A system and method for co-producing ultra-high purity oxygen and ultra-high purity hydrogen from a water electrolysis unit is provided. The presently disclosed system and method includes upgrading the crude oxygen stream coming from the water electrolysis unit by means of a small, stand-alone cryogenic distillation system wherein the refrigeration for such cryogenic distillation system is supplied by a nitrogen recycle refrigeration loop.

A binderless zeolite adsorbent for separation of oxygen from a gaseous stream. The adsorbent is a blend of a lithium exchanged zeolite 13X, a lithium exchanged low silica zeolite X zeolite, and halloysite clay. Also disclosed is a process of making the binderless zeolite adsorbent. Further disclosed is a process for production of oxygen from a gaseous stream utilizing the binderless zeolite adsorbent.

A perovskite oxygen carrier having the formula Sr.sub.1-xCa.sub.xFe.sub.1-yNi.sub.yO.sub.3, where 0.05<x<0.30 and 0.001<y<0.125 and a method of using the perovskite carrier to carry oxygen. A mesoporous perovskite oxygen carrier having the formula Sr.sub.1-xCa.sub.xFeO.sub.3, where 0.01<x<0.40 and methods for making and using the mesoporous perovskite oxygen carrier.

An improved method and system of carbon sequestration of a pyrolysis piston engine power system is provided. The system includes a pyrolysis piston engine for generating power and exhaust gas and a water cooling and separation unit which receives the exhaust gas and cools and removes water from the exhaust gas to create C02 gas supply. The system also includes a mixing pressure vessel which receives at least a portion of the C02 gas supply from the water cooling and separation unit and mixes the C02 gas supply with oxygen to create a working fluid to be provided to the piston engine and an oxygen generator for providing oxygen to the mixing pressure vessel. The system also includes a pyrolysis interface for inputting byproducts from a pyrolysis system, wherein the pyrolysis interface comprises a pyrolysis gas interface and a pyrolysis gas/oil interface.

An improved method and system of carbon sequestration of a pyrolysis piston engine power system is provided. The system includes a pyrolysis piston engine for generating power and exhaust gas and a water cooling and separation unit which receives the exhaust gas and cools and removes water from the exhaust gas to create C02 gas supply. The system also includes a mixing pressure vessel which receives at least a portion of the C02 gas supply from the water cooling and separation unit and mixes the C02 gas supply with oxygen to create a working fluid to be provided to the piston engine and an oxygen generator for providing oxygen to the mixing pressure vessel. The system also includes a pyrolysis interface for inputting byproducts from a pyrolysis system, wherein the pyrolysis interface comprises a pyrolysis gas interface and a pyrolysis gas/oil interface.

An apparatus and process for oxygen production can be configured to utilize flash vapor losses, recovery of regeneration heat and/or utilize a compressor to provide better heat integration and/or less wasteful processing for the recovery of oxygen that can be obtained from electrolysis (e.g., operation of one or more electrolyzers). Some embodiments may utilize all three of these features while other embodiments may use only one of these features or a combination of two of these features.