Integrated plants and associated processes for producing ammonia and sulfuric acid have been developed comprising air separation and water electrolysis subsystems and which make surprisingly efficient use of the products from these subsystems (i.e. oxygen and nitrogen from the former and hydrogen and oxygen from the latter). The invention is particularly suitable for use as part of an integrated fertilizer production plant.

The present invention provides for a method for producing an aqueous monoammonium phosphate containing fertilizer solution. The method provides for means to control the temperature of a reaction zone as measured at a reagent entry point and a product exit point. The pH of the reaction is monitored and the reaction is terminated when the reaction mixture has reached a pH of between about 5.5 and about 7.5. The invention further provides for a method of treating crops with a monoammonium phosphate solution having a pH of between 6 and 7.

A method for production of ammonium phosphate from phosphate rock slurry. The method includes: introducing flue gas containing SO.sub.2 into a phosphate rock slurry, to yield an absorption solution; evaporating waste ammonia water containing 10-20 wt. % ammonia to yield ammonia gas; introducing the ammonia gas into the absorption solution at a temperature of 110-135° C. until a neutralization degree of the absorption solution reaches 1.5-1.6, thus yielding an ammonium phosphate solution and calcium sulfate; separating the calcium sulfate from the ammonium phosphate solution; and introducing the ammonium phosphate solution to a granulator for granulation to yield ammonium phosphate granules; drying and sieving the ammonium phosphate granules, thereby yielding ammonium phosphate.

A method for production of ammonium phosphate from phosphate rock slurry. The method includes: introducing flue gas containing SO.sub.2 into a phosphate rock slurry, to yield an absorption solution; evaporating waste ammonia water containing 10-20 wt. % ammonia to yield ammonia gas; introducing the ammonia gas into the absorption solution at a temperature of 110-135° C. until a neutralization degree of the absorption solution reaches 1.5-1.6, thus yielding an ammonium phosphate solution and calcium sulfate; separating the calcium sulfate from the ammonium phosphate solution; and introducing the ammonium phosphate solution to a granulator for granulation to yield ammonium phosphate granules; drying and sieving the ammonium phosphate granules, thereby yielding ammonium phosphate.

A method for removal and recovery of phosphorus includes a precipitation step for precipitating phosphorus from a liquid stream comprising at most 30 mg of phosphorus per litre and at most than 50 mg of suspended solids per litre, using a precipitation agent, to form a precipitate, to form a precipitate; a first separation step for separating the precipitate from the liquid stream; a dissolution step for dissolving the precipitate in phosphoric acid to obtain a first solution; and a second separation step for separating the phosphoric acid and the precipitation agent.

A method for removal and recovery of phosphorus includes a precipitation step for precipitating phosphorus from a liquid stream comprising at most 30 mg of phosphorus per litre and at most than 50 mg of suspended solids per litre, using a precipitation agent, to form a precipitate, to form a precipitate; a first separation step for separating the precipitate from the liquid stream; a dissolution step for dissolving the precipitate in phosphoric acid to obtain a first solution; and a second separation step for separating the phosphoric acid and the precipitation agent.

An arrangement (100) for production of fully soluble, pure and well defined mono- or di-ammonium phosphates, comprises an extraction section (10), a stripping section (20) and end treatment arrangements (90). The extraction section performs a liquid-liquid extraction of phosphate between a feed liquid (1) comprising phosphoric acid and being essentially free from nitrate ions, and a solvent (5) having a solubility in water of less than 2%. The stripping section performs a liquid-liquid extraction of phosphate between solvent loaded with phosphate and a strip solution (4). The solvent depleted in phosphate is recirculated to the extraction section for further extraction of phosphate. The strip solution is an aqueous ammonium phosphate solution, wherein at least 80% of the ammonium phosphate is monoammonium phosphate and/or wherein the solvent is a water-immiscible alcohol. The end treatment arrangements comprise a source of ammonia (60), an adding arrangement (70), a cooling arrangement (50), a precipitate remover (40) and a recirculation system (80).

An arrangement (100) for production of fully soluble, pure and well defined mono- or di-ammonium phosphates, comprises an extraction section (10), a stripping section (20) and end treatment arrangements (90). The extraction section performs a liquid-liquid extraction of phosphate between a feed liquid (1) comprising phosphoric acid and being essentially free from nitrate ions, and a solvent (5) having a solubility in water of less than 2%. The stripping section performs a liquid-liquid extraction of phosphate between solvent loaded with phosphate and a strip solution (4). The solvent depleted in phosphate is recirculated to the extraction section for further extraction of phosphate. The strip solution is an aqueous ammonium phosphate solution, wherein at least 80% of the ammonium phosphate is monoammonium phosphate and/or wherein the solvent is a water-immiscible alcohol. The end treatment arrangements comprise a source of ammonia (60), an adding arrangement (70), a cooling arrangement (50), a precipitate remover (40) and a recirculation system (80).

Disclosed are a cathode active material for a lithium secondary battery including a core containing lithium composite metal oxide, and a coating layer disposed on the core, containing a mixture of lithium oxide, tungsten oxide, boron oxide and phosphorus oxide, and having an amorphous phase, and a lithium secondary battery including the same.

The present disclosure is generally directed to a water processing system. In some embodiments, the water processing system may be configured to generate a potassium salt, such as potassium nitrate, an ammonium salt, such as ammonium nitrate, or both. In some embodiments, the water processing system may be at least partially powered by renewable energy, such as by using a liquid storage system that is at least partially underground. In some embodiments, the water processing system may be configured to reuse certain greenhouse emissions to improve performance of power generation systems associated with the water processing system.