Provided herein is a gas mixer for the safe mixing of a hydrocarbon containing gas with a gaseous oxidant. The gas mixer and method for mixing described includes a closed mixing vessel where bubbles of gas injected at the bottom of the vessel are mixed during their rise to the top of the vessel, forming a homogeneous mixture that can safely be removed. This simple design and method allows for safe mixing of gases and is applicable to catalytic oxidative processes such as oxidative dehydrogenation of paraffins where there is a risk of thermal runaway of reactions.

The disclosure relates to methods, systems, and apparatus arranged and designed for converting non-methane hydrocarbon gases into multiple product gas streams including a predominately hydrogen gas stream and a predominately methane gas steam. Hydrocarbon gas streams are reformed, cracked, or converted into a synthesis gas stream and methane gas stream by receiving a volume of flare gas or other hydrocarbon liquid or gas feed, where the volume of hydrocarbon feed includes a volume of methane and volume of nonmethane hydrocarbons. The hydrogen contained in the syngas may be separated into a pure hydrogen gas stream. A corresponding gas conversion system can include a super heater to provide a hydrocarbon feed/steam mixture, a heavy hydrocarbon reactor for synthesis gas formation, and a hydrogen separator to recover the hydrogen portion of the synthesis gas.

A process for producing syngas that uses the syngas product from an oxygen-fired reformer to provide all necessary heating duties, which eliminates the need for a fired heater. Without the flue gas stream leaving a fired heater, all of the carbon dioxide produced by the reforming process is concentrated in the high-pressure syngas stream, allowing essentially complete carbon dioxide capture.

Method for the preparation of synthesis gas combining electrolysis of water, tubular steam reforming and autothermal reforming of a hydrocarbon feed stock in parallel.

Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.

An engine system for internal combustion and reformation of a fuel includes an engine, and a reforming reactor. The engine comprising an intake manifold for receiving a first fuel and an exhaust manifold for releasing an exhaust gas. The reforming reactor includes a first end portion, a second end, a wall having an outer surface and an inner surface. The inner surface defines an interior cavity for receiving the first fuel, a second fuel, reactants for the first fuel, or combinations thereof. The exhaust manifold of the system is sized and shaped for receiving a portion of the reforming reactor such that the exhaust gas flows along a surface of the reforming reactor within the exhaust manifold.

A reactor containing a heat exchanger is disclosed, which can be operated with co-current or counter-current flow. Also disclosed is a system that includes a reactor having a reformer and a vaporizer, a fuel supply, and a water supply. The reactor includes a source of combustion gas, a reformer operative to receive reformate, and a vaporizer operative to receive water. The reformer and vaporizer each include a stack assembly formed by a combination of separator shims and channel shims. The separator shims and channel shims are stacked in a regular pattern to form two sets of channels within the stack assembly. One set of channels will have vertical passageways at either end and a horizontal flowpath between them, while the other set of channels has only a horizontal flowpath.

The invention relates to petroleum sludge or other wastes recycle treatment system, which comprises a pre-treatment operation facility for a treated matter to be treated as a raw material. A feeding unit is arranged to feed the raw material into at least one gasification reactor with a push rod or a screw for pyrolysis gasification. The upper half of the at least one gasification reactor is provided with a syngas collecting pipe which can be connected with a gas collecting pump, and the lower half is provided with a liquid petroleum output pipe and an ash residue outlet, in which the ash residue outlet can be provided with a spiral pipe to draw the ash residue out. The petroleum sludge and other wastes in a dense fluid state are transported from a raw material tank to the at least one gasification reactor end which is bent upward through at least one pipe body, and the feeding mode of pyrolysis gasification of the raw material from below to upper of the gasification reactor is adopted. The top of the at least one gasification reactor is provided with a syngas collecting pipe, and the other side is provided with an ash residue accumulation chamber. The ash residue can be centralized and discharged through the lower buffer chamber and the slag discharge chamber, so as to convert the petroleum sludge or other wastes into more energy-efficient syngas providing human beings as users of electric or thermal energy.

Integrated liquid fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongated tube having a gas-permeable wall with internal and external surfaces. The wall encloses an unobstructed gaseous flow passageway. At least a portion of the wall has CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The liquid fuel CPOX reformer also can include a vaporizer, one or more igniters, and a source of liquid reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the CPOX reactor unit.

A reformer system (11) having a hydrodesulfurizer (12) provides desulfurized natural gas feedstock to a catalytic steam reformer (16), the outflow of which is treated by a water gas shift reactor (20) and optionally a preferential CO oxidizer (58) to provide reformate gas (28, 28a) having high hydrogen and moderate carbon dioxide content. To avoid damage to the hydrodesulfurizer from overheating, any deleterious hydrogen reactants, such as the oxygen in peak shave gas or olefins, in the non-desulfurized natural gas feedstock (35) are reacted (38) with hydrogen (28, 28a; 71) to convert them to alkanes (e.g., ethylene and propylene to ethane and propane) and to convert oxygen to water in a catalytic reactor (38) having no sulfide sorbent, and cooled (46), below a temperature which would damage the reactor, by evaporative cooling with pressurized hot water (42). Hydrogen for the desulfurizer and the hydrogen reactions may be provided as recycle reformate (28, 28a) or from a mini-CPO (67), or from other sources.