The present invention relates to hollow nanocoils having a three-dimensional helical structure in the form of a hollow tube and a method of manufacturing the same.

The present invention provides a method of synthesizing metal nanocoils into inorganic hollow nanocoils using the galvanic replacement reaction and an electrochemical reaction including the Kirkendall effect. The inorganic hollow nanocoil structure body of the present invention can be applied to various fields such as sensors, catalysts, batteries, or gene delivery and therapy using a large surface area.

The present invention relates to hollow nanocoils having a three-dimensional helical structure in the form of a hollow tube and a method of manufacturing the same.

The present invention provides a method of synthesizing metal nanocoils into inorganic hollow nanocoils using the galvanic replacement reaction and an electrochemical reaction including the Kirkendall effect. The inorganic hollow nanocoil structure body of the present invention can be applied to various fields such as sensors, catalysts, batteries, or gene delivery and therapy using a large surface area.

A method of preparing ferric phosphate from iron-containing waste, including: step a) providing a ferric chloride-containing mixture solution obtained from acidolysis of iron-containing waste; step b) adjusting pH of the ferric chloride-containing mixture solution to satisfy 0<pH≤2 and Fe.sup.3+ concentration to 10-80 g/L with an alkaline compound and water, to obtain an iron source solution; step c) mixing and reacting the iron source solution obtained from the step b) with a solution of calcium dihydrogen phosphate in a molar ratio of P to Fe of 1 : 1-1.8, to obtain a slurry with a pH of 0.2-2; and step d) performing aging and crystal transformation on the slurry, to obtain ferric phosphate. A battery-grade ferric phosphate with high purity and good product quality can be obtained without the need for deep purification of raw materials.

To provide an unprecedented novel zirconium phosphate. A zirconium phosphate represented by Formula [1]: Zr(H.sub.a(NH.sub.4).sub.b(PO.sub.4))(HPO.sub.4).nH.sub.2O, wherein Ia/Ib is 1.0 or less where the maximum peak intensity in the range of 2θ=5 to 13° measured by the X-ray diffraction method is denoted by Ia and the maximum peak intensity in the range of 2θ=26 to 28° is denoted by Ib, and in Formula [1], a, b, and c are numbers satisfying a+b=1 and 0≤b<1, and n is a number satisfying 0≤n≤2.

To provide an unprecedented novel zirconium phosphate. A zirconium phosphate represented by Formula [1]: Zr(H.sub.a(NH.sub.4).sub.b(PO.sub.4))(HPO.sub.4).nH.sub.2O, wherein Ia/Ib is 1.0 or less where the maximum peak intensity in the range of 2θ=5 to 13° measured by the X-ray diffraction method is denoted by Ia and the maximum peak intensity in the range of 2θ=26 to 28° is denoted by Ib, and in Formula [1], a, b, and c are numbers satisfying a+b=1 and 0≤b<1, and n is a number satisfying 0≤n≤2.

The present disclosure belongs to technical field of cathode materials of lithium batteries, and discloses a preparation method of high-safety high-capacity lithium manganese iron phosphate. The method includes the steps: (1) synthesizing a ferrous phosphate precursor through a co-precipitation process, and sintering to obtain an anhydrous ferrous phosphate precursor; (2) synthesizing a manganese phosphate precursor through co-precipitation process, and sintering to obtain an anhydrous manganese phosphate precursor; (3) adding lithium phosphate and deionized water into anhydrous ferrous phosphate precursor, and performing ball milling and wet sanding to obtain slurry A; (4) adding lithium phosphate, an organic carbon source, a dispersant, a dopant and deionized water into anhydrous manganese phosphate precursor, and performing ball milling and wet sanding to obtain slurry B; and (5) mixing slurry A with slurry B, and performing ball milling, spray drying, sintering and air jet pulverization to obtain high-safety high-capacity lithium manganese iron phosphate.

The present invention relates to a process for preparing an ammonium vanadium phosphate of formula (NH.sub.4)(VO.sub.2)(HPO.sub.4). It also relates to a process for preparing a vanadium orthophosphate VPO.sub.4.

Provided are zirconium phosphate particles, obtained by bringing α-zirconium phosphate particles into contact with a basic liquid having a pH of 9 or higher and then further bringing the particles into contact with an acidic liquid having a pH of 6 or lower, or zirconium phosphate particles, in which, after leaving for 10 minutes from putting 10 mg of zirconium phosphate particles and 3 L of air that contains 1,000 ppm of an ammonia gas into a test bag at normal temperature and normal pressure, an ammonia gas reduction rate within the test bag that contains the zirconium phosphate particles is 50% or more.

Provided are zirconium phosphate particles, obtained by bringing α-zirconium phosphate particles into contact with a basic liquid having a pH of 9 or higher and then further bringing the particles into contact with an acidic liquid having a pH of 6 or lower, or zirconium phosphate particles, in which, after leaving for 10 minutes from putting 10 mg of zirconium phosphate particles and 3 L of air that contains 1,000 ppm of an ammonia gas into a test bag at normal temperature and normal pressure, an ammonia gas reduction rate within the test bag that contains the zirconium phosphate particles is 50% or more.

A compound of Formula 1
Li.sub.1+(4−a)αHf.sub.2−αM.sup.a.sub.α(PO.sub.4−δ).sub.3  (1)
is disclosed, wherein M is at least one cationic element having a valence of a, wherein 0<α≤⅔, 1≤a≤4, and 0≤δ≤0.1. Also described are an electrolyte composition, a separator, a protected positive electrode, a protected negative electrode, and a lithium battery, each including the compound of Formula 1.