C01B2203/143

Synthetic fuels by electrically heated steam methane reforming

A method for producing a synthesis gas for use in the production of a hydrocarbon product, particularly a synthetic fuel, the method including the steps of: providing a hydrocarbon feed gas; optionally, purifying the hydrocarbon feed gas in a gas purification unit; optionally, prereforming the hydrocarbon feed gas together with a steam feedstock in a prereforming unit; carrying out steam methane reforming in a reforming reactor heated by means of an electrical power source; providing the synthesis gas to a synthetic fuel synthesis unit, preferably a Fischer-Tropsch synthesis unit, for converting the synthesis gas into hydrocarbon product and producing a tail gas. Also, a system for producing a synthesis gas for use in the production of a hydrocarbon product, particularly a synthetic fuel.

Biogas Conversion To Synthesis Gas For Producing Hydrocarbons

The invention relates to a a method for producing a synthesis gas for use in the production of a hydrocarbon product, particularly a synthetic fuel, said method comprising the steps of: providing a hydrocarbon feed stream comprising biogas; optionally, purifying the hydrocarbon feed stream in a gas purification unit; optionally, prereforming the hydrocarbon feed stream together with a steam feedstock in a prereforming unit; carrying out steam methane reforming in a reforming reactor heated by means of an electrical power source; providing the synthesis gas to a synthetic fuel synthesis unit, preferably a Fischer-Tropsch synthesis unit, for converting said synthesis gas into hydrocarbon product and producing a tail gas. The invention also relates to a system for producing a synthesis gas for use in the production of a hydrocarbon product, particularly a synthetic fuel.

Low steam/carbon revamp of a plant comprising a steam reforming section and a water-gas shift section

The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH.sub.4, CO, CO.sub.2, H.sub.2 and H.sub.2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step,
said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.

PYROLYSIS GAS REFORMING SYSTEM

A pyrolysis gas reforming system is provided. The pyrolysis gas reforming system includes a pyrolysis unit configured to perform pyrolysis of waste, an oil-gas separation unit configured to separate a product generated by the pyrolysis unit into oil and gas, a pyrolysis gas purification unit configured to refine pyrolysis gas generated through the separation by the oil-gas separation unit, a pyrolysis gas reforming unit configured to generate synthesis gas by reforming the pyrolysis gas purified by the pyrolysis gas purification unit, a hydrogen gas shift reaction unit configured to convert carbon monoxide contained in the synthesis gas generated by the pyrolysis gas reforming unit into hydrogen and carbon dioxide, and a hydrogen separation unit configured to separate hydrogen from the synthesis gas discharged from the hydrogen gas shift reaction unit, wherein combustion gas generated by a burner of the pyrolysis gas reforming unit and used to supply heat to the pyrolysis gas reforming unit is used to supply heat to the pyrolysis unit.

A PROCESS FOR GENERATION OF SNTHESIS GAS BY FLUE GAS RECYCLE
20170369312 · 2017-12-28 · ·

A novel process for synthesis gas generation comprises treating a hydrocarbon feed in a primary reformer (PR), compressing at least part of the flue gas from the primary reformer in a compressor (C1), and feeding the compressed flue gas to a secondary reformer (SR) together with the primary reformer effluent. In the process, enriched air (EA) is added either to the primary reformer, to the secondary reformer or both. The process is especially suited for co-production of ammonia and methanol or for production of either ammonia or methanol. The total CO.sub.2 emission is lowered considerably by using the process of the invention.

DIESEL REFORMING APPARATUS HAVING A HEAT EXCHANGER FOR HIGHER EFFICIENCY STEAM REFORMING FOR SOLID OXIDE FUEL CELLS (SOFC)

Embodiments of the present disclosure are directed to a diesel reformer system comprising: a diesel autothermal reforming unit; a post-reforming unit disposed downstream of the autothermal reforming unit; a heat exchanger disposed downstream of the post-reforming unit; and a desulfurization unit disposed downstream of the heat exchanger.

SYSTEMS AND METHODS FOR INCREASING THE HYDROGEN PERMEANCE OF HYDROGEN-SEPARATION MEMBRANES IN SITU

Hydrogen-producing fuel processing systems and related methods. The systems include a hydrogen-producing region configured to produce a mixed gas stream from a feedstock stream, a hydrogen-separation membrane module having at least one hydrogen-selective membrane and configured to separate the mixed gas stream into a product hydrogen stream and a byproduct stream, and an oxidant delivery system configured to deliver an oxidant-containing stream to the hydrogen-separation membrane module in situ to increase hydrogen permeance of the hydrogen-selective membrane. The methods include operating a hydrogen-producing fuel processing system in a hydrogen-producing regime, and subsequently operating the hydrogen-producing fuel processing system in a restoration regime, in which an oxidant-containing stream is delivered to the hydrogen-separation membrane module in situ to expose the at least one hydrogen-selective membrane to the oxidant-containing stream to increase the hydrogen permeance of the at least one hydrogen-selective membrane.

PROCESS FOR THE PRODUCTION OF HYDROGEN

A process of hydrogen production comprising the steps of: subjecting a gaseous mixture comprising a hydrocarbon and steam, and having a steam to carbon ratio of at least 0.9:1, to adiabatic pre-reforming in a pre-reformer followed by autothermal reforming with an oxygen-rich gas in an autothermal reformer to generate a reformed gas mixture, optionally adding steam to the reformed gas mixture, increasing the hydrogen content of the reformed gas mixture by subjecting it to one or more water-gas shift stages in a water-gas shift unit to provide a hydrogen-enriched reformed gas, cooling the hydrogen-enriched reformed gas and separating condensed water therefrom, passing the resulting de-watered hydrogen-enriched reformed gas to a carbon dioxide separation unit to provide a carbon dioxide gas stream and a crude hydrogen gas stream, passing the crude hydrogen gas stream to a purification unit to provide a purified hydrogen gas and a fuel gas.

REACTOR AND TEMPERATURE CONTROL METHOD THEREOF
20170282149 · 2017-10-05 · ·

A reactor suitable for a reaction containing an exothermic reaction is provided. The reactor includes the following components. A reaction channel has an inlet and an outlet, and has a front-end reaction zone, middle-end reaction zones, and a back-end reaction zone from the inlet to the outlet. A front-end catalyst support and a front-end catalyst are located in the front-end reaction zone, a middle-end catalyst support and a middle-end catalyst are respectively located in the middle-end reaction zones, and a back-end catalyst support and a back-end catalyst are located in the back-end reaction zone. The concentration of the front-end catalyst is less than the concentration of the back-end catalyst, and the concentration of the middle-end catalyst is decided via a computer simulation of reaction parameters. The reaction parameters include size and geometric shape of the reaction channel.

Apparatus and process for gasification of carbonaceous materials to produce syngas

A process and apparatus are provided for gasification of a carbonaceous material. The process produces a raw syngas that can be further processed in a tar destruction zone to provide a hot syngas. The process includes contacting said carbonaceous material with molecular oxygen-containing gas in a gasification zone to gasify a portion of said carbonaceous material and to produce a first gaseous product. A remaining portion of the carbonaceous material is contacted with molecular oxygen-containing gas in a burn-up zone to gasify additional portion of the carbonaceous material and to produce a second gaseous product and a solid ash. The first gaseous product and said second gaseous product are combined to produce a raw syngas that includes carbon monoxide (CO), carbon dioxide (CO.sub.2) and tar. The raw syngas is contacted with molecular oxygen containing gas in a tar destruction zone to produce said hot syngas.