An arrangement (100) for production of fully soluble, pure and well defined mono- or di-ammonium phosphates, comprises an extraction section (10), a stripping section (20) and end treatment arrangements (90). The extraction section performs a liquid-liquid extraction of phosphate between a feed liquid (1) comprising phosphoric acid and being essentially free from nitrate ions, and a solvent (5) having a solubility in water of less than 2%. The stripping section performs a liquid-liquid extraction of phosphate between solvent loaded with phosphate and a strip solution (4). The solvent depleted in phosphate is recirculated to the extraction section for further extraction of phosphate. The strip solution is an aqueous ammonium phosphate solution, wherein at least 80% of the ammonium phosphate is monoammonium phosphate and/or wherein the solvent is a water-immiscible alcohol. The end treatment arrangements comprise a source of ammonia (60), an adding arrangement (70), a cooling arrangement (50), a precipitate remover (40) and a recirculation system (80).

Embodiments described herein provide systems and methods for a phosphate processing system with integrated sub-systems, such as a phosphoric acid plant, precipitation system, crystallizer system, rinsing system, granulation system, pond water system, organics removal system, and/or exhaust treatment system. Such sub-systems can be integrated with each other by using one or more output streams from one or more sub-systems as one or more input streams for one or more sub-systems. In some embodiments, the phosphate processing system can produce phosphoric acid, struvite containing fertilizer, fertilizer using recycled struvite, magnesium or fluoride containing compositions using recycled magnesium or fluoride, and other components using phosphoric acid collected from a phosphoric acid and gypsum composition or using sludge collected from a waste stream, for example.

There is provided a process for preparing a crystalline electrode material, the process comprising: providing a liquid bath comprising the electrode material in a melted state; and introducing a precursor of the electrode material into the liquid bath, wherein the electrode material comprises lithium, a metal and phosphate. There is also provided a crystalline electrode material, comprising lithium substituted by less than 0.1 atomic of Na or K; Fe and/or Mn, substituted by less than 0.1 atomic ratio of: (a) Mg, Ca, Al and B, (b) Nb, Zr, Mo, V and Cr, (c) Fe(III), or (d) any combinations thereof; and PO.sub.4, substituted by less than 20% atomic weight of an oxyanion selected from SO.sub.4, SiO.sub.4, BO.sub.4, P.sub.2O.sub.7, and any combinations thereof, the material being in the form of particles having a non-carbon and non-olivine phase on at least a portion of the surface thereof.