The use of a modified reduced indium tin oxide to provide a security image wherein the modified reduced indium tin oxide is obtained by heating indium tin oxide in a reducing atmosphere at a temperature of from 300 to 500° C.; and contacting the reduced indium tin oxide with an organophosphorus compound.

There is described a method of manufacturing a security article, said method comprising the steps of: introducing into an offset printing device a transparent film comprising a non-fibrous substrate layer of regenerated cellulose; disposing an opacification layer on at least a portion of at least one surface of said film by a first offset printing step; and disposing printed information on at least a portion of said opacification layer by a second offset printing step.

There is described a method of manufacturing a security article, said method comprising the steps of: introducing into an offset printing device a transparent film comprising a non-fibrous substrate layer of regenerated cellulose; disposing an opacification layer on at least a portion of at least one surface of said film by a first offset printing step; and disposing printed information on at least a portion of said opacification layer by a second offset printing step.

A method for marking a product (1) with a photoluminescent mark, said mark comprising a photoluminescent portion (10) which is transparent under normal light conditions and revealed by photoluminescence under UV illumination, said mark further comprising a non photoluminescent portion (9) which is transparent under normal light conditions as well s under UV illumination, said method comprising: deposing on said product a stack, said stack comprising alternatively layers (2,4) such as AlN, with a thickness of less than 1 micron and layers (3) of a second material, such as GaN with a thickness of less than 10 nm; raising the transparency of said non photoluminescent portion (10) with a deposition of transparent material (6) or incorporation of ions into said non photoluminescent portions.

A method for marking a product (1) with a photoluminescent mark, said mark comprising a photoluminescent portion (10) which is transparent under normal light conditions and revealed by photoluminescence under UV illumination, said mark further comprising a non photoluminescent portion (9) which is transparent under normal light conditions as well s under UV illumination, said method comprising: deposing on said product a stack, said stack comprising alternatively layers (2,4) such as AlN, with a thickness of less than 1 micron and layers (3) of a second material, such as GaN with a thickness of less than 10 nm; raising the transparency of said non photoluminescent portion (10) with a deposition of transparent material (6) or incorporation of ions into said non photoluminescent portions.

The present invention relates to security, or decorative elements, comprising a transparent, or translucent substrate, which may contain indicia or other visible features in or on its surface, and on at least part of the substrate surface, a first layer, comprising transition metal particles having an average diameter of from 5 nm to 500 nm and a binder, on at least part of the first layer a second layer, comprising an organic material and having a refractive index of from 1.2 to 2.3 and having a thickness of from 20 to 1000 nm, wherein the transition metal is silver, copper, gold and palladium, wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 20:1 to 1:2 in case the binder is a polymeric binder, or wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 5:1 to 1:15 in case the binder is an UV curable binder. The security or decorative element show a certain color in transmission and a different color in reflection and a color flop on the coating side. The color in reflection and the color flop of the security or decorative elements are controlled by adjusting the refractive index and thickness of the second layer.

The present invention relates to security, or decorative elements, comprising a transparent, or translucent substrate, which may contain indicia or other visible features in or on its surface, and on at least part of the substrate surface, a first layer, comprising transition metal particles having an average diameter of from 5 nm to 500 nm and a binder, on at least part of the first layer a second layer, comprising an organic material and having a refractive index of from 1.2 to 2.3 and having a thickness of from 20 to 1000 nm, wherein the transition metal is silver, copper, gold and palladium, wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 20:1 to 1:2 in case the binder is a polymeric binder, or wherein the weight ratio of transition metal particles to binder in the first layer is in the range from 5:1 to 1:15 in case the binder is an UV curable binder. The security or decorative element show a certain color in transmission and a different color in reflection and a color flop on the coating side. The color in reflection and the color flop of the security or decorative elements are controlled by adjusting the refractive index and thickness of the second layer.

There is described a method of manufacturing a security article, said method comprising the steps of: introducing into an offset printing device a transparent film comprising a non-fibrous substrate layer of regenerated cellulose; and disposing printed information on at least a portion of said transparent film by an offset printing step, wherein said transparent film introduced into said offset printing device further comprises an ink-receptive layer on at least one surface of said substrate layer.

There is described a method of manufacturing a security article, said method comprising the steps of: introducing into an offset printing device a transparent film comprising a non-fibrous substrate layer of regenerated cellulose; and disposing printed information on at least a portion of said transparent film by an offset printing step, wherein said transparent film introduced into said offset printing device further comprises an ink-receptive layer on at least one surface of said substrate layer.

The present invention relates to a security marker; a method of preparing same; the use of said security marker; a security article, document, or element comprising said marker; the use of said security article, document, or element; an object of value comprising said marker; a method of preparing said security article, document, or element or said object of value; a method for determining the authenticity of said security article, document, or element or said object of value; and a system for determining the authenticity of said security article, document, or element or said object of value.