an inner aluminum oxide layer of average dry thickness of 300-3,000 nm and a multiplicity of inner micropores of average inner micropore diameter of ≤100 nm. An outer aluminum oxide layer is provided with a multiplicity of outer micropores of average outer micropore diameter of 15-30 nm and a dry thickness of 30-650 nm. A hydrophilic layer is disposed on the outer aluminum oxide layer at 0.0002-0.1 g/m.sup.2 and has a (1) compound having an ethylenically unsaturated polymerizable groups; a —OM group connected directly to a phosphorus atom, wherein M represents hydrogen, sodium, potassium, or aluminum; and (2) one or more hydrophilic polymers having (a) recurring units comprising an amide group, and (b) recurring units having an —OM′ group that is directly connected to a phosphorus atom, wherein M′ represents hydrogen, sodium, potassium, or aluminum.

IR-sensitive lithographic printing plate precursors provide a stable print-out image using a unique IR radiation-sensitive composition in an infrared radiation-sensitive image-recording layer. This IR radiation-sensitive composition includes: (1) a free radical initiator composition that comprises an electron-donating agent; (2) a free radically polymerizable composition; and (3) a color-changing compound that is represented by the Structure (I) having a conjugated carbon chain between the aromatic terminal groups. The compound also has a —SO.sub.2—R.sup.3 group wherein R.sup.3 represents alkyl, aryl or heteroaryl groups. After IR imaging, these precursors exhibit desirable printout images both fresh and after dark storage. The precursors can be developed off-press or on-press.