Disclosed are apparatuses, systems, methods, and devices for generating hydrogen pyrolysis of hydrocarbons (methane, diesel, JP8, etc.) in a reactor. The reactor includes multiple channels in parallel. A hydrocarbon flows in a channel and decomposes into hydrogen and carbon. Hydrogen gas flows out and some of the carbon will deposit on the channel wall. Once carbon deposition reaches a predetermined level, the hydrocarbon flow stops, and air or oxygen is caused to flow into the channels to oxidize carbon into carbon monoxide or carbon dioxide and supply heat to neighboring channels. Simultaneously, the hydrocarbon will flow into neighboring channels causing decomposition into hydrogen and carbon in the neighboring channels. When the carbon coating in the neighboring channels reaches a predetermined level, the gas flow is switched again to air or oxygen. In this way, each channel alternates between decomposing the hydrocarbon and oxidizing the deposited carbon.

A process for the manufacture of a useful product from carbonaceous feedstock of fluctuating compositional characteristics, comprising the steps of: continuously providing the carbonaceous feedstock of fluctuating compositional characteristics to a gasification zone; gasifying the carbonaceous feedstock in the gasification zone to obtain raw synthesis gas; recovering at least part of the raw synthesis gas from the gasification zone and supplying at least part of the recovered raw synthesis gas to a partial oxidation zone; equilibrating the H.sub.2:CO ratio of the raw synthesis gas in the partial oxidation zone to obtain equilibrated synthesis gas; recovering at least part of the equilibrated synthesis gas from the partial oxidation zone and treating the gas to remove impurities and generate a fine synthesis gas; and converting the optionally adjusted fine synthesis gas into the useful product in a further chemical reaction requiring a usage ratio.

Provided is a process capable of converting the cokes on spent catalysts in a fluid catalytic cracking (FCC) process into synthesis gas. The produced synthesis gas contains high concentrations of CO and H.sub.2 and may be utilized in many downstream applications such as syngas fermentation for alcohol production, hydrogen production and synthesis of chemical intermediates. A reducer/regenerator reactor for a fluid catalytic process comprising a chemical looping system to produce synthesis gas is also described.

The invention provides a system and method for conversion of raw syngas and tars into refined syngas, while optionally minimizing the parasitic losses of the process and maximizing the usable energy density of the product syngas. The system includes a reactor including a refining chamber for refining syngas comprising one or more inlets configured to promote at least two flow zones: a central zone where syngas and air/process additives flow in a swirling pattern for mixing and combustion in the high temperature central zone; at least one peripheral zone within the reactor which forms a boundary layer of a buffering flow along the reactor walls, (b) plasma torches that inject plasma into the central zone, and (c) air injection patterns that create a recirculation zone to promotes mixing between the high temperature products at the core reaction zone of the vessel and the buffering layer, wherein in the central zone, syngas and air/process additives mixture are ignited in close proximity to the plasma arc, coming into contact with each other, concurrently, at the entrance to the reaction chamber and method of using the system.

A burner for producing synthesis gas by partial oxidation of liquid or gaseous, carbon-containing fuels in the presence of an oxygen-containing oxidant and a moderator, which burner can be operated uncooled, i.e. without a fluid coolant being passed through the burner, is proposed. Steam or carbon dioxide or else mixtures of these materials are used as moderator. This is achieved by the feed channels being configured so that mixing of the fuel, the moderator and the oxidant occurs only outside the burner.

The invention relates to the chemical industry and can be used for processing methane and other volatile, liquid, solid fusible hydrocarbons when producing hydrogen, soot, and other flammable gases. The invention relates to a method for the pyrolytic decomposition of hydrocarbons, in which a pyrolysis reactor arranged in a space bounded by a lining is heated by flue gases generated by combusting a hydrogen-enriched mixture of air and gaseous hydrocarbons, while ensuring a maximum decrease in CO.sub.2 emissions into the atmosphere. The invention also relates to a unit for the pyrolytic decomposition of hydrocarbons. The technical result is a high degree of separation of hydrogen and carbon by fast high-temperature pyrolysis at atmospheric pressure without oxygen supply and without CO.sub.2 production.

A process and a plant are proposed for producing a synthesis gas including hydrogen and carbon oxides by partial oxidation of carbon-containing fuel in the presence of an oxygen-containing oxidant and a moderator, wherein the obtained raw synthesis gas is laden with soot particles. According to the invention the cooling of the raw synthesis gas is carried out using a crossflow heat exchanger, a shell and tube heat exchanger or a spiral heat exchanger, wherein the carbon-containing input stream or the oxidant stream or the moderator stream or a plurality of these streams serve as the first coolant and are thus preheated before introduction into the partial oxidation plant.

A reforming device is provided with: a reformer in which an ammonia gas is burnt by air to generate heat to reform the ammonia gas utilizing the generated heat; a supply pipe through which a gas comprising the ammonia gas and air to be fed to the reformer flows; a gas inlet which is arranged in the supply pipe and through which the ammonia gas and air are introduced into the inside of the supply pipe in such a manner that a tubular flow can be generated; an igniter which can ignite the ammonia gas introduced into the inside of the supply pipe through the gas inlet; and an ammonia gas inlet which is arranged in the supply pipe on a side closer to the reformer than the gas inlet and through which the ammonia gas is introduced into the inside of the supply pipe.

The present disclosure relates to systems and methods useful for power production. In particular, a power production cycle utilizing CO.sub.2 as a working fluid may be configured for simultaneous hydrogen production. Beneficially, substantially all carbon arising from combustion in power production and hydrogen production is captured in the form of carbon dioxide. Further, produced hydrogen (optionally mixed with nitrogen received from an air separation unit) can be input as fuel in a gas turbine combined cycle unit for additional power production therein without any atmospheric CO.sub.2 discharge.

What is described is an integrated steel mill and a bioreactor configured to produce useful products from the waste stream of the steel mill. A waste gas stack which is connected to the steel mill is connected to a heat exchanger to cool the waste gas from the steel mill. The cooled gas is pressurized using a pressurization apparatus connected to the heat exchanger. The pressurized gas is sent to an oxygen removal apparatus connected to the pressurization apparatus. An oxygen depleted waste stream from the oxygen removal apparatus is passed to a bioreactor (connected to the oxygen removal apparatus) where microorganisms ferment the waste stream to products. Optional apparatus such as scrubbers, valves, buffers, are also disclosed. The products of the fermentation in the bioreactor can be ethanol and or acetate.