C01B15/023

INTEGRATED PROCESS FOR MAKING PROPENE OXIDE AND AN ALKYL TERT-BUTYL ETHER

An integrated process for making propene oxide and an alkyl tert-butyl ether comprises dehydrogenating a feed stream comprising propane and iso-butane to provide a stream comprising propene, iso-butene and hydrogen; separating this stream into a stream consisting essentially of hydrogen and a stream comprising propene and iso-butene; separating the stream comprising propene and iso-butene into a stream comprising propene and a stream comprising iso-butene; reacting a part or all of the stream comprising iso-butene with an alkanol in the presence of a solid acid catalyst to provide an alkyl tert-butyl ether; and reacting a part or all of the stream comprising propene with hydrogen peroxide in the presence of an epoxidation catalyst to provide propene oxide.

INTEGRATED PROCESS FOR MAKING PROPENE OXIDE AND AN ALKYL TERT-BUTYL ETHER

An integrated process for making propene oxide and an alkyl tert-butyl ether comprises dehydrogenating a feed stream comprising propane and iso-butane to provide a stream comprising propene, iso-butene and hydrogen; separating this stream into a stream consisting essentially of hydrogen and a stream comprising propene and iso-butene; separating the stream comprising propene and iso-butene into a stream comprising propene and a stream comprising iso-butene; reacting a part or all of the stream comprising iso-butene with an alkanol in the presence of a solid acid catalyst to provide an alkyl tert-butyl ether; and reacting a part or all of the stream comprising propene with hydrogen peroxide in the presence of an epoxidation catalyst to provide propene oxide.

CATALYST FOR SYNTHESIS OF HYDROGEN PEROXIDE AND RECOVERY, AND METHOD OF PREPARING SAME
20220331789 · 2022-10-20 ·

Described is a catalyst for preparing hydrogen peroxide by an anthraquinone process and for regenerating a working solution and a method of preparing the catalyst. The catalyst contains palladium, magnesium, and cerium components uniformly distributed in alumina. Alternatively, the catalyst contains a palladium component distributed in a ring shape in an alumina sphere and magnesium and cerium components uniformly distributed in the alumina.

CATALYST FOR SYNTHESIS OF HYDROGEN PEROXIDE AND RECOVERY, AND METHOD OF PREPARING SAME
20220331789 · 2022-10-20 ·

Described is a catalyst for preparing hydrogen peroxide by an anthraquinone process and for regenerating a working solution and a method of preparing the catalyst. The catalyst contains palladium, magnesium, and cerium components uniformly distributed in alumina. Alternatively, the catalyst contains a palladium component distributed in a ring shape in an alumina sphere and magnesium and cerium components uniformly distributed in the alumina.

METHODS AND APPARATUS FOR PRODUCING HYDROGEN PEROXIDE

Apparatuses and methods for producing hydrogen peroxide by performing coupled chemical and electrochemical reactions are disclosed. An electrochemical cell has a chemical reaction chamber configured to hydrogenate a shuttle molecule and an electrochemical chamber configured to electrochemically dissociate water to form hydrogen ions at an anode, and to reduce the hydrogen ions to atomic hydrogen at a cathode. The chemical reaction chamber and the anode chamber are separated by a metallic membrane. The metallic membrane acts as a cathode of the cell, a hydrogen-selective layer and a catalyst. The metallic membrane may comprise a layer of palladium or a palladium alloy. A layer of co-catalyst may optionally be electrodeposited on the layer of palladium or palladium alloy. An ion exchange membrane separates the metallic membrane and the anode chamber. The hydrogenated shuttle molecule may be supplied to a reactor for contacting an oxygen-containing gas to yield hydrogen peroxide.

Composition, composition reservoir, and method for producing composition
11192786 · 2021-12-07 · ·

A composition including hydrogen peroxide is provided, which can be used for semiconductor device manufacturing and which exhibits an excellent storage stability and has a reduced effect of defects on a semiconductor substrate. Further, a method is provided for producing the composition including hydrogen peroxide, and a composition reservoir for storing the composition. The composition includes hydrogen peroxide, an acid, and an Fe component, in which the content of the Fe component is 10.sup.−5 to 10.sup.2 in terms of mass ratio with respect to the content of the acid.

Composition, composition reservoir, and method for producing composition
11192786 · 2021-12-07 · ·

A composition including hydrogen peroxide is provided, which can be used for semiconductor device manufacturing and which exhibits an excellent storage stability and has a reduced effect of defects on a semiconductor substrate. Further, a method is provided for producing the composition including hydrogen peroxide, and a composition reservoir for storing the composition. The composition includes hydrogen peroxide, an acid, and an Fe component, in which the content of the Fe component is 10.sup.−5 to 10.sup.2 in terms of mass ratio with respect to the content of the acid.

DEVICE AND PROCESS FOR PRODUCING HYDROGEN PEROXIDE BY AN ANTHRAQUINONE PROCESS

In a cyclic anthraquinone process for producing hydrogen peroxide, which comprises a distillation unit with vapor compression for concentrating hydrogen peroxide, aqueous condensate from the distillation unit is passed over a bed of a cation exchange resin in its protonated from to provide a purified condensate, and the purified condensate is used as extractant for extracting hydrogen peroxide in the anthraquinone process, as column reflux for the distillation unit or as a diluent for diluting an aqueous hydrogen peroxide solution.

DEVICE AND PROCESS FOR PRODUCING HYDROGEN PEROXIDE BY AN ANTHRAQUINONE PROCESS

In a cyclic anthraquinone process for producing hydrogen peroxide, which comprises a distillation unit with vapor compression for concentrating hydrogen peroxide, aqueous condensate from the distillation unit is passed over a bed of a cation exchange resin in its protonated from to provide a purified condensate, and the purified condensate is used as extractant for extracting hydrogen peroxide in the anthraquinone process, as column reflux for the distillation unit or as a diluent for diluting an aqueous hydrogen peroxide solution.

Method for separating 2-alkylanthracenes and use thereof for producing hydrogen peroxide

A method for preparing 2-alkylanthracene includes the step of separating 2-alkylanthracene from a reaction product of anthracene alkylation reaction. The anthracene alkylation reaction is a reaction of anthracene and an alkylation reagent under an alkylation condition and in the presence of an alkylation reaction solvent and a catalyst. The reaction product of the anthracene alkylation reaction contains anthracene and the product of a series of alkylanthracenes containing 2-alkylanthracene.