A process for production of ammonia includes: providing a reaction stream including carbon monoxide and hydrogen; passing the reaction stream and steam over a water gas shift catalyst in a catalytic shift reactor, forming a shifted gas mixture depleted in carbon monoxide and enriched in hydrogen; passing the shifted gas mixture with an oxygen-containing gas over a selective oxidation catalyst at ≧175° C., forming a selectively oxidized gas stream with a portion of the carbon monoxide converted to carbon dioxide; removing some of the carbon dioxide from the selectively oxidized gas stream in a carbon dioxide removal unit; passing the carbon dioxide depleted stream over a methanation catalyst in a methanator to form a methanated gas stream, optionally adjusting its hydrogen:nitrogen molar ratio to form an ammonia synthesis gas; and passing the ammonia synthesis gas over an ammonia synthesis catalyst in an ammonia converter to form ammonia.

Hydrogen generation assemblies, hydrogen purification devices, and their components, and methods of manufacturing those assemblies, devices, and components are disclosed. In some embodiments, the devices may include an insulation base having insulating material and at least one passage that extends through the insulating material. In some embodiments, the at least one passage may be in fluid communication with a combustion region.

This invention provides a preparation method of a catalyst for preferential oxidization of CO in a hydrogen-enriched atmosphere, and a catalyst product obtained from the method and its applications thereof. Particularly, in this invention, a wide-temperature catalyst for preferential oxidization of CO in a hydrogen-enriched atmosphere is obtained by depositing one or more of an iron oxide, cobalt oxide, and nickel oxide as a promoter onto the surface of a supported Pt-group noble metal catalyst precursor via chemical vapor deposition or atomic layer deposition. In the wide-temperature catalyst, the active noble metal component has a content of 0.1 to 10 wt %, and the promoter has a content of 0.1 to 10 wt % in terms of the metal element thereof. In the reaction of preferential oxidation of CO in a hydrogen-enriched atmosphere, the catalyst prepared by this invention can exhibit excellent catalytic performance and can achieve high conversion of CO with high selectivity in a wide temperature range of −80 to 200° C., for example. Also, the catalyst can remain stable for a long time even in a case where steam and CO.sub.2 are present in the hydrogen-enriched atmosphere.

A method of removing CO from a mixture of CO and saturated and unsaturated hydrocarbons CO to CO.sub.2 is provided. In one embodiment, the method is to contact feed stream with an oxygen transfer agent; and then oxidize at least a portion of the CO to CO.sub.2 to produce a stream enriched in CO.sub.2. The saturated and unsaturated hydrocarbons in the feed are not further oxidized during the oxidation. The oxygen transfer agent includes at least one of: i) water; ii) at least one reducible metal oxide; iii) at least one reducible chalcogen; or mixtures thereof. In another embodiment, the CO is converted to methane. The unsaturated hydrocarbons in the feed are not hydrogenated. In both of these alternatives, the CO.sub.2 or methane are then removed. Systems for removing the CO are also provided.

A process for the co-production of low carbon methanol and ammonia, including providing renewable power to an electrolysis unit, thereby producing at least a green oxygen stream and a green hydrogen stream. Providing renewable power to a nitrogen generation unit, thereby producing a green nitrogen stream. Providing a hydrocarbon stream and some amount of steam to an oxygen based reformer, along with at least part of the green oxygen stream, thereby producing a raw syngas stream. Combining the green hydrogen stream with the oxygen-based reformer feed to adjust the composition of the raw syngas stream to be suitable for methanol synthesis. Introducing the raw syngas stream into either a conventional or once-through methanol synthesis reactor, thereby producing at least a low carbon methanol product (after purification) and an unreacted syngas stream.

A method and system for decarbonization of a hydrocarbon conversion process such as steam methane reforming process for hydrogen production utilizing oxygen transport membrane reactors. The system employs catalyst-containing reforming reactors for converting natural gas into synthesis gas which is further treated in high temperature or medium temperature water gas shift reactors and fed to a hydrogen PSA to produce hydrogen product. The system further employs oxygen transport membrane reactors thermally coupled to reforming reactors and configured to oxy-combust about 90% to about 95% of combustibles in PSA tail gas that may be optionally mixed with natural gas. The oxy-combustion product stream leaving the oxygen transport membrane reactors contains about 90% of the carbon provided to the feed of the reforming reactor. The carbon dioxide in the oxy-combustion product stream can be recovered and further purified for utilization or geologic storage or liquefied to form a liquid carbon dioxide product.

A process to synthesize a catalyst performing Water-Gas shift reaction at a temperature more than 300° C. using a precursor having general formula [(Cu, Zn).sub.1−x (Al, M).sub.x (OH).sub.2].sup.x+ (A.sup.n−.sub.x/n).kH.sub.2O with M=Al, La, Ga or In, A=CO.sub.3, 0.33<x<0.5, 1<n<3.

A process for producing and storing hydrogen includes providing an intermediate gas mixture having an increased proportion of hydrogen and contacting of the intermediate gas mixture with a hydrogen carrier medium in order to hydrogenate the hydrogen carrier medium.

Integrated liquid fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongated tube having a gas-permeable wall with internal and external surfaces. The wall encloses an unobstructed gaseous flow passageway. At least a portion of the wall has CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The liquid fuel CPOX reformer also can include a vaporizer, one or more igniters, and a source of liquid reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the CPOX reactor unit.

The process of the present invention provides high recovery and low capital cost giving it an economic advantage over previously known purification processes. The present process has particular applicability to the purification of synthesis gases comprising at least hydrogen (H.sub.2), carbon monoxide (CO), methane (CH.sub.4), CO.sub.2, and H.sub.2O to obtain a gas stream including at least H.sub.2, CO, and CH.sub.4, that is substantially free of H.sub.2O and CO.sub.2. The process also has applicability to the purification of natural gases inclusive of at least CH.sub.4, N.sub.2, CO.sub.2, and H.sub.2O to produce a gas stream including at least CH.sub.4 and N.sub.2, but which is substantially free of H.sub.2O and CO.sub.2.