A process and apparatus for managing hydrogen sulfide in a refinery is provided. In the process, a hydrogen sulfide stream from said refinery is fed to a sulfur recovery unit to produce sulfur and a sulfur compound stream or to a thermal oxidizer. The sulfur compound stream and the hydrogen sulfide stream are then thermally oxidized to produce a sulfur oxide stream. The sulfur oxide stream is then reacted with an ammonia stream. In aspect, the product of the reaction can be a fertilizer. The ammonia stream can be obtained from stripping the hydrogen sulfide stream.

A process and apparatus for managing hydrogen sulfide in a refinery is provided. In the process, a hydrogen sulfide stream from said refinery is fed to a sulfur recovery unit to produce sulfur and a sulfur compound stream or to a thermal oxidizer. The sulfur compound stream and the hydrogen sulfide stream are then thermally oxidized to produce a sulfur oxide stream. The sulfur oxide stream is then reacted with an ammonia stream. In aspect, the product of the reaction can be a fertilizer. The ammonia stream can be obtained from stripping the hydrogen sulfide stream.

The present invention is directed at the conversion of ammonium nitrate and related compounds upon reaction with methane into compounds such as ethyl acetate, ammonia, nitrogen and hydrogen. The reaction may proceed within a fluid-solid type reactor. The reaction may be facilitated in the presence of inert or catalytic solids.

The present invention is directed at the conversion of ammonium nitrate and related compounds upon reaction with methane into compounds such as ethyl acetate, ammonia, nitrogen and hydrogen. The reaction may proceed within a fluid-solid type reactor. The reaction may be facilitated in the presence of inert or catalytic solids.

Proposed is a moisture removal device using a rotating disk and nitrogen peeling according to the present disclosure may include a circulation pump unit for circulating the oil in the storage tank connected to the circulation pump on one side of the device body via a valve, a chamber for exposing the oil circulated through the circulation pump unit into the chamber headspace through the rotation of the plurality of rotating disks, and a membrane unit that supplies dry nitrogen gas to oil exposed in the chamber headspace through rotation of a plurality of rotating disks of the chamber. The moisture removal device may remove free moisture, emulsified moisture, and dissolved moisture in oil contaminated with moisture through dry nitrogen gas purging by using a continuously rotating disk.

A method for ammonia decomposition to produce hydrogen, the method comprising the steps of introducing an ammonia stream to a reactor, wherein the ammonia stream comprises ammonia, wherein the reactor comprises a cobalt-based catalyst, the cobalt-based catalyst comprising 15 wt % and 70 wt % of cobalt, 5 wt % and 45 wt % of cerium, and 0.4 wt % and 0.5 wt % barium, wherein a remainder of weight of the cobalt-based catalyst is oxygen; contacting the ammonia in the ammonia stream with the cobalt-based catalyst, wherein the cobalt-based catalyst is operable to catalyze an ammonia decomposition reaction; catalyzing the ammonia decomposition reaction to cause the ammonia decomposition in the presence of the cobalt-based catalyst to produce hydrogen; and withdrawing a product stream from the reactor, the product stream comprising hydrogen.

Methods and catalysts for oxidizing ammonia to nitrogen are described. Specifically, diruthenium complexes that spontaneously catalyze this reaction are disclosed. Accordingly, the disclosed methods and catalysts can be used in various electrochemical cell-based energy storage and energy production applications that could form the basis for a potential nitrogen economy.

Methods and catalysts for oxidizing ammonia to nitrogen are described. Specifically, diruthenium complexes that spontaneously catalyze this reaction are disclosed. Accordingly, the disclosed methods and catalysts can be used in various electrochemical cell-based energy storage and energy production applications that could form the basis for a potential nitrogen economy.

A catalyst bed includes a structure defining a plurality of channels configured to receive flow of fluid to be chemically catalyzed. The plurality of channels are oriented at least partially non-parallel to an overall flow direction of the flow from inputs of the plurality of channels to outputs of the plurality of channels. A catalyst is exposed at an exterior of the structure.

The invention relates to a method for nitrogen removal from aqueous medium, comprising steps of (a) converting NH.sub.4.sup.+ in the aqueous medium to NO.sub.2.sup.− by partial aerobic nitrification, (b) partially reducing the obtained NO.sub.2.sup.− to N.sub.2O in anoxic conditions, and (c) decomposing N.sub.2O to N.sub.2 with energy recovery. A mixture of ferrous sulfate and ferric sulfate is used in step (b) for reduction of NO.sub.2.sup.− to N.sub.2O.