Disclosed are apparatuses, systems, methods, and devices for generating hydrogen pyrolysis of hydrocarbons (methane, diesel, JP8, etc.) in a reactor. The reactor includes multiple channels in parallel. A hydrocarbon flows in a channel and decomposes into hydrogen and carbon. Hydrogen gas flows out and some of the carbon will deposit on the channel wall. Once carbon deposition reaches a predetermined level, the hydrocarbon flow stops, and air or oxygen is caused to flow into the channels to oxidize carbon into carbon monoxide or carbon dioxide and supply heat to neighboring channels. Simultaneously, the hydrocarbon will flow into neighboring channels causing decomposition into hydrogen and carbon in the neighboring channels. When the carbon coating in the neighboring channels reaches a predetermined level, the gas flow is switched again to air or oxygen. In this way, each channel alternates between decomposing the hydrocarbon and oxidizing the deposited carbon.

Systems and methods for molten media pyrolysis for the conversion of methane into hydrogen and carbon-containing particles are disclosed. The systems and methods include the introduction of seed particles into the molten media to facilitate the growth of larger, more manageable carbon-containing particles. Additionally or alternatively, the systems and methods can include increasing the residence time of carbon-containing particles within the molten media to facilitate the growth of larger carbon-containing particles.

An apparatus for generating hydrogen from solid carbonaceous feed stock for production of electricity, chemicals, or fuels using all-steam gasification includes a micronized char preparation system comprising a devolatilizer and an indirect all-steam gasifier generating syngas. A syngas cooler is configured to at least partial quench the syngas and can to produce steam. A syngas clean up system removes ash and residual carbon, a carbon-capture system includes a water gas shift system and CO.sub.2 removal system. A pressure swing absorber (PSA) generating tailgas. An oxygen-fueled burner receives tailgas from the PSA and provides heat to a sorbent enhanced reformer (SER) battery limit system. A hydrogen cooler receives tailgas from the PSA that provides heat to the SER battery limit system. A CO.sub.2 cooler receives tailgas from the PSA that providing heat to the sorbent enhanced reformer battery limit system.

A process for producing hydrogen and pyrolytic carbon from hydrocarbons may involve converting hydrocarbons into hydrogen and carbon in a reactor at temperatures of 1000° C. or more. The reactor may include two electrodes spaced apart from one another in a flow direction of the hydrocarbons. In a region of the reactor between the electrodes an inert gas component is supplied over an entire reactor cross section. The reactor contains carbon particles in the region between the two electrodes. By introducing an inert gas component over the entire reactor cross section, deposition of carbon in this region of the reactor inner wall is prevented, thus effectively inhibiting the formation of conductivity bridges on the reactor inner wall.

A circular carbon process involves: a) reacting hydrogen and carbon monoxide to produce methane and water, b) decomposing methane into carbon and hydrogen, and c) using carbon as reducing agent and/or using carbon in a carbon-containing material as reducing agent, in a chemical process to produce carbon monoxide and a reduced substance. The methane produced in a) is used in b), the carbon produced in b) is used in c), and carbon monoxide produced in c) is used in a).

A fuel reforming apparatus includes a pre-reformer that converts a fuel gas to methane by bringing the fuel gas into a reaction with water, a reformer that generates a mixture gas including hydrogen by bringing the fuel gas pre-reformed by the pre-reformer into a reaction with the water, a reformer burner that supplies heat to the reformer, and an exhaust gas supply line that causes an exhaust gas discharged from the reformer burner to be supplied to the pre-reformer as a heat source for the reaction of the pre-reformer.

Provided herein are novel devices, systems, and methods of using the same, that enable plasma-enhanced pyrolysis of biogenic waste material comprising pyrolysis systems including primary tuyeres for introduction of natural gas directly to a molten lava bed, one or more plasma torches for introducing inert gas into the system, together with mechanisms for capture and collection of combustion products including, but not limited to, turquoise hydrogen and carbon black.

The invention relates to the chemical industry and can be used for processing methane and other volatile, liquid, solid fusible hydrocarbons when producing hydrogen, soot, and other flammable gases. The invention relates to a method for the pyrolytic decomposition of hydrocarbons, in which a pyrolysis reactor arranged in a space bounded by a lining is heated by flue gases generated by combusting a hydrogen-enriched mixture of air and gaseous hydrocarbons, while ensuring a maximum decrease in CO.sub.2 emissions into the atmosphere. The invention also relates to a unit for the pyrolytic decomposition of hydrocarbons. The technical result is a high degree of separation of hydrogen and carbon by fast high-temperature pyrolysis at atmospheric pressure without oxygen supply and without CO.sub.2 production.

A cooler installed to cool NG supplied from a compressor to a pyrolysis reactor and configured to independently use multiple refrigerants is provided; a first refrigerant supply device provided to supply a first refrigerant for the cooler; and a second refrigerant supply device configured to supply, to the cooler, a fuel gas for a burner, including an off-gas and NG which has not passed through the compressor, as a second refrigerant for the cooler.

A method can be used for operating a descending moving bed reactor with flowable granular material. The method involves: (i) filling an upper lock-hopper with granular material and/or emptying a lower lock-hopper, (ii) purging the lock-hoppers with purging gas, and (iii) filling the reaction chamber containing a descending moving bed from the upper lock-hopper and/or emptying the reaction chamber into the lower lock-hopper. The pressure equalization between the reaction chamber and lock-hopper is achieved with product gas. The method then involves: (iv) optionally, relieving the lock-hoppers and conveying the product gas flow into the product line, and (v) purging the lock-hoppers with purging gas.