C01B2203/1264

Hydrogen production by steam methane reforming

A hydrogen plant for producing hydrogen, including: a reforming reactor system including a first catalyst bed including an electrically conductive material and a catalytically active material, a heat insulation layer between the first catalyst bed and the pressure shell, and at least two conductors electrically connected to the electrically conductive material and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of the first catalyst bed to a temperature of at least 500° C. by passing an electrical current through the electrically conductive material, where the pressure shell has a design pressure of between 5 and 200 bar; a water gas shift unit downstream the reforming reactor system; and a gas separation unit downstream the water gas shift unit. A process for producing hydrogen from a feed gas including hydrocarbons.

Hydrogen production with membrane reformer

A system and method for producing hydrogen from hydrocarbon and steam, including a membrane reformer with multiple membrane reactors each having a tubular membrane. The bore of the tubular membrane is the permeate side for the hydrogen. The region external to the tubular membrane is the retentate side for carbon dioxide. A sweep gas flows through the bore to displace hydrogen in a direction countercurrent to flow of hydrocarbon and steam in the region external to the tubular membrane. The method includes discharging hydrogen as permeate with the sweep gas from the bore, and discharging carbon dioxide in the region external to the tubular membrane as retentate from the membrane reactor.

Low steam/carbon revamp of a plant comprising a steam reforming section and a water-gas shift section

The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH.sub.4, CO, CO.sub.2, H.sub.2 and H.sub.2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step,
said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.

PROCESS FOR THE PREPARATION OF SYNGAS
20170327374 · 2017-11-16 ·

The invention is directed to a process for the preparation of a syngas comprising hydrogen and carbon monoxide from a methane comprising gas, which process comprises the steps of: (a) reacting the methane comprising gas with an oxidising gas in an autothermal reformer to obtain a hot raw syngas comprising carbon monoxide and hydrogen; (b) cooling the hot raw syngas resulting from step (a) to obtain the syngas, wherein step (b) comprises cooling the hot raw syngas by indirect heat exchange against the methane comprising gas used in step (a) and wherein sulphur is added upstream of cooling step (b). The invention also relates to a process for the preparation of hydrocarbon products in which a feed syngas is prepared in the process as described above followed by a desulphurisation treatment and the desulphurised syngas is subsequently converted into hydrocarbon products in a Fischer-Tropsch process.

Hydrogen Production with Membrane Reformer

A system and method for producing hydrogen from hydrocarbon and steam, including a membrane reformer with multiple membrane reactors each having a tubular membrane. The bore of the tubular membrane is the permeate side for the hydrogen. The region external to the tubular membrane is the retentate side for carbon dioxide. A sweep gas flows through the bore to displace hydrogen in a direction countercurrent to flow of hydrocarbon and steam in the region external to the tubular membrane. The method includes discharging hydrogen as permeate with the sweep gas from the bore, and discharging carbon dioxide in the region external to the tubular membrane as retentate from the membrane reactor.

ATR-Based Hydrogen Process and Plant

A plant and process for producing a hydrogen rich gas and improved carbon capture are provided, said process comprising the steps of: reforming a hydrocarbon feed by optional prereforming, autothermal reforming (ATR), yet no primary reforming, thereby obtaining a synthesis gas; shifting said synthesis gas in a shift section including a high temperature shift step; removal of CO.sub.2 upstream hydrogen purification unit, thereby producing a hydrogen rich stream and an off-gas stream, and where at least part of the off-gas stream is recycled to the process, thus to the ATR and optional prereforming, and/or to the shift section.

Synthesis gas production process for the implementation of a natural gas liquefaction

Natural gas liquefaction process in combination with a synthesis gas production process, where the steam derived from the synthesis gas production process is used as a heating source for the implementation of the pre-treatment step for eliminating the impurities liable to freeze during the natural gas liquefaction process.

Process and apparatus for producing a feed stream for a steam reforming plant

The invention relates to a process and an apparatus for producing an olefin-containing feed stream for a steam reforming plant. According to certain embodiments of the invention, the olefin-containing hydrocarbon starting material is for this purpose vaporized and catalytically hydrogenated. The hydrogenation product stream obtained is separated into a gaseous reforming feed stream, which is fed to a steam reforming plant, and a gaseous recycle stream. As a result of the cooling according to the invention of the gaseous recycle stream down to at least partial condensation thereof and the separate recirculation of the gaseous partial recycle stream and of the liquid partial recycle stream, the procurement of a large and complicated circulation compressor is avoided and electric energy for operating this compressor is saved.

HYDROGEN PRODUCTION BY STEAM METHANE REFORMING

A hydrogen plant for producing hydrogen, including: a reforming reactor system including a first catalyst bed including an electrically conductive material and a catalytically active material, a heat insulation layer between the first catalyst bed and the pressure shell, and at least two conductors electrically connected to the electrically conductive material and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of the first catalyst bed to a temperature of at least 500° C. by passing an electrical current through the electrically conductive material, where the pressure shell has a design pressure of between 5 and 200 bar; a water gas shift unit downstream the reforming reactor system; and a gas separation unit downstream the water gas shift unit. A process for producing hydrogen from a feed gas including hydrocarbons.

STEAM REFORMING HEATED BY RESISTANCE HEATING

A reactor system for carrying out steam reforming of a feed gas comprising hydrocarbons, including: a structured catalyst arranged for catalyzing steam reforming of a feed gas including hydrocarbons, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the macroscopic structure and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of the structured catalyst to a temperature of at least 500° C. by passing an electrical current through the macroscopic structure. Also, a process for steam reforming of a feed gas comprising hydrocarbons.